月表环境无线电波传播分段预测模型

针对经典无线电波传播模型不适用于月球特殊的传播环境问题,提出一种月表环境下电波传播损耗分段预测模型。该模型首先建立包含自由空间段、月面反射段和月球绕射段的理想分段预测模型,并给出不同区间内传播损耗预测算法,然后考虑传播路径剖面上多重障碍物导致的额外损耗,以及其对分段区间参数的修正方法。将其应用于美国国家航天局提供的月表实际场景,仿真结果表明该模型预测结果与“阿波罗”登月工程获得的实测数据非常吻合,可用于辅助月表无线通信系统的参数设计和性能评估。     

基于System Generator的内插位同步法

针对数字接收机中如何全数字地实现位同步,设计了一种内插位同步法。利用内插与Gardner算法相结合的原理设计位同步,通过System Generator进行建模仿真,并直接生成代码下载到FPGA实现位同步。利用QPSK信号进行仿真分析,FPGA硬件协同仿真进行验证。实验结果表明,内插位同步法具有很好的位同步效果。     

Effect of SiO2 on rheology,morphology, thermal,and mechanical properties of high thermal stable epoxy foam

A series of highly thermostable epoxy foams with diglycidyl ether of bisphenol‐A and bisphenol‐S epoxy resin (DGEBA/DGEBS), 4,4′‐diaminodiphenyl sulfone (DDS) as curing agent have been successfully prepared through a two‐step process. Dynamic and steady shear rheological measurements of the DGEBA/DGEBS/DDS reacting mixture are performed. The results indicate all samples present an extremely rapid increase in viscosities after a critical time. The gel time measured by the crossover of tan δ is independent of frequency. The influence of SiO₂ content on morphology, thermal, and mechanical properties of epoxy foams has also been investigated. Due to the heterogeneous nucleation of SiO₂, the pore morphology with a bimodal size distribution is observed when the content of SiO₂ is above 5 wt %. Dynamic mechanical analysis (DMA) reveals that pure epoxy foam possesses a high glass transition temperature (206°C). The maximum of specific compressive strength can be up to 0.0253 MPa m³ kg^?1 at around 1.0 wt % SiO₂. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 40068.     

空心玻璃微珠复合聚氨酯泡沫的模塑成型收缩率

研究了用空心玻璃微珠复合聚氨酯泡沫塑料制成厚度不同、形状不同、结构不同的制品时模型成型的收缩率，以及在模塑成型过程中，熟化温度、熟化时间和熟化后在模具内保持的时间对模塑成型收缩率的影响。结果表明，制品模塑成型收缩率随着厚度的增加而增大；加入金属嵌件后可较大程度地限制制品收缩；当熟化温度高于100℃时，随着熟化温度的升高，制品收缩率增大。     

ECR微波等离子体对单晶金刚石表面的碳纳米墙修饰

利用电子回旋共振(ECR)微波等离子体,在CH₄/H₂体系下,对高温高压单晶金刚石表面进行了碳纳米墙修饰。通过等离子体发射光谱研究ECR等离子体内基团的谱线强度在不同工作气压、CH₄浓度下的变化规律,结合扫描电子显微镜对单晶金刚石表面的微观形貌进行分析,进一步研究了工作气压和CH₄浓度对碳纳米墙修饰结果的影响。结果表明:碳纳米墙的取向性受工作气压影响大,低气压(0.07 Pa)条件下生长的碳纳米墙垂直取向明显,金刚石表面也出现垂直刻蚀形貌;在高气压(5 Pa)条件下生长的碳纳米墙取向性较差。同时,碳纳米墙生长的临界CH₄浓度也与工作气压有关:低气压条件下碳纳米墙生长的临界CH₄浓度高,工作气压为0.07 Pa时,碳纳米墙生长的临界CH₄浓度为3%;工作气压升至5 Pa时,碳纳米墙生长的临界CH₄浓度降为1%,碳纳米墙密度随CH₄浓度升高而增大。      

Evaluating the Pore Structures of Polysulfone Membranes by Positron 3<Emphasis Type="Italic">γ</Emphasis>-Annihilation Probability and Electrochemical Impedance Spectroscopy

A series of polysulfone membranes with different porous structures were prepared via phase inversion method. These membranes were examined by electrochemical impedance spectroscopy (EIS), the positron annihilation technique, and water flux measurement. EIS and water flux results confirmed that the membranes exhibited more tunnels for the permeation of ions or water molecules with increasing polyethylene glycol (PEG) content. The positron results (evaluated by the R parameter) exhibited lower values at PEG contents higher than 1 wt%, which seemed to be inconsistent with the general positron results, because usually a lower R parameter is found for dense structures while a higher R parameter for porous structures. The inconsistency could be attributed to the combination of pores in the studied membranes. This suggests that the R parameter could be promisingly utilized to probe the evolution of the pores in membranes.     

复合混凝剂处理石油化工二级出水的研究

考察了不同混凝剂对石油化工生化出水的混凝效果,并针对不同混凝剂的特性复配,对复配组分的种类、加量、pH、混凝沉降时间进行了研究,同时通过预制絮体实验对复合混凝剂去除有机物的机理进行了探讨。结果表明,复合混凝剂PFAC+FC+AC+PAM比单独的混凝剂处理效果有显著的提高,该体系最佳混凝条件为pH=5.0、PFAC加量为150mg/L、m(FeCl3)∶m(AlCl3)=9∶1(总量保持50mg/L)、沉降时间为1h。在此条件下TOC去除率高达40.39%,处理后TOC降至15.51mg/L,水质达到污水综合排放标准的一级标准(GB 8978—1996);电中和和络合吸附是混凝过程中有机物的主要去除机理。     

功能梯度类金刚石薄膜的脉冲激光制备

长期以来 ,高质量的纯类金刚石薄膜的成功制备一直受其巨大内部压应力的阻碍 ,因为这种压应力导致严重的附着问题。厚度大于 50 0nm的类金刚石薄膜中的压应力常使薄膜与基体剥离。作者采用功能梯度的设计概念 ,应用准分子脉冲激光沉积方法 ,成功制备了厚度超过 1 0 μm的高质量类金刚石薄膜。薄膜中的SP3碳原子含量超过 6 0 %。纳米硬度测试表明 ,薄膜的弹性模量高达 50 0GPa ,纳米硬度高达 6 0GPa ,薄膜与基体间附着良好。证明功能梯度的设计概念可以用于制备较厚的超硬类金刚石薄膜。