Thermoplastic vulcanizates obtained by reaction-induced phase separation: Interplay between phase separation dynamics,final morphology and mechanical properties

Reaction-induced phase separation (RIPS) of miscible blends of poly(?-caprolactone) (PCL) and an epoxy resin based on poly(propylene oxide) (PPO) was used to prepare thermoplastic vulcanizates (TPVs) with fine rubber dispersions. Scanning electron microscopy (SEM) confirmed the formation of cross-linked rubber particles dispersed in the thermoplastic matrix at PCL contents ≥20 wt%. The morphology development during phase separation was studied by optical microscopy (OM) and time-resolved small-angle light scattering (SALS). It was shown that higher curing temperatures lead to a decrease in rubber particle size, but at the same time lead to an increase in the extent of particle connectivity. In some cases, gelation of the PPO-rich phase limits full structure development, which leads to extensive connectivity between the dispersed rubber particles and a strong deterioration in tensile properties.     

Acute bilateral striatal necrosis in an infant: CT and MRI

We report a case of acute bilateral striatal necrosis in an infant. CT and MRI findings are described.     

A review of the effects of water transfers in the La Grande Hydroelectric Complex (Québec,Canada)

Construction of the La Grande Complex in Eastern Canada called for complete or partial diversion of six rivers, the mean annual discharge of which varied from 60 to 1600 m³ s^?1, and the transfer of water from two adjoining watersheds (1586m³ s^?1) into La Grande Rivière. Three of these rivers with reduced flow, Eastmain (from 700 to 95m³ s^?1), Opinaca (from 260 to 35m³ s^?1), and Caniapiscau (from 1708 to 960m³ s^?1) and the waterways with increased flows, Boyd-Sakami (from 1 to 811m³ s^?1) and La Grande Rivière (from 1760 to 3400m³ s^?1) were intensively monitored from 1978 to 1988, while the others were surveyed sporadically. Very few modifications were observed, compared to previous conditions, in banks stability, water quality, and aquatic fauna of the affected rivers: those which appeared can be explained by the water level fluctuations, the water quality of the tributaries of the residual drainage basin, and/or by the direct influence of the reservoirs. In James Bay, the areal extent of the Eastmain River and La Grand Rivière plumes varied with discharge in an exponential relation, mostly under ice cover; resources from the coastal environment had not yet undergone any major changes. Because of the very small population dwelling in the area, less than 3000 inhabitants, modifications in the hydrological regime of these rivers did cause relatively few impacts, the main being greater banks instability in specific locations, reduction of the thickness and ice cover on La Grande Rivière, enhancement of navigation constraints on Eastmain River, and higher mercury levels in fish related to operation of the reservoirs.     

How Non-native Species in Lake Erie Influence Trophic Transfer of Mercury and Lead to Top Predators

Lake Erie's food web has been dramatically modified by exotic species. Both exotic dreissenid mussels and the round goby Neogobius melanastomus have shifted the food web from a pelagicbased to a benthic-based one, potentially creating a new pathway for contaminant transfer to top predators. Before the invasion of round gobies, few predators of dreissenids occurred in Lake Erie, allowing contaminants to be confined to these benthic organisms. The invasion of the round goby has produced a new pathway through which these contaminants can enter the food web. To characterize heavy-metal transfer through this new food web and to assess risk to humans, water, surficial sediment, dreissenid, round goby, and smallmouth bass Micropterus dolomieui samples were collected at three sites during summers, 2002 and 2003, and analyzed for total lead (Pb), total mercury (Hg), and methyl mercury (MeHg). In addition, we compared smallmouth bass Pb and Hg concentrations to those measured in 1993/1994, before round gobies were prevalent. Pb biodiminished and MeHg biomagnified through the food web to smallmouth bass; patterns were similar among our three sites. Total Pb concentrations in smallmouth bass were higher before the incorporation of round gobies into their diet. We attributed this decline to changes in food web structure, changes in contaminant burdens in prey, or declines in sediment Pb concentrations in Lake Erie. By comparison, Hg concentrations in smallmouth bass changed little, before and after the round goby invasion, possibly due to a shift in diet that increased growth. Despite a decline in sediment Hg concentrations in Lake Erie, smallmouth bass continued to accumulate Hg at historical rates possibly because of their high consumption rates of benthivorous round gobies. As smallmouth bass continue to consume round gobies during their lives, their Hg concentrations may well continue to increase, potentially increasing the risk of Hg contamination to humans.     

Distinction between enzymically and chemically catalyzed interesterification

The 1,3-specific lipase-catalyzed interesterified fats were distinguished from chemically catalyzed products by the fatty acids in the 2-position. The fatty acid contents in the 2-position of the 1,3-lipase-catalyzed and the original triglycerides were similar but different from that of chemically interesterified fat. Also, the saturated-to-unsaturated fatty acid ratio in the 2-monoglycerides was lower for the 1,3-specific lipase-catalyzed interesterified fats than for the corresponding chemical products.     

Transistors made in laser recrystallized polysilicon on insulator films

lpcvd polycrystalline silicon films were deposited on thermally oxidized silicon as well as onlpcvd silicon nitride deposited on silicon. Acw argon ion laser was used to recrystallize the polysilicon film into large grains (grain size from 5μm to 40μm). Boron was then implanted and standard N-channel silicon gate process and N-channel metal gate process were carried out to realisemosfets on this material. Channel mobilities upto 450 cm²/V-sec for electrons have been measured. This thin filmmosfet has a four-terminal structure with a top and a bottom gate and the influence of one gate on the drain current due to the other gate has been investigated. Comparison of theI _D v-V _D curves of the devices with physical models was found in good agreement.     

Evaluation of wear of turning carbide inserts using neural networks

Recent trends, being towards mostly unmanned automated machining systems and consistent system operations, need reliable on-line monitoring processes. A proper on-line cutting tool condition monitoring system is essential for deciding when to change the tool. Many methods have been attempted in this connection.Recently, artificial neural networks have been tried for this purpose because of its inherent simplicity and reasonably quick data-processing capability. The present work uses the back propagation algorithm for training the neural network of 5-3-1 structure. The technique shows close matching of estimation of average flank wear and directly measured wear value. Thus the system developed demonstrates the possibility of successful tool wear monitoring on-line.