Topological evolution of laminar juncture flows under different critical parameters

Horseshoe vortex topological structure has been studied extensively in the past, traditional “saddle of separation” and new “attachment saddle point” topologies found in literature both have theoretical basis and experimental and computational evidences for support. The laminar incompressible juncture flows at low Reynolds numbers especially are observed to have new topology. Studies concerning the existence of the new topology though found in literature, the topological evolution and its dependency on various critical flow parameters require further investigation. A Particle Image Velocimetry based analysis is carried out to observe the effect of aspect ratio, δ*/D and shape of the obstacle on laminar horseshoe vortex topology for small obstacles. Rise in aspect ratio evolves the topology from the traditional to new for all the cases observed. The circular cross section obstacles are found more apt to having the new topology compared to square cross sections. It is noted that the sweeping effect of the fluid above the vortex system in which horseshoe vortex is immersed plays a critical role in this evolution. Topological evolution is observed not only in the most upstream singular point region of horseshoe vortex system but also in the corner region. The corner vortex topology evolves from the traditional type to new one before the topological evolution of the most upstream singular point, resulting in a new topological pattern of the laminar juncture flows “separation-attachment combination”. The study may help extend the understanding of the three-dimensional boundary layer separation phenomenon.     

Geological Engineering,Civil Engineering,Traffic and Transportation Engineering Electrical capacitance volume tomography for measurement soil water infiltration in vessel experiments简

Electrical capacitance volume tomography （ECVT） is a recently-developed technique for real-time, non-invasive 3D monitoring of processes involving materials with strong contrasts in dielectric permittivity. This work is first application of the method to visualization of water flow in soil. We describe the principles behind the method, and then demonstrate its use with a simple laboratory infiltration experiment. 32 ECVT sensors were installed on the sides of an empty PVC column. Water was poured into the column at a constant rate, and ECVT data were collected every second. The column was then packed with dry sand and again supplied with water at a constant rate with data collected every second. Data were analyzed to give bulk average water contents, which proved consistent with the water supply rates. Data were also analyzed to give 3D images （216 voxels） allowing visualization of the water distribution during the experiments. Result of this work shows that water infiltration into the soil, wall flow, progress of the unstable wetting front and the final water distribution are clearly visible.     

Computationally efficient 2D beamspace matrix pencil method for direction of arrival estimation

In this paper, we propose a new 2-dimensional beamspace matrix pencil (2D BMP) method for direction of arrival (DOA) estimation of plane wave signals using a uniform rectangular array (URA). Based on some a priori information about DOA, the proposed method transforms the complex signal subspace in 2D matrix pencil (2D MP) method [Y. Hua, Estimating two-dimensional frequencies by matrix enhancement and matrix pencil, IEEE Trans. Signal Process. 40 (9) (1992) 2267–2280] into a real and reduced dimensional beamspace using the discrete Fourier transform (DFT) matrix transformation. Consequently, the computational complexity is reduced (several times) in comparison with 2D MP method. Computer simulations are provided to show that 2D BMP method gives comparable performance in terms of average mean square error of the estimated DOA with lesser floating point operations as compared to the existing (MP) methods.     

A Flavanone and Two Phenolic Acids from Chrysanthemum morifolium with Phytotoxic and Insect Growth Regulating Activity

Leaves of Chrysanthemum morifolium cv. Ramat were extracted sequentially with hexane, ethyl acetate, and methanol. The methanol fraction, when incorporated into artificial diet was found to reduce the growth of cabbage looper (Trichoplusia ni Hubner) larvae at concentrations between 500 and 5000 ppm of diet. Fractionation of the methanol extract on a Sephadex column yielded five fractions, three of which reduced the weight of larvae relative to the control. One fraction was analyzed using high performance liquid chromatography (HPLC) and found to contain three main constituents. These compounds were purified using a combination of gel permeation chromatography on Sephadex LH20 and HPLC, and analyzed by 1H and 13CNMR as well as undergoing chemical and physical analyses. The compounds were identified as: 1, chlorogenic acid (5-O-caffeoylquinic acid); 2, 3,5-O-dicaffeoylquinic acid; and 3, 3', 4',5-trihydroxyflavanone7-O-glucuronide (eriodictyol7-O-glucuronide). At concentrations between 100 to 1000 ppm these compounds reduced both growth and photosynthesis of Lemna gibba L. with the order of efficacy being: flavanone > chlorogenic acid > 3,5-O-dicaffeoylquinic acid. Furthermore, when incorporated separately into artificial diet these compounds, at 10 to 1000 ppm, enhanced or reduced growth of the cabbage looper (Trichoplusia ni) and gypsy moth (Lymantria dispar L.).     

Novel Organometallic Aromatic Azo Polyesters Based on Ferrocene

Some ferrocene containing aromatic azo polyesters were prepared by condensing 1,1-ferrocenedicarbonyl chloride with different azo groups containing aromatic diols, which were synthesized by diazotization coupling reaction from aromatic diamines. The polymeric products were separated as two portions on the basis of their solubility and subsequently characterized by their elemental analysis and FTIR spectral studies. Thermal properties of the products were measured by differential scanning calorimetry and thermogravimetry and the activation energies of pyrolysis were calculated using Horowitz and Metzger's method. The molecular weights of the soluble portions were determined by gel permeation chromatography (GPC) and these portions were also characterized by their inherent viscosities and UV-Vis spectroscopic studies.     

Asymmetric Sharpless epoxidation of 13S‐hydroxy‐ 9Z, 11E‐octadecadienoic acid (13S‐HODE)

The asymmetric Sharpless epoxidation of methyl 13S‐hydroxy‐9Z, 11E‐octadeca‐dienoate (13S‐HODE, 1 ) with tert‐butyl hydroperoxide (TBHP) catalysed by titanium tetraisopropoxide {Ti(ⁱOPr)₄} in the presence of L(+)‐diisopropyl tartrate (L‐DIPT) gave methyl 13S‐hydroxy‐11S, 12S‐epoxy‐9Z‐octadecenoate 2 (erythro isomer) in 84% diastereomeric excess (de). The epoxidation of 1 with TBHP catalysed by Ti(ⁱOPr)₄ in the presence of D(‐)‐DIPT yielded methyl 13S‐hydroxy‐11RR12R‐epoxy‐9Z‐octadecenoate (threo isomer) 3 in 76% de.     

Synergistic electronic and geometric effects of Au/CeO2 catalyst for oxidative esterification of methacrolein

Methyl methacrylate (MMA) is an important monomer for the production of acrylic plastics and polymer dispersions. In this study, we demonstrate a strategy to synergize the electronic and geometric effects of the Au/CeO₂ catalyst, achieving three orders of magnitude improvement in reaction rate for the oxidative esterification of methacrolein to MMA. The electronic properties of Au in terms of the valence electron population of 5d states are decoupled from the redox ability and acid–base properties of catalyst support as the main cause for the significant increase in the specific activity of the active site. Moreover, the Au edge site is identified as the main active site for this reaction, whose number reaches the maximum for the 1.6 nm-sized Au particles. Hence, the synergism between the electronic (lower valence electron population of 5d states) and geometric (more edge active sites) promotions of the Au-10/CeO₂ catalyst contributes to the highest catalytic activity.     

Numerical modelling of rotating packed beds used for CO2 capture processes: A review

Over the last decades, renewable and clean energy sources are being rigorously adopted along with carbon capture technologies to tackle the increasing carbon dioxide (CO₂) concentration level in the environment. CO₂ capture is a quintessential option for tackling global warming issues. In this context, the present paper has reviewed the process intensification equipment called a rotating packed bed (RPB), which is highly industry applicable due to high gravity (HiGee) force. This facilitates strong mass transfer characteristics, a compact design, and low energy consumption. In this review, the current research scenario of RPBs using numerical, computational fluid dynamics (CFD), and mathematical modelling, along with different machine learning approaches in the CO₂ capture process, has been reviewed. The different geometry designs, hydrodynamic characteristics, performance parameters, research methods, and their effects on CO₂ removal efficiency have been discussed. Furthermore, the latest experimental studies are also summarized, especially in the absorption and adsorption domain. Finally, recommendations have been given to support the RPBs in different industrial and commercial applications of CO₂ removal.     

HYDROMAGNETIC UNSTEADY RIVLIN-ERICKSEN THIRD-GRADE FLOW FOR STOKES' SECOND PROBLEM

In this article, the flow of an unsteady third-grade Rivlin-Ericksen fluid on an oscillating plate is discussed. The magnetic lines of force act perpendicular to the flow field. Several interesting features of the flow are obtained. The physical interpretation of the second-grade parameters, third-grade parameters, oscillating frequency, and magnetohydrodynamic parameters are examined graphically and then are deduced to already known results in the literature.     

Advances in Polymer-based Nanostructured Membranes for Water Treatment

Water pollution has become the most severe dilemma in the entire world. In this review, we have discussed the advancement in preparation and properties, plus background and challenges regarding polymer-based nanocomposite membranes. Nanofiltration thin film composite membranes have been given tremendous attention over last two decades relative to conventional systems in desalination of sea water, waste water from industries and ultra pure water production etc. In recent years, significant research efforts have been devoted towards the development of high-performance membranes through surface modification of polymers and nanoparticles, nanotubes, etc. to achieve appreciable salt rejection, water flux and antifouling properties.