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991.
A major challenge confronting psychologists is finding relevant professional development experiences. An Internet-based professional community is one approach to meeting this challenge. The authors investigated the development of such a professional community among school psychologists. Results from behavioral measures and questionnaires reflected a moderate to strong sense of community among the participants. The single best predictor of sense of community was the participants' perceptions that the Internet site enhanced their professional development. On-line participation and social support also related to sense of community. Results suggest that the Internet is a promising medium for the development of professional communities. (PsycINFO Database Record (c) 2010 APA, all rights reserved)  相似文献   
992.
Only a few hours after five thousand basketball fans had left, the roof of the Hartford Civic Center Coliseum collapsed under a heavy snowfall. Fortunately, the arena was empty. The design of the space frame roof had been based on an innovative and extensive computer analysis. However, when deflections twice as great as those predicted by the computer analysis were observed during construction, the warning was ignored. Overconfidence in computer analysis results played a large part in this failure. A useful lesson from this case is that the computer is only an analytical tool and computed results must be checked by the designer with a careful eye. The long, unbraced lengths of compression members made them highly susceptible to buckling. This case serves as a lesson for engineering students and practicing engineers concerning the difficult technical, professional, procedural, and ethical issues that may arise during the design and construction of a complex, high-occupancy structure.  相似文献   
993.
994.
    
Solid propellants, like all highly filled elastomers, exhibit a complex nonlinear viscoelastic behavior. The aim of this study was to establish the relationships between the structure and properties, which is needed to construct a robust constitutive law for these materials. An extensive design of experiments approach allowed us to quantify the influence of the curing agents and plasticizer molecules on the microstructure of the propellant and its viscoelastic properties. Swelling and gel permeation chromatography measurements described the microstructure of the propellant and prestrained dynamic mechanical analysis (PDMA) characterized the viscoelastic behavior. The curing agents reacted with polymer chain ends participating in the network, in the sol fraction, or in filler–binder links. Consequently, the polymer network was incomplete even in stoichiometric conditions, and a minimum of 10% of the polymer was free in the microstructure. In addition, preswelling the polymer with plasticizer molecules before curing modified the obtained network by decreasing the crosslink density in the binder and increasing it in the vicinity of the filler surface. This study provided new insight into the local deformation mechanisms controlling nonlinearity as measured by PDMA. The nonlinear behavior appeared between 0 and 1.7% prestrain in both the elastic and viscous parts of the behavior. The network reached its maximum extensibility in the elastic part and constrained the sol fraction in this extended mesh for the viscous part. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 40392.  相似文献   
995.
    
Isothiocyanates (ITCs) are one of the many classes of breakdown products of glucosinolates found in crucifers such as broccoli and are thought to be partially responsible for the reduced risk of degenerative diseases associated with the consumption of vegetables. The production of ITCs such as L-sulforaphane is dependent on the hydrolytic bioactivities of myrosinase, localized both within vegetable tissues and within flora of the human GI tract, and is associated with important cancer chemopreventive activities. We hypothesized that novel isothiocyanates with enhanced chemopreventive properties relative to L-sulforaphane could be identified and that their glucosinolate precursors could be synthesized. From a library of 30 synthetic ITCs, we identified several with bioactivities equal or superior to those of L-sulforaphane. The corresponding non-natural glucosinolate precursors to these novel ITCs were constructed and found to be substrates for myrosinase. By utilizing a novel RP-HPLC assay to monitor myrosinase-dependent hydrolysis reactions, 2,2-diphenylethyl glucosinolate and (biphenyl-2-yl)methyl glucosinolate were shown to exhibit 26.5 and 2.8 %, respectively, of the relative activity of sinigrin and produced their corresponding ITCs in varying yields. These data support the notion that non-natural glucosinolates can act as prodrugs for novel ITCs, with a mechanism of action reliant on their hydrolytic cleavage by myrosinase. Such non-natural glucosinolates may serve as very economical chemopreventive agents for individuals at risk for cancers of and around the GI tract.  相似文献   
996.
    
There is great current interest in bridging the gap between robust synthetic polymers and complex biological polymers to allow for the preparation of novel functional, well‐defined, biocompatible and tailorable materials. In this mini‐review recent reports on the preparation of functional amino acid polymers using controlled radical polymerisation techniques are discussed. The future potential applications of these materials as well as the proposed further directions in the field are also highlighted. Copyright © 2010 Society of Chemical Industry  相似文献   
997.
    
BACKGROUND: UV‐curable coatings are promising candidates for environmentally friendly marine fouling‐release coatings. Cationic UV‐curable epoxy‐siloxane release coatings show good release performance but suffer from poor coating mechanical properties. A difunctional oxetane monomer, DOX, was co‐photopolymerized with an epoxy‐siloxane oligomer at loading levels from 10 to 40 wt% to obtain toughened fouling‐release coatings. RESULTS: The DOX‐toughened coatings showed enhanced cationic photopolymerization activity, solvent resistance and modulus. DOX‐toughened coatings (10 and 20 wt%) exhibited higher impact resistance. The DOX‐toughened coatings showed no leachate toxicity and the coatings were hydrophobic and non‐toxic to biofilm growth when analyzed with marine bacteria and algae. In general, 10 and 20 wt% DOX‐toughened coatings exhibited better marine bacteria and algae fouling‐release performance among the DOX‐toughened coatings. Pseudo‐barnacle shear release stress for the DOX‐toughened coatings increased with increasing DOX content. Live barnacle reattachment assay showed that 10 and 20 wt% DOX‐toughened coatings had comparable barnacle removal stress to commercial silicone reference coatings. CONCLUSIONS: DOX‐toughened (10 and 20 wt%) UV‐curable epoxy‐siloxane coatings exhibited enhanced mechanical properties and better overall marine fouling‐release performance among the toughened UV‐curable release coatings studied. Copyright © 2008 Society of Chemical Industry  相似文献   
998.
999.
    
Reliable and rapid analysis remains a high priority for quality control in biodiesel production. Quantifying biodiesel with alternative analytical tools such as proton nuclear magnetic resonance (1H NMR) can provide total methyl esters distributions without significant sample pretreatment. Using unique spectra of individual methyl esters, we investigate the feasibility of using 1H NMR spectroscopy to identify and quantify relative and absolute concentrations of methyl esters in a biodiesel.  相似文献   
1000.
The claim that appropriate "after-event review (AER)" may increase the relative value of drawing lessons from successes, as compared with failures, was examined in the present study. The study was a laboratory experiment in which the effect of type of AER (failure-focused, success-focused, failure- and success-focused, and no AER review) on performance improvement and causal attributions was tested under conditions of earlier success and earlier failure. In general, 2 results were demonstrated: (a) Drawing lessons from successful experience is feasible, and its effectiveness is contingent upon the type of AER. More specifically, after successful events, the most effective review is that of wrong actions, whereas after failed events, any kind of event review (correct or wrong actions) is effective. (b) AERs elicit more internal (as opposed to external) and specific (as opposed to general) attributions. These 2 classifications moderate the effect of AERs on task performance. (PsycINFO Database Record (c) 2010 APA, all rights reserved)  相似文献   
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