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111.
Nicolas Verplanck Yannick Coffinier Vincent Thomy Rabah Boukherroub 《Nanoscale research letters》2007,2(12):577-596
The wetting properties of superhydrophobic surfaces have generated worldwide research interest. A water drop on these surfaces
forms a nearly perfect spherical pearl. Superhydrophobic materials hold considerable promise for potential applications ranging
from self cleaning surfaces, completely water impermeable textiles to low cost energy displacement of liquids in lab-on-chip
devices. However, the dynamic modification of the liquid droplets behavior and in particular of their wetting properties on
these surfaces is still a challenging issue. In this review, after a brief overview on superhydrophobic states definition,
the techniques leading to the modification of wettability behavior on superhydrophobic surfaces under specific conditions:
optical, magnetic, mechanical, chemical, thermal are discussed. Finally, a focus on electrowetting is made from historical
phenomenon pointed out some decades ago on classical planar hydrophobic surfaces to recent breakthrough obtained on superhydrophobic
surfaces. 相似文献
112.
Sabine Szunerits Sami Abou Rich Marie-Angélique Languille Rabah Boukherroub 《Electrochimica acta》2008,53(11):3910-3915
The paper reports on the preparation and characterization of organosilicon thin polymer films deposited on glass slides coated with 5 nm adhesion layer of titanium and 50 nm of gold. The polymer was obtained by the decomposition of 1,1,3,3-tetramethyldisiloxane precursor (TMDSO) premixed with oxygen induced in a N2 plasma afterglow using remote plasma-enhanced chemical vapor deposition (PECVD) technique. The film thickness was controlled by laser interferometry and was 9 nm. The chemical stability of the gold substrate coated with the organosilicon polymer film (p-TMDSO) was studied in different acidic and basic solutions (pH 1-14). While the gold/polymer interface showed a high stability in acidic media, the film was almost completely removed in basic solutions. The resulting surfaces were characterized using atomic force microscopy (AFM), X-ray photoelectron spectroscopy (XPS), water contact angle measurements, cyclic voltammetry, and surface plasmon resonance (SPR). 相似文献
113.
Two laboratory scale fluidized-bed biofilm reactors (FBBRs) were used to investigate the biomass concentration and the biofilm characteristics in a high performance FBBR used for the denitrification of exceptionally high-nitrate wastewater (1000 mg-N/L). Reported correlations by other workers for predicting the biomass concentration in FBBR were examined for their validity in comparison with the experimental results of this study and the best set of applicable correlations was recommended. The effects of the two main operational parameters, the superficial velocity and nitrogen loading rate on the biomass concentration in the FBBR were also studied. Correlations for the drag coefficient and the expansion index from the literature, together with the biofilm dry density correlation produced from this study were found to produce the best prediction of the FBBR biomass concentration compared to other reported correlations. The average biomass concentration in the FBBR decreased with the increase of the superficial velocity in the range of 45 to 65 m/h at all the applied nitrogen loadings (i.e. 6, 8, 12 and 16 kg-N/m3(bed).d). 相似文献
114.
Laurent Djakovitch Vronique Dufaud Rabah Zaidi 《Advanced Synthesis \u0026amp; Catalysis》2006,348(6):715-724
Heterogeneous palladium catalysts ([Pd(NH3)4]2+/NaY and [Pd]/SBA‐15) were applied to the synthesis of 2‐functionalised indoles, giving generally high conversions and selectivities (>89% yield) using only 1 mol % [Pd]‐catalyst under standard reaction conditions (polar solvent, 80 °C). For the synthesis of 2,3‐functionalised indoles by cross‐coupling arylation, the [Pd]/SBA‐15 catalyst was found to be particularly interesting, producing the expected compound with =35% yield after 12 days of reaction, which is comparable to the homogeneous catalyst, Pd(OAc)2 (=48% yield). In the course of the study, the dual reactivity of the indole nucleus was demonstrated: aryl bromides gave clean C C coupling while aryl iodides led to a clean C N coupling. 相似文献
115.
SE Barbour C Wong D Rabah A Kapur AD Carter 《Canadian Metallurgical Quarterly》1998,35(14-15):977-987
Bacterial lipopolysaccharide (LPS) is a potent activator of cells of the macrophage/monocyte lineage. Two mature macrophage cell lines, P388D1 and RAW264.7, exhibit very different biological responses to LPS. Although RAW264.7 cells release arachidonic acid from phospholipid in response to LPS stimulation, P388D1 cells do not respond in this manner. However, LPS primes P388D1 cells to release arachidonic acid in response to other stimuli. The goal of this work is to contrast the biochemical events that occur in LPS-treated P388D1 and RAW264.7 macrophages. Enzyme assays indicate that LPS treatment induces the activation of cytosolic PLA2 in RAW264.7, but not in P388D1 cells. Phorbol ester (PMA), a receptor-independent stimulus, also fails to induce arachidonic acid release from P388D1 cells, suggesting that these cells may have a defect in the signal transduction machinery that is common to LPS and PMA. This hypothesis is supported by the observation that the expression of the LPS receptors CD14 and CD11b/CD18 is similar on P388D1 and RAW264.7 cells. Western blot analyses indicate that the erk kinases are activated upon LPS treatment of RAW264.7 but not P388D1 cells. LPS-induced arachidonic acid release is reduced in cells treated with the MEK inhibitor PD98059, suggesting that activated erk kinases mediate the phosphorylation and activation of cPLA2 in this system. Interestingly, the p42 isoform of erk (erk2) appears to be activated in resting P388D1 cells. This observation indicates that the MAP kinase cascade may be constitutively activated in P388D1 cells which may in turn limit their ability to respond to LPS. Together, these data provide evidence that mature macrophages from different sources can exhibit variable responses to LPS and highlight the danger of making generalizations regarding the effects of LPS on macrophages. 相似文献
116.
In the present work FeS2 films have been grown by spray pyrolysis followed by sulfidation. The structural, optical and electrical properties of these films have been investigated. The films were found to be n-type with an indirect band gap of 1.17 eV. These films have a high potential for use in thin film solar cells and photoelectrochemical cells. 相似文献
117.
This paper reports on silicon nanowire growth on oxidized silicon substrates using different approaches for gold catalyst
deposition. The gold coated surfaces and the resulting nanowires were characterized using scanning electron microscopy. The
gold catalysts were made up of gold nanoparticles (50 nm diameter), which were either dispersed or spotted at different concentrations
using a robot, or were formed on a patterned Si/SiO2 substrate by metal evaporation (63 nm diameter). The subsequent silicon nanowire growth was accomplished by CVD decomposition
of silane gas (SiH4) at high temperature (400–500°C) in a vapor-liquid-solid (VLS) process. Under these conditions, a high density of silicon nanowires (SiNWs) was achieved
on the oxidized silicon surfaces, but the distribution of the nanowires was found to be inhomogeneous in the case of the gold
nanoparticles. Such result is attributed to the aggregation of the nanoparticles during the growth process. Alternatively,
when gold nanodot catalysts were lithographically patterned on the surface, the nanowires were obtained in the patterned regions. 相似文献
118.
Haniyeh Tahzibi Saeid Azizian Sabine Szunerits Rabah Boukherroub 《Advanced Engineering Materials》2023,25(19):2300197
Recently, a straightforward method for the preparation of a Janus carbon cloth (Janus-CC) is reported. The method relies on polydimethylsiloxane (PDMS) coating, followed by flame exposure of one face of the PDMS-coated CC. The nonexposed to the flame face of the Janus-CC is superhydrophobic, while the exposed to the flame face is superhydrophilic. Underwater, the superhydrophobic face shows superaerophilicity, while the supherhydophilic face shows superaerophobicity. A tethered gas bubble onto the superhydrophobic face has a paraboloid of revolution shape due to the cohesion force between the bubble and the gaseous film. Herein, the geometrical parameters of underwater tethered gas bubbles onto the Janus-CC are obtained, and the tendency of Janus-CC for capturing of bubbles is interpreted based on the derived Gibbs free-energy change equation. It is experimentally observed that a small sited bubble moves toward the bigger one through the formed gaseous film, but this observation cannot be interpreted based on the classical Young–Laplace equation because here the smaller bubble has bigger curvature radius. Herein, a modified Young–Laplace equation is derived and applied for interpretation of the movement of a small bubble toward the bigger one. Also, the buoyancy force for a sited bubble on the gaseous film is discussed. 相似文献
119.
Souhila AbaciBelkacem Nessark Rabah BoukherroubKamal Lmimouni 《Thin solid films》2011,519(11):3596-3602
The analysis of the electrochemical and spectroscopic properties of a composite material obtained starting from the polyaniline and TiO2 in H2SO4 medium, using cyclic voltamperometry, shows three redox couples characteristic of the different oxidation and reduction states of produced polymer. The electroactivity of the composite in acid medium was better than that obtained in basic medium. The impedance spectroscopy study shows that the resistance of the film increases with the aniline concentration, but is not significantly affected by the amount of TiO2 incorporated in polymer. The increase of pH decreases the resistance of the films and consequently increases its conductivity. 相似文献
120.
Mohamed M. Ibrahim Amine Mezni Mohammed Alsawat Tushar Kumeria Arwa Alrooqi Abdallah A. Shaltout Sameh I. Ahmed Rabah Boukherroub Mohammed A. Amin Tariq Altalhi 《国际能源研究杂志》2020,44(8):6725-6744
A newly synthesized zinc(II) complex, namely tert-butyl N-(2 mercaptoethyl)carbamatozinc(II) complex [Zn(Boc-S)2] (Boc = tert-butyl N-[2-mercaptoethyl]carbamate), has been used as an organozinc precursor for the production of crystalline ZnO and ZnO/TiO2 nanoparticles. The synthesized complex and the obtained nanomaterials were fully characterized using various spectroscopic and surface analysis techniques. Their surface morphology, chemical purity and stoichiometry have been investigated by scanning electron microscopy (SEM), energy dispersive X-ray analysis (EDX) as well as X-ray fluorescence. The synthesized Zn(II) molecular complex, ZnO and ZnO/TiO2 nanomaterials have been tested in alkaline aqueous solution (1.0 MNaOH) for the hydrogen evolution reaction (HER) using various electrochemical techniques. The results revealed high HER catalytic performance of ZnO and ZnO/TiO2 cathode materials, with the latter exhibiting higher catalytic activity recording an exchange current density (jo) of 0.3 mA cm−2. This current value, which approaches that of Pt wire (0.5 mA cm−2), cross-sectional area ~0.008 cm2, is about 11 and 100 times greater than those measured for ZnO alone (0.028 mA cm−2) and TiO2 alone (0.0032 mA cm−2), respectively. Moderate catalytic activity was recorded for the complex catalyst, namely GC-Zn(Boc-S)2 with jo value of (0.01 mA cm−2). Tafel slope values of 130 and 122 mV dec−1 were calculated for ZnO and ZnO/TiO2, respectively. Such Tafel slope values, which are close to that of the Pt wire (120 mV dec−1), referred to a Volmer-controlled HER kinetics. Other important electrochemical parameters describing the kinetics of the HER, such as roughness factor (Rf) and turnover frequency (TOF) were also estimated and discussed. The high numerical values of the various HER kinetic parameters recorded for the ZnO/TiO2 catalyst, in addition to its high stability and durability (stable for up to 10 000 continuous cathodic polarization cycles), besides maintaining its morphology and chemical composition after stability test (confirmed from SEM/EDX and XRD examinations), located it in a privileged position among the most efficient HER electrocatalysts reported in the literature. 相似文献