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An alkali‐soluble, photocrosslinkable polymer was synthesized by esterification of OH groups of acrylic phenolic resin with maleic anhydride. The OH groups were formed by the ring‐opening reaction of epoxy groups of epoxy phenolic resin with acrylic acid. The esterification conditions were studied. The results showed that it is better to use tetramethyl ammonium bromide as catalyst than N,N‐dimethylbenzylamine. The conversion of maleic anhydride in acetone can reach about 80% at 56°C for 4 h. The purified product was characterized by IR, DSC, and TGA. The product containing acrylate and maleic acid monoester groups, above a certain content, can be dissolved in 1% Na2CO3 solution. The photocrosslinkable properties of the product were investigated through selection of photoinitiator, accelarator, crosslinkable diluent monomer, etc. The acrylate and maleic acid monoester group‐containing phenolic resin exhibited very good photocrosslinking behavior, since it contains double bonds from both acrylate groups and maleic acid monoester groups. The activity of photoinitiator decreases in the order: isopropylthioanthraquinone > benzoin ethyl ether (BE) > anthraquinone (AQ) > benzophenone > Michel ketone (MK) > 2,2‐diethoxyacetophenone. The combination of some photoinitiators showed synergistic effects. The order of increasing activity for the accelerator is as follows: MK > ethyl p‐(dimethylamino)benzoate > N,N‐dimethylaniline > triethanolamine. The optimum diluent monomer is trimethylolpropane trimethacrylate. The gel content of the mixture of the resin and trimethylolpropane trimethacrylate could reach 85% using the combined photoinitiators of BE and AQ under UV exposure for 120 s. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 98: 1607–1614, 2005 相似文献
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三氧化二钕催化制备尼泊金乙酯 总被引:11,自引:0,他引:11
研究了以三氧化二钕为固体催化剂,由对羟基苯甲酸和乙醇合成尼泊金乙酯。讨论了影响酯化反应的因素,与大孔阳离子交换树脂和Fe2(SO4)3·XH2O相比,三氧化二钕用量少,是对酸的6%,反应时间短,只需4h,反应温度低,不超过90℃,可循环使用,产率较高,对环境和产品无污染等。 相似文献
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Ying Quan Mingshan Yang Tongxiang Liang Qin Yan Deshan Liu Riguang Jin 《应用聚合物科学杂志》2007,103(6):3940-3949
Novel composite particles based on nanoscale calcium carbonate (nano‐CaCO3) as the core and polyacrylates as the shell were first synthesized by in situ encapsulating emulsion polymerization in the presence of the fresh slush pulp of calcium carbonate (CaCO3) nanoparticles. Subsequently, these modified nanoparticles were compounded with rigid poly(vinyl chloride) (RPVC) to prepare RPVC/CaCO3 nanocomposites. At the same time, the effects of the reinforcement and toughening of these modified nanoparticles on RPVC were investigated, and the synergistic effect of modified nanoparticles with chlorinated polyethylene (CPE) was also studied. The results showed that in the presence of nano‐CaCO3 particles, the in situ emulsion polymerization of acrylates was carried out smoothly, and polyacrylates successfully encapsulated on the surface of nano‐CaCO3 to prepare the modified nanoparticles, breaking down nano‐CaCO3 particle agglomerates, improving their dispersion in the matrix, and also increasing the particle–matrix interfacial adhesion. Thus, the effects of the reinforcement and toughening of these modified nanoparticles on RPVC were very significant, and the cooperative effect of the nanoparticles with CPE occurred in the united modification system. Scanning electron microscopy analyses indicated that large‐fiber drawing and network morphologies coexisted in the system of joint modification of nanoparticles with CPE. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 103: 3940–3949, 2007 相似文献
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A novel method for the preparation of a quaternary ammonium ionomer of styrene–butadiene–styrene triblock copolymer (SBS) was developed by a ring‐opening reaction of epoxidized SBS with triethylamine hydrochloride in the presence of a phase transfer catalyst. The optimum conditions were studied. The ionomer was characterized by quantitative analysis, IR spectroscopy, and 1H‐NMR spectroscopy. Its water absorbency, oil absorbency, dilute solution viscosity, and use as a compatibilizer for the blending of SBS and chlorosulfonated polyethylene (CSPE) were investigated. The results showed that, under optimum conditions, the epoxy groups can be completely converted to the quaternary ammonium groups. The IR spectrum did not exhibit the absorption peak for quaternary ammonium groups, whereas the 1H‐NMR spectrum and titration method demonstrated it. With increasing ionic group content, the water absorbency of the ionomer increased whereas its oil absorbency decreased. These indicated the amphiphilic character of the SBS ionomer. The dilute solution viscosity of the ionomer in toluene/methanol (9/1) solvent increased with increasing quaternary ammonium group content. The ionomer was used as a compatibilizer for the blends of SBS and CSPE. The addition of a small amount of the ionomer to the blend enhanced the mechanical properties of the blends: 2 wt % ionomer based on the blend increased the tensile strength and ultimate elongation of the blend nearly 2 times. The blends of equal parts SBS and CSPE behaved as oil‐resistant thermoplastic elastomers. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 99: 1975–1980, 2006 相似文献
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Brief review of the evolutive course of preparation and refining of mother liquor in Hou's soda-manufacturing Process and the historical root of inferior quality of the product from Hou's Process to that of Ammonium Soda Process. By determination in production, the technical causes of carrying of "escaping crystal" in flooding liquid from the salting out crystallizer and necessity of replacing the existing mother liquor Ⅱ vat by mother liquor Ⅱ settling tank. Theoretical and engineering basis of refining of mother liquor in Hou's Process is emphasized. Main results from field test of purification and filtration at low temperature of mother liquor Ⅱ prepared from three kinds of salt as raw material are introduced. Principle opinions of application on production are put forward. 相似文献
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该文侧重于学术期刊定性属性的评价方法研究。学术期刊定性属性特征通常具有模糊性,因而往往需要由专家给出主观判断。通过建立基准语言等级评价集合,提出了将专家给出的关于各定性属性的主观评价信息规范化为基准语言等级评价集合并集成的综合评价方法。最后通过计算可以得到学术期刊的综合评价值,进而使得学术期刊评价尽可能的公平化。 相似文献