Correlation between magnetic hysteresis and magnetic relaxation in YBaCuO single crystals

The dependence of the magnetic momentm obtained from the hysteresis loops on the speed of the magnetic field sweep =dH _ext/dt is explained on the basis of Anderson's interpretation of the magnetic flux creep. In addition, a phenomenological model is suggested which predicts a linear dependence ofm on ln with the slope m/ ln , numerically equal to the relaxation rate m/ ln(t) from the usual magnetic relaxation. Such linear relations betweenm and ln were observed experimentally in single crystals of YBaCuO. Preliminary experiments on the complementary time dependent relaxation ofm after a simulated step change ofH _ext gave mostly relaxation rates close to the predicted values. The model here presented also enables one to compare the critical state in the superconductor at a field sweep rate with the critical state at some timet _eff after a step change ofH _ext. The values of analyzed in our experiments actually correspond to the critical state at timest _eff between0.04 and4 sec after an imaginary large step change ofH _ext.     

Scientometric analysis of the research activities of chemists from the “Rugjer Bošković” Institute (Yugoslavia), 1976–1985

The research activity of chemists from the Rugjer Bokovi Institute (RBI, Zagreb, Yugoslavia) was analyzed for the period 1976–1985, covering 2018 research years of scientific work, and 1149 SCI registered papers (0.57 publications per research year). At the average, one paper was published by 3.05 scientists. The papers were published in 235 different journals, most frequently is the nationalCroatica Chemica Acta (171 papers). The publications were divided into two groups: for the periods 1976–1980 and 1981–1985, and for each paper citations were collected in the respective time period. An average publication had 2.58 citations. Chemical papers from the second period had 2.73 citations per paper, which is 85% of the expected value, and this was considerably more than for Yugoslav papers (66%) in general. The papers were classified according to the subfields used in theJournal Citation Reports, and the results compared with the data published bySchubert, Glänzel andBraun. The distribution of citations was also analyzed.     

A study of Nd2Fe14B and a neodymium-rich phase in sintered NdFeB magnets

The microstructure and properties of NdFeB sintered permanent magnets were analysed by different methods. Samples analysed were sintered and thermally treated. The hard magnetic Nd₂Fe₁₄B phase and amorphous neodymium-rich phase were observed by TEM. The neodymium-rich phase contained iron and boron, in elemental and in B₂O₃ form, which is known as a glass former. At the sintering temperature, Nd₂Fe₁₄B and the neodymium-rich phase are supersaturated with iron, which should be dissolved at the annealing temperature to react with neodymium and boron and form additional Nd₂Fe₁₄B phase. Iron precipitates of size up to 2 nm were detected in the Nd₂Fe₁₄B phase. These superparamagnetic precipitates of -Fe could affect the hard magnetic properties of NdFeB magnets.     

Carcass traits and meat quality of male lambs fed monensin or lasalocid

Male lambs, crossbred Merino × Ille de France, were fed a diet supplemented with 31 mg monensin or 32 mg lasalocid per kg of feed dry matter from an initial body weight of 23·6–23·9 kg to the slaughter weight of approximately 40 kg.

Carcass traits and meat quality were evaluated after slaughter; the values obtained were compared with those of the control group fed the same diet without the ionophore supplement.

There were few significant differences among the individual groups in carcass value, sensoric and technological properties of meat and of its composition. However, the lasalocid-fed group seemed to be somewhat better in muscling and in the composition of meat.     

Frequency dependence of the spin-fluctuation spectrum in Pd: Calculations within the finite bandwidth model

The frequency dependence of the electron-paramagnon spectrumP() in Pd is calculated within the finite bandwidth model. It is found that for an almost full band, the magnitude, the range, and the position of the peak frequency inP() are dramatically reduced compared to their values in the usual paramagnon theory. Also, we find that the frequency dependence of the spin-fluctuation contribution to the electron self-energy is strongly affected by a close proximity of the Fermi level to the top of the band. We speculate that an unusually large value of the Coulomb pseudopotential is probably partially responsible for the absence of superconductivity in Pd.     

Synthesis and characterization of phenolic and amino resins based on α, β-unsaturated aldehydes

Phenolic and amino resins on the basis of α,β-unsaturated aldehydes were synthesized in bulk or solution. Catalysts were HCl, H₃PO₄, or formic acid, and in some cases NaOH. The course of the reactions was followed by GPC and NMR while the structure of the reaction products was determined by one- and two-dimensional NMR. The course of the reactions is influenced by experimental conditions: the type of monomers, their molar ratio, the type and quantity of the catalyst, the reaction time and temperature, and the reaction medium. At the beginning of the reaction the addition of a nucleophile to an aldehyde takes place through parallel 1,2-addition to and 1,4-addition to group. Oligomers with ? OH, , and ? CHO functional groups are able to add new monomer units or to react mutually to form higher molecular weight addition and condensation products. The overall rate constants for the beginning of the reactions were between 10^?3 L/mol s for the high reactive mixtures and 10^?7 L/mol s for the less reactive mixtures. The resins were cured by heating at temperatures above 135°C with the addition of hexamethylenetetramine.     

Formation of oxide phases in the system Fe2O3−Gd2O3

The formation of oxide phases in the system (1 -x) Fe₂O₃ +xGd₂O₃ was investigated for 0 x 1. On the basis of XRD measurements the distribution of oxide phases, -Fe₂O₃, Gd₃Fe₅O₁₂, GdFeO₃ and Gd₂O₃ was determined, as a function ofx. No solid solutions were observed with certainty even at the very ends of the concentration range. This was also confirmed by⁵⁷Fe Mössbauer spectroscopy. New accurate crystallographic data for Gd₃Fe₅O₁₂ are given. The formation of oxide phases in the system Fe₂O₃- Gd₂O₃ is compared with the data for analogous system Fe₂O₃-Eu₂O₃.     

Magnetic pinning in inhomogeneous type II superconductors

The magnetic structure of a vortex in the presence of an anisotropic inhomogeneity distribution is calculated within the London model. The anisotropic supercurrent pattern consists of closed current loops, superimposed on a backflow pattern. The nonvanishing current density at the vortex core gives rise to an intrinsic Lorentz force identical with the pinning force resulting from the spatial variation of the vortex self-energy.