The strength of energetic materials is one of the principal parameters to express their performance. Two new methods were introduced for the prediction of the strength of CaHbNcOd energetic materials through the Trauzl test. They are based on elemental composition and the condensed or gas phase heats of formation of energetic compounds. The model is based on the gas phase heat of formation, uses the group additivity method and requires only the molecular structure of the desired energetic compound. These methods provide more reliable predictions as compared to the best available theoretical methods. Some of the benefits of these new models are their accuracy, precision, simplicity, and low price. 相似文献
Linear poroelastic effective stress law is often used to relate in situ total stresses to pore fluid pressure in underground formations. The indirect estimations of effective stress coefficient (Biot coefficient) based on porosity relationships are often not accurate, and therefore the Biot coefficient measurements on retrieved samples using hydro-mechanical laboratory testing is considered. In this study, we propose a new indirect technique to infer the Biot coefficient from micro X-ray computed tomography (XRCT) images of porous granular samples whenever images are available using a simple principle of continuum mechanics. The performance of the method was assessed through a series of experiments conducted on sandstone and unconsolidated sand. The proposed method enables calculating the anisotropy of the Biot coefficient of the sample in three dimensions. We also conducted the conventional hydro-mechanical experiment to validate the obtained Biot coefficient results from the XRCT technique. The proposed technique shows promising results on estimation of the Biot coefficient. The analysis of the images confirms that the method performs well when the connectivity between grains (skeleton structure) can be extracted from XRCT images with enough resolution. The method is also able to (a) estimate the Biot coefficient of both consolidated and unconsolidated sand structure and (b) map the anisotropy of Biot coefficient in three dimensions.
The aim of this study is to exploit the waste heat of a biomass-based solid oxide fuel cell (SOFC)–model (a)–in a gas turbine (GT) to enhance the power generation/exergy efficiency (model (b)). Moreover, surplus power which is generated by the GT is transferred to a proton exchange membrane electrolyzer (PEME) for hydrogen production (model (c)). Parametric study is performed to investigate the influence of the effective parameters on performance and economic indicators. Eventually, considering exergy efficiency and total product cost as the objective functions, the proposed models are optimized by multi-objective optimization method based on genetic algorithm. Accordingly, the optimum solution points are gathered as Pareto frontiers and subsequently favorable solution points are ascertained from exergy/economic standpoints. Results of parametric study indicate that model (b) is the best model as it has higher exergy efficiency and lower total product cost. Moreover, model (c) may be a more suitable model compared to the model (a) because of higher exergy efficiency and capability of hydrogen production. The results further show that, at the best final solution point, the exergy efficiency and total product cost of the model (b) would be 33.22% and 19.01 $/GJ, respectively. Corresponding values of exergy efficiency and total product cost of the model (c) are 32.3% and 20.1 $/GJ. Moreover, the rate of hydrogen production of the model (c) is 8.393 kg/day, at the best solution point. Overall, the integration methods are promising techniques for increasing exergy efficiency, reducing total product cost and also for hydrogen production. 相似文献
This article presents criteria for predicting transitions in free convection from isothermal convex bodies in fluids with any Prandtl number (conduction–laminar and laminar–turbulent transitions). Laminar–turbulent transition results for vertical plates happening in the vicinity of Grashof number 109 in fluids with any Prandtl number and other geometries show that this criterion based on Grashof number is a better choice compared to that of the Rayleigh number, as the Prandtl number yields a large change in the transition Rayleigh number. Besides, for convex geometries other than vertical plates, the laminar–turbulent transition occurs at values slightly less than Grashof number 109 owing to longitudinal vortices bringing about separation over their surface and helping laminar–turbulent transition to arise sooner. On the other side, the results of the conduction–laminar transition criterion for different convex bodies disclose that the Rayleigh number is superior to the Grashof number. Likewise, the present results for five different geometries over a wide range of Prandtl numbers are compared with the available experimental data, and excellent agreement is found. This reveals that the proposed criteria is powerful enough to predict the two transition phenomena in free convection heat transfer from isothermal convex bodies for a wide range of convex geometries in fluids with any Prandtl number. 相似文献
Energy and exergy analyses are reported of hydrogen production via an ocean thermal energy conversion (OTEC) system coupled with a solar-enhanced proton exchange membrane (PEM) electrolyzer. This system is composed of a turbine, an evaporator, a condenser, a pump, a solar collector and a PEM electrolyzer. Electricity is generated in the turbine, which is used by the PEM electrolyzer to produce hydrogen. A simulation program using Matlab software is developed to model the PEM electrolyzer and OTEC system. The simulation model for the PEM electrolyzer used in this study is validated with experimental data from the literature. The amount of hydrogen produced, the exergy destruction of each component and the overall system, and the exergy efficiency of the system are calculated. To better understand the effect of various parameters on system performance, a parametric analysis is carried out. The energy and exergy efficiencies of the integrated OTEC system are 3.6% and 22.7% respectively, and the exergy efficiency of the PEM electrolyzer is about 56.5% while the amount of hydrogen produced by it is 1.2 kg/h. 相似文献
In this research, the impact of pulsation intensity and phase flow rates on the volumetric overall mass transfer coefficients based on the continuous phase (Koca) and the axial dispersion coefficients of phases in a horizontal pulsed sieve-plate column has been investigated using axial dispersion model. The toluene-acetone-water and butyl acetate-acetone-water systems with acetone transfer in both directions were used. In this study, the flow regime transition from pseudo-dispersion regime to emulsion regime has been characterized. Two new correlations have been proposed for prediction of Koca and Ec. 相似文献
The available SMD(Sauter mean diameter) correlations on pressure-swirl injectors predict droplet sizing very different from each other, especially for heavy fuels. Also there was a lack in the literature for comparing available correlations. So an experimental study was conducted on a heavy fuel oil(HFO) spray, Mazut 380. A pressure swirl injector was designed and fabricated. The experiments for Mazut at 40 °C and 80 °C were compared with the results for water, including spray half cone angle, breakup length and mean droplet diameter,at different injection pressures. Lower spray angle, higher breakup length and larger droplets were observed for lower injection pressures and higher liquid viscosity. SMD was about 75 μm for water and about 87 μm for Mazut at 80 °C. The results for droplet mean diameter were also compared with correlations from previous studies on pressure swirl atomizers. The SMD results show that for water spray, LISA method was in good agreement,also Babu and Ballester correlations were successful when high viscosity fluid was injected. 相似文献
In this study, an impinging streams cyclone reactor has been utilized as a novel apparatus in photocatalytic degradation of phenol. Degussa P25 TiO2 nano particles have been applied as the photocatalyst under UV radiation. The operating parameters including catalyst loading, pH, initial phenol concentration and light Intensity have been found to affect the efficiency of the photocatalytic degradation process within this photoreactor. Photocatalytic degradation of phenol has been also investigated in a continuous flow impinging streams system. The results have shown a higher efficiency and an increased performance capability of the present reactor in comparison with the conventional processes. 相似文献