T型接头TOFD检测时缺陷深度的定位计算与评判

讨论了在T型接头TOFD检测时如何建立模拟等腰三角形,以适应仪器内置的深度定位计算程序.介绍了显示深度与实际深度的修正计算方法,并通过计算显示深度测量值与计算值的误差,验证了上述计算方法的准确性.最后,通过对T型接头试块检测结果的分析,探讨了T型接头翼板未熔合、腹板未熔合及角焊缝内缺陷的评判规律.     

农作物秸秆缓冲包装材料的研制

研究了以农作物秸杆为主要原料制备缓冲包装材料,结果表明：利用玉米秸杆的芯部为主要原料,选择合适的粘合剂;通过模压成型工艺,能够得到性能良好的缓冲包装材料。影响玉米秸杆缓冲包装材料性能的因素主要有粘合剂、预处理和粒径等。开展该研究对保护环境、节约矿物资源、增加农民收入具有重要的意义。     

现场录井资料数字化处理系统的研究与开发

为适应"数字化油田"建设的需要,解决录井源头数据信息化处理、信息入库和信息共享问题,阐述了将计算机技术和网络传输技术与录井专业技术有机结合进行实时数据处理、传输与共享的途径,改变了数据重复录入和图、表手工绘制等传统方式,实现了数据一次录入,重复使用,保证了数据的一致性,提高了数据的利用效率.在阐述系统结构的基础上,介绍了系统录入编辑模块、报表生成模块和图件绘制模块的功能、技术特色以及数据远程传输的原理、方法和实现方式,提出了实现数据网络化的安全保障措施.该系统的研究与开发对加快油田信息化建设具有重要的推动作用.     

Si-RE复合合金化对AZ31镁合金显微组织及力学性能的影响

采用Si-RE元素对AZ31镁合金进行复合微合金化,利用光学显微镜(OM)、扫描电镜(SEM)、X射线衍射仪(XRD)及拉伸实验仪等手段研究Si-RE元素对AZ31镁合金的微观组织和力学性能的影响规律。结果表明,Si-RE复合加入可以明显细化AZ31镁合金的铸态组织,β-Mg17Al12相也由网状分布变为颗粒状,同时生成了短棒状和针状的Mg2Si相及Al11RE3相;合金的综合力学性能显著改善,AZ31+0.4%Si+0.5%RE的强度和延伸率比原始AZ31镁合金分别提高了42MPa和3.9%,试样室温拉伸断口虽然是以解理为主的脆性断裂,但断口中出现了少量的韧窝,解理面也较小。     

低价钒－锯氧化物系的相关系和电导率

研究了Ｓｒ－Ｖ－Ｏ系统内低价钒氧化物存在时的相关系．用Ｘ光衍射分析鉴定了相组成，并用标准直流四探针法测定了１００～１０００Ｋ温度范围内的组成相的电阻率．结果表明在该系统内，在还原气氛下形成的低价钒化合物有六方的Ｓｒ８Ｖ８Ｏ（２５），立方的Ｓｒ２Ｖ２Ｏ５和Ｖ２Ｏ３，三者在１５０Ｋ以上均具有１０ｏ～１０１Ω·ｃｍ的电阻率．Ｖ２Ｏ３相在低于１５０Ｋ附近电阻率有一个约１０４数量级的跃升，显示了在降温时由导电性向绝缘性的突变．     

Graphene‐Bonded and ‐Encapsulated Si Nanoparticles for Lithium Ion Battery Anodes

Silicon (Si) has been considered a very promising anode material for lithium ion batteries due to its high theoretical capacity. However, high‐capacity Si nanoparticles usually suffer from low electronic conductivity, large volume change, and severe aggregation problems during lithiation and delithiation. In this paper, a unique nanostructured anode with Si nanoparticles bonded and wrapped by graphene is synthesized by a one‐step aerosol spraying of surface‐modified Si nanoparticles and graphene oxide suspension. The functional groups on the surface of Si nanoparticles (50–100 nm) not only react with graphene oxide and bind Si nanoparticles to the graphene oxide shell, but also prevent Si nanoparticles from aggregation, thus contributing to a uniform Si suspension. A homogeneous graphene‐encapsulated Si nanoparticle morphology forms during the aerosol spraying process. The open‐ended graphene shell with defects allows fast electrochemical lithiation/delithiation, and the void space inside the graphene shell accompanied by its strong mechanical strength can effectively accommodate the volume expansion of Si upon lithiation. The graphene shell provides good electronic conductivity for Si nanoparticles and prevents them from aggregating during charge/discharge cycles. The functionalized Si encapsulated by graphene sample exhibits a capacity of 2250 mAh g^?1 (based on the total mass of graphene and Si) at 0.1C and 1000 mAh g^?1 at 10C, and retains 85% of its initial capacity even after 120 charge/discharge cycles. The exceptional performance of graphene‐encapsulated Si anodes combined with the scalable and one‐step aerosol synthesis technique makes this material very promising for lithium ion batteries.     

制备工艺条件对SiO2气凝胶微球粒径及其均匀性的影响

为拓展SiO2气凝胶的应用范围,克服SiO2气凝胶微球制备技术中的不足,采用搅拌成球工艺以水玻璃为硅源在单一油相中制备了直径为2～1500μm的SiO2气凝胶微球,并研究了制备工艺条件对其粒径大小及均匀性的影响.研究结果表明,各个工艺条件之间互相关联和影响,成胶时间起着关键作用.当成胶时间适中或较长时,工艺条件中只有搅拌速度对粒径大小影响显著,同时所有工艺条件都对粒径的均匀性无明显影响;而成胶时间较短时,任一工艺条件的改变都会使粒径大小及均匀性发生变化.     

钛酸锶基粉体功能材料的合成与应用研究进展

钛酸锶作为一种典型的钙钛矿型结构物质,具有介电损耗低、热稳定性好和光催化性能优良等特点,是一种用途广泛的功能陶瓷材料。综述了近年来以钛酸锶为基体各种功能陶瓷材料的合成方法与重要应用,并探讨了其今后的主要发展方向。     

Preparation and characterization of magnetic poly(ε-caprolactone)-poly(ethylene glycol)-poly(ε-caprolactone) microspheres

In this article, nano-magnetite particles (ferrofluid, Fe₃O₄) were prepared by chemical co-deposition method. A series of biodegradable triblock poly(ε-caprolactone)-poly(ethylene glycol)-poly(ε-caprolactone) (PCL-PEG-PCL, PCEC) copolymers were synthesized by ring-opening polymerization method from ε-caprolactone (ε-CL) initiated by poly(ethylene glycol) diol (PEG) using stannous octoate as catalyst. And the magnetic PCEC composite microspheres were prepared by solvent diffusion method. The properties of the ferrofluid, PCEC copolymer, and magnetic PCEC microspheres were studied in detail by SEM, VSM, XRD, Malvern Laser Particle Sizer, ¹H-NMR, GPC, and TG/DTG. Effects of macromolecular weight and concentration of polymer, and the time for ultrasound dispersion on properties of magnetic microspheres were also investigated. The obtained magnetic PCEC microspheres might have great potential application in targeted drug delivery system or cell separation. This work was financially supported by Chinese Key Basic Research Program (2004CB518800 and 2004CB518807), and Sichuan Key Project of Science and Technology (06(05SG022-021-02)). Qian ZY and Wang H did the even work with Gou ML, and are the co-first authors for this paper.