Morphology evolution induced by carbon nanotubes on thermal and mechanical characters of semi-crystalline aromatic polyimide

A series of nanocomposites based on a new semi-crystalline polyimide (PI) and multi-walled carbon nanotubes (MWCNTs) were prepared by in situ polymerization. The TEM measurement reveals the improved dispersion of carboxylic acid-functionalized MWCNTs (COOH-MWCNTs) in semi-crystalline PI compared with pristine MWCNTs. The TGA analysis show that the concentration of carboxylic acid groups on the surface of nanotubes is about 4.34 wt%. The FT-IR spectroscopy analysis indicate that the imide rings of the PI interact non-covalently with nanotubes. The Polarized optical microscopy observation reveals significant morphology evolution in semi-crystalline PI induced by MWCNTs. The SEM micrographs suggest the strong interfacial interaction between COOH-MWCNTs and PI main chains, and significant changes in the fracture surfaces morphology. The WAXRD measurements reveal that COOH-MWCNTs promote the semi-crystalline PI crystallinity and structure change. COOH-MWCNTs can more efficiently improve the mechanical and thermal properties of resulting nanocomposites than pristine MWCNTs. COOH-MWCNT/PI nanocomposites show increases of Young’s modulus and yield strength, as high as 20–30 %, without sacrificing the elongation at break at loadings of 0.5 wt% nanotubes. Furthermore, with increasing the loadings of COOH-MWCNTs to 1.0 wt%, Young’s modulus and yield strength decrease due to nanotube aggregation, but elongation at break increase about 46 %. An abrupt increase of elongation at break in pristine MWCNT/PI nanocomposites was also registered at nanotubes loadings increasing from 0.5 to 1 wt%. These results indicate that the properties of semi-crystalline PI nanocomposites reinforced with carbon nanotubes are not only determined by the dispersion of nanotubes in the PI matrix and their interfacial interactions, but also by the crystalline phase morphology evolution in the PI matrix.     

Thermal stability evaluation of polypropylene protected with grafted amine

Summary Polypropylene containing a grafted amine as oxidation protector was subjected to γ-irradiation for the evaluation of thermal stability. Several formulations were prepared containing hindered amine, Sanduvor PR 31 (0.1, 0.2 and 0.3% w/w) and CaCO₃ (0.6% w/w). The stability assessment was carried out in air by oxygen uptake procedure under isothermal and isobaric conditions (165 °C and normal pressure, respectively). The exposure doses were placed in the range from 0 to 70 kGy. The changes appeared in the main kinetic parameters (oxidation induction time and oxidation rate) evaluated for thermal degradation of irradiated PP specimens are presented and the stability analysis is explained starting from the behaviour differences of various formulations of radiation processed polypropylene. On the low dose range, the drop in thermal stability of modified polypropylene films occurs more abrupt than it was observed for the samples irradiated at higher doses.     

Semi-fragile watermarking for image authentication with sensitive tamper localization in the wavelet domain

This paper proposes a novel image authentication scheme in the wavelet domain. The scheme uses a semi-fragile watermark to detect and precisely locate malicious tampering in images. The wavelet coefficients selected for embedding are randomly permuted with a secret key, achieving high security. A bit of the watermark is embedded in a group of coefficients by means of quantization. The experimental results show, that our algorithm achieves high image quality and high tampering detection resolution at a low watermark payload, compared to block-based authentication schemes. Thanks to the random permutation, the watermark is protected against local attacks. We have also conducted experiments to demonstrate the robustness of the watermark against mild to moderate JPEG compression.     

Comparison of environmental impacts of two residential heating systems

This paper presents a comparison of environmental impacts of two residential heating systems, a hot water heating (HWH) system with mechanical ventilation and a forced air heating (FAH) system. These two systems are designed for a house recently built near Montreal, Canada. The comparison is made with respect to the life-cycle energy use, the life-cycle greenhouse gas (GHG) emissions, the expanded cumulative exergy consumption (ECExC), the energy and exergy efficiencies, and the life-cycle cost. The results indicate that the heating systems cause marginal impacts compared with the entire house in the pre-operating phase. In the operating phase, on the other hand, they cause significant environmental impacts. The HWH systems with a heat recovery ventilator (HRV) using either electricity or natural gas have the lowest life-cycle energy use and lowest ECExC. The HWH and FAH systems using electricity as energy source have the lowest GHG emissions. Finally, the FAH systems have, on the average, a lower life-cycle cost than the HWH systems.     

Ba(Ti1 − xSnx)O3 (x = 0.13) nanomaterials produced by low-temperature aqueous synthesis

BaTi_0.87Sn_0.13O₃ (BTS₁₃) nanopowder was prepared by low-temperature aqueous synthesis (LTAS) method. The evolution of the structure and microstructure of the precursor precipitate, heated at temperatures up to 1000 °C was studied by TGA, FT-IR, SEM and XRD techniques. The dried precipitate showed a microstructure consisting of nano-sized grains (∼40 nm) with great tendency to agglomeration. BaTi_0.87Sn_0.13O₃ single phase was obtained at 800 °C. The ceramics prepared from as-obtained BTS₁₃ powders (60-70 nm) show good dielectric and ferroelectric characteristics. The dielectric constant was about 4800 and the dielectric loss (tan δ) was 0.229 at 1 kHz and at the Curie temperature (31 °C). The remanent polarization (P_r) and the coercive field (E_C) of Ba_0.97Ho_0.03TiO₃ ceramics, at 1 kHz, were P_r = 13 μC/cm² and E_C = 0.89 kV/cm. The ferroelectric parameters E_C and P_r decrease with increasing frequency in the domain 100 Hz to 10 kHz.     

Factors Influencing the Reversion of Stress-induced Martensite to Austenite in a Fe-Mn-Si-Cr-Ni Shape Memory Alloy

It is well known that one way shape memory effect (SME) in Fe-Mn-Si-based shape memory alloys (SMAs) is related to the thermally induced reversion of ε (hexagonal close packed, hcp) stress-induced martensite (SIM) to γ (face centered cubic, fcc) austenite. In the case of a Fe-Mn-Si-Cr-Ni SMA, this reverse martensitic transformation was analyzed in regard to the critical temperature for the beginning of austenite formation (A _s) in different states characterized by quenching temperature and permanent tensile strain. For this purpose, dynamic mechanical analysis (DMA), dilatometry (DIL), differential thermal analysis (DSC), and optical microscopy (OM) were employed to determine the influence of quenching temperature and permanent tensile straining on SIM reversion to austenite during heating.     

Inside looking out: a framework for discussing the question of architectural design doctorates

This text proposes a framework for provoking and sustaining a debate on the question of architectural design doctorates. Through a series of aphorisms it argues that the formal structure of architectural research should be defined by architects according to disciplinary specificity.

1. Architectural design is to architecture what research is to science.
2. The recognition of architectural design as research is more a problem of academic and social legitimisation than an epistemological one.
3. The process of architectural design is close to the process of knowledge creation in the sciences.
4. Architectural design is a process that incorporates and reconstructs knowledge.
5. The doctorate is a link in the chain of professional training of scientists as researchers and of architects as designers.
6. The ArchD is an opportunity to improve the practice of architecture.
7. The ArchD is an exploration of architectural design, the main tool of architects.
8. The Interface ArchD connects architectural design to theories and practices, to other forms of design and to other types of knowledge.
9. The Didactic ArchD contributes to the training of design professors, to the conversion of design knowledge into educational content and to innovation in learning environments in architecture.
10. The Self-reflective ArchD questions real or simulated practice, or proposes visionary designs.
11. There is no axiological difference between architectural design and scientific research.