Nitrites Derived From Foneiculum Vulgare (Fennel) Seeds Promotes Vascular Functions

Abstract: Recent evidence has demonstrated that nitrites play an important role in the cardiovascular system. Fennel (Foneiculum vulgare) seeds are often used as mouth fresheners after a meal in both the Indian sub‐continent and around the world. The present study aims to quantify the nitrite and nitrates in fennel seeds as well as elucidating the effect of fennel derived‐nitrites on vascular functions. Results from our study show that fennel seeds contain significantly higher amount of nitrites when compared to other commonly used post‐meal seeds. Furthermore our study confirmed the functional effects of fennel derived‐nitrites using in vitro and ex vivo models that describe the promotion of angiogenesis, cell migration, and vasorelaxation. We also showed that chewing fennel seeds enhanced nitrite content of saliva. Thus our study indicates the potential role of fennel derived‐nitrites on the vascular system. Practical Application: This study is focused on determining the effect of fennel‐derived nitrites on angiogenesis (the formation of new blood vessels from pre‐existing ones), cell migration, and vasorelaxation (dilation of blood vessels) thereby preserving cardiovascular health.     

Combustion characteristics of a stationary diesel engine fuelled with a blend of crude rice bran oil methyl ester and diesel

The objective of the present work is to analyze the combustion characteristics of crude rice bran oil methyl ester (CRBME) blend (20% of CRBME with 80% no.2 diesel on volume basis) as a fuel in a stationary small duty direct injection (DI) compression ignition (CI) engine. When operating with CRBME blend the cylinder pressure was comparable to that of diesel. It was observed that the delay period and the maximum rate of pressure rise for CRBME blend were lower than those of diesel. The occurrence of maximum heat release rate advanced for CRBME blend with lesser magnitude when compared to diesel. CRBME blend requires more crank angle duration to release 50% & 90% of heat when compared with diesel. The brake specific fuel consumption of CRBME blend was found to be only marginally different from that of the diesel and its hourly fuel cost was higher than that of diesel. CRBME blend has lower smoke intensity and higher NOx emission than those of diesel. Since the measured parameters for CRBME blend differs only by a smaller magnitude, when compared with diesel, this investigation ensures the suitability of CRBME blend as fuel for CI engines with higher fuel cost.     

An experimental investigation on DI diesel engine with hydrogen fuel

The internal combustion engines have already become an indispensable and integral part of our present day life style, particularly in the transportation and agricultural sectors [Nagalingam B. Properties of hydrogen. In: Proceedings of the summer school of hydrogen energy, IIT Madras, 1984]. Unfortunately the survival of these engines has, of late, been threatened due to the problems of fuel crisis and environmental pollution. Therefore, to sustain the present growth rate of civilization, a nondepletable, clean fuel must be expeditiously sought. Hydrogen exactly caters to the specified needs. Hydrogen, even though “renewable” and “clean burning”, does give rise to some undesirable combustion problems in an engine operation, such as backfire, pre-ignition, knocking and rapid rate of pressure rise [Srinivasa Rao P. Utilization of hydrogen in a dual fueled engine. In: Proceedings of the summer school of hydrogen energy, IIT Madras, 1984; Siebers DL. Hydrogen combustion under diesel engine conditions. Hydrogen Energy 1998;23:363–71]. The present investigation compares the performance and emission characteristics of a DI diesel engine with gaseous hydrogen as a fuel inducted by means of carburation technique and timed port injection technique (TPI) along with diesel as a source of ignition [Swain N, Design and testing of dedicated hydrogen-fueled engine. SAE 961077, 1996]. In the present study the specific energy consumption, NO_x emission and the exhaust gas temperature increased by 6%, 8% and 14%, respectively, and brake thermal efficiency and smoke level reduced by 5% and 8%, respectively, using carburation technique compared to baseline diesel. But in the TPI technique, the specific energy consumption, exhaust gas temperature and smoke level reduced by 15%, 45% and 18%, respectively. The brake thermal efficiency and NO_x increased by 17% and 34%, respectively, compared to baseline diesel. The emissions such as HC, CO, and CO₂ is very low in both carburation and TPI techniques compared baseline diesel.     

Photostimulated luminescence studies of γ-irradiated KBr1−xIx:TlI mixed crystals

Results on photoluminescence and photostimulated luminescence studies of KBr_1−xI_x:TlI (0.01 and 0.05 mol%) mixed crystals grown in vacuum and air are presented. Photoluminescence spectra of the mixed crystals excited in the A-absorption band of KBr:Tl⁺ exhibited the characteristic emission bands of Tl⁺ ions in KBr:Tl⁺. When excited in the low energy tail of A-band absorption, additional emission bands were observed. Compared with earlier reports, excitation bands observed around 4.8, 4.6 and 4.4 eV are attributed to complex thallium centres of the form TlBr_6−nI_n (n = 0, 1, 2, 3). Photostimulated luminescence of γ-irradiated KBr_1−xI_x:TlI mixed crystals showed the presence of emission bands similar to the characteristic photoluminescence of Tl⁺ ions. The photostimulated luminescence slightly shifted towards the low energy side with increasing iodide composition x. The mechanism of emission in these mixed crystals is discussed. Dose response and storage stability (fading characteristics) in these mixed crystals are reported.     

Exergy Analysis of Solar Still with Sand Heat Energy Storage

This paper studies the experimental and exergy analysis of solar still with the sand heat energy storage system. The cumulative yield from solar still with and without energy storage material is found to be 3.3 and 1.89 kg/m², respectively for 8-h operation. Results show that the exergy efficiency of the system is higher with the least water depth of 0.02 m (m_w = 20 kg). Competitive analysis of second law efficiency shows that the exergy efficiency improves the system by 30% than conventional single slope solar still without any heat storage. The maximum exergy efficiency with energy storage material is found as 13.2% and it is less than the conventional solar still without any material inside the basin.     

An analysis of subsynchronous resonance in hybrid marine current and wind farms with squirrel cage induction generator

Subsynchronous resonance (SSR) is a well-known phenomenon in series-compensated systems with synchronous generators. With the rapid growth of renewable energy systems, it is likely that with its integration to series-compensated system for the transmission of bulk power may lead to the problem of SSR. This paper conducts an analysis of SSR phenomena in the squirrel cage induction generator-based hybrid wind farm and marine current farm connected to series-compensated system with power variation due to the addition or removal of small turbine units. A dynamic model has been developed to analyse the induction generator effect and torsional interaction of SSR on the IEEE first bench mark model for SSR studies. The eigenvalue analysis was performed on the developed model with MATLAB and the time domain electro magnetic transient simulation performed on DiGSILENT Power Factory confirms the predicted results by the eigenvalue analysis.     

Experimental studies on homogeneous charge CI engine fueled with LPG using DEE as an ignition enhancer

Producing and using renewable fuels for transportation is one approach for sustainable energy future for the world. A renewable fuel contributes lesser global climate change. The present work reports on the utilization of liquified petroleum gas (LPG) as a primary fuel with diethyl ether (DEE) as an ignition enhancer in a direct injection diesel engine. LPG has a simpler hydrocarbon structure than conventional fuels. DEE is recently reported as a renewable fuel and to be a low-emission high-quality diesel fuel replacement. A single cylinder, four-stroke, water-cooled naturally aspirated DI diesel engine having rated output of 3.7 kW at 1500 rpm was used for the experiments. Measurements were made to study the performance, combustion and emissions characteristics. From the results, it is observed that, the brake thermal efficiency lower by about 23% at full load with a reduction of about 65% NO emission than the diesel operation. The maximum reduction in smoke and particulate emissions is observed to be about 85% and 89%, respectively, when compared to that of diesel operation, however an increase in CO and HC emissions was observed.     

Combined effect of injection timing,EGR and injection pressure in reducing the NOx emission of a biodiesel blend

In this study, an attempt was made to reduce the higher oxides of nitrogen (NO_x) emission of a crude rice bran oil methyl ester (CRBME) blend through modification of combustion process by retarding fuel injection timing and exhaust gas recirculation at an increased fuel injection pressure. At modified condition, delay period and peak pressure of CRBME blend were lower than those at normal condition. The occurrence of maximum heat release rate retarded with a higher magnitude when compared with normal condition. Experimental results show that as a result of combustion modification, NO_x and carbon monoxide emissions were reduced significantly with marginal increase in smoke density. Brake thermal efficiency and unburnt hydrocarbon emissions of the engine were increased significantly as a result of this modification process. This investigation shows that the NO_x emission of a biodiesel blend can be reduced with less sacrifice on smoke density and increase in the brake thermal efficiency by modifying the combustion process.     

Synthesis,characterization, thermal,electrical and electrochemical studies of oligo nitrobenzimidazoles and their p–n diode applications

Three novel nitro oligobenzimidazoles, oligo-2-(6-nitro-1H-benzo[d]imidazol-2-yl)phenol (OBINP2), oligo-3-(6-nitro-1H-benzo[d]imidazol-2-yl)phenol (OBINP3) and oligo-4-(6-nitro-1H-benzo[d]imidazol-2-yl)phenol (OBINP4) were synthesized by oxidative polycondensation of benzimidazole monomers with NaOCl in aqueous alkaline medium. The structure of the monomers and oligomers were confirmed by FT-IR, UV–Vis, ¹H and ¹³C NMR spectroscopic techniques. The monomer BINP2 and its oligomer are showing dual emission through excited state intramolecular proton transfer process. The band gap values of monomers and oligomers were calculated from both UV–Vis spectroscopic and cyclic voltammetric data. Theoretical band gap values of monomers obtained from DFT were compared with experimentally calculated band gap values. The electrical conductivity of I₂ doped and undoped oligomers were measured using two point probe technique and are showing good correlation with the charge densities on imidazole nitrogen obtained from Huckel method. The conductivity of oligomers increases with increase in iodine vapour contact time up to 144 h. The variation of dielectric properties of oligomers has been investigated at different frequency and temperature. Among the oligomers, OBINP3 is having greater thermal stability as evidenced by its high carbine residue of around 65% at 600 °C in thermogravimetric analysis.     

Nanoscale domain switching behaviour in polycrystalline ferroelectric thin films

We report on the nanoscale domain switching behaviour in polycrystalline tetragonal perovskite lead zirconate titanate (PZT) ferroelectric thin films investigated via piezoresponse force microscopy (PFM). Local domain structures were imaged as a function of varying biasing conditions and spatial location of the tip within 50-100?nm sized grains. Nanoscale piezoresponse images provided direct visual evidence of the complex interplay between electrical and mechanical fields in a polycrystalline system, which causes effects such as correlated switching between the grain of interest and neighbouring grains, ferroelastic domain switching, inhomogeneous piezostrain profiles and domain pinning on very minute length scales. Detailed investigations on mechanisms which induce such domain behaviour are presented.