Swift and Selective Reduction of Nitroaromatics to Aromatic Amines with Ni–Boride–Silica Catalysts System at Low Temperature

Various nitroaromatics are successfully reduced to amines with 100% conversion and selectivity in methanol at low temperature (≈5 °C), by using versatile system of 5% Ni–SiO₂ catalyst and NaBH₄ and in situ generation of Ni boride. The catalytic efficiency of Ni loading (5%, 10% and 15%) with silica or titania as support materials is investigated for reduction of nitrobenzene. The Ni–titania/NaBH₄ system recorded lower conversion and selectivity. The IR studies indicate that silica support does not have free –OH group on its surface. Thus the nickel boride is anchored to the silica to facilitate the catalytic process.     

Multilevel optimization applied to hull girder design using three panel forms

A multilevel design scheme for ship's hull girders (longitudinal members between two adjacent transverse frames) is presented in this paper. This design scheme handles, very conveniently, the complexity of using an optimization algorithm for such complex design problems having a large number of design variables, nonlinear constraints dealing with different failure modes and interactions among substructures, and nonlinear design objectives. The conventional multilevel design technique is modified by introducing an approach called constraint coordination to increase the probability of achieving the overall optimum very efficiently.The scheme is demonstrated by application to the structural design of hull girders with simple structural modelling to represent inland waterway ships on which there was a special emphasis in the original research project (Rahman 1991). Three possible panel (consisting of one stiffener and its attached plating) forms; tee stiffened, flat-bar stiffened and corrugated, are optimized to synthesize the hull girder in order to achieve the most efficient structure. The effect of price-structure (labour rate to material price ratio) on the design is also investigated.     

Cyclobutanones as markers for irradiated samples of Brie and Camembert cheese

The feasibility of applying a chemical method based on the formation of 2-alkylcyclobutanone to samples of irradiated soft cheese (Brie and Camembert) was investigated. Significant quantities of 2-dodecylcyclobutanone (DCB) and 2-tetradecylcyclobutanone (TCB) were detected in both types of irradiated cheese and are proposed as qualitative markers. Other members of the cyclobutanone family (decyl- and tetradecenyl-) are also thought to be present but could not be substantiated due to a lack of authentic standards. These compounds were absent from the unirradiated samples. Results also show a significant linear relationship between the irradiation dose (1 to 8 kGy) and the amount of DCB and TCB detected in the cheese.     

Activation of 5-HT2 receptors facilitates depolarization of neocortical neurons by N-methyl-D-aspartate

We prospectively studied 63 children with transient hyperglycemia to determine their risk of acquiring insulin-dependent diabetes mellitus (IDDM) and to evaluate the predictive value of immunologic markers of prediabetes and of the intravenous glucose tolerance test. Children with transient hyperglycemia were identified by a prospective systematic review of the laboratory reports of a large children's hospital and an office-based pediatric practice and by referral from pediatricians. Transient hyperglycemia occurred in 0.46% of children seen in the children's hospital and in 0.013% of children attending a pediatric office practice. Insulin-dependent diabetes mellitus developed within 18 months of identification in 32% of children in whom transient hyperglycemia was discovered in the absence of a serious illness, compared with 2.3% of children identified during a serious illness (relative risk, 13.9; 95% confidence interval, 1.56 to 123.5). Islet cell antibodies and competitive insulin autoantibodies each had a 100% positive predictive value for IDDM; the negative predictive value of islet cell antibodies and competitive insulin autoantibodies was 96% and 98%, respectively. The stimulated insulin release during an intravenous glucose tolerance test, adjusted for age, had the highest overall accuracy of prediction. All children less than 6 years of age with stimulated insulin release levels < 85 pmol/L (12 microU/ml) subsequently had IDDM, as did an 11-year-old child whose stimulated insulin release level was below the 1st percentile of 170 pmol/L (24 microU/ml). To date, no child whose stimulated insulin release level was above the 5th percentile has had IDDM. We conclude that when transient hyperglycemia occurs during a serious intercurrent illness, the risk of progression to IDDM is low. In contrast, one third of children in whom transient hyperglycemia is identified without a serious illness can be expected to have IDDM within 1 year. A combination of islet cell antibodies, competitive insulin autoantibodies, and stimulated insulin release levels during an intravenous glucose tolerance test can accurately distinguish children with prediabetes from those with presumed benign transient increases in plasma glucose concentrations.     

Simulation and experimental analyses of electromagnetic transients behaviors of lightning surge on vertical conductors

Simulation of very fast surge phenomena in a three-dimensional (3-D) structure requires a method based on Maxwell's equations, such as the finite-difference time-domain (FDTD) method or the method of moments, because circuit-equation-based methods cannot handle the phenomena. This paper uses a method of thin-wire representation of the vertical conductor system for the FDTD method which is suitable for the 3-D surge simulation. The thin-wire representation is indispensable to simulate electromagnetic surges on wires or steel frames in which the radius is smaller than a discretized space step used in the FDTD simulation. In this paper, a general surge analysis program named the virtual surge test lab based on the Maxwell's equations formulated by the FDTD method, is used to simulate the surge phenomena of a vertical conductor, including the effects of horizontal wave incidence and vertical wave incidence. Experimental results on the reduced scale model have been presented in order to compare among the simulation results by the FDTD method and the results using numerical electromagnetic code based on the MoM.     

The functional reanimation of paralyzed limbs.

The functional reanimation of paralyzed limbs has been a longstanding goal of neural prosthetic research, but clinically successful applications have been elusive. Natural voluntary limb movement requires four major elements: actuators (i.e., motor units), sensors (i.e., somatosensory afferents), commands (i.e., cerebral cortical activity), and control (i.e., integration of the previous three elements at various levels of the neuraxis). Prosthetic equivalents of each of these elements are, as yet, primitive and often cumbersome to deploy, but new technologies promise substantial improvements for all. This article focuses on one such technology, bionic neuon (BION) modular microimplants, and its relationship to alternative and complementary technologies. The challenge remains to select and integrate them into systems that can be tailored efficiently to the widely disparate needs of patients with various patterns of weakness and paralysis.     

A PRACTICAL CLASSIFICATION OF KEROGENS RELATED TO HYDROCARBON GENERATION

The present classification systems of kerogens have many shortcomings, especially in respect of amorphous kerogens which have, so far, remained undifferentiated in relation to hydrocarbon generation. Hence, a practical classification method based on density separation, elemental composition and optical characteristics, which discriminatingly identifies kerogens with indications of their hydrocarbon potential, has been developed. The method first divides the whole range of kerogens into liptinite and humic groups. The liptinitic kerogens are subdivided into Hyperliptinites (prolific oil sources); Mesoliptinites (which are oil-prone); Metaliptinites (gas-prone); and Hypoliptinites (having no potential for hydrocarbons). The humic kerogens are similarly divided into subgroups consisting of Hyperhumics (with some gas potential); Mesohumics (mainly gas sources); and Hypohumics (organic materials with no potential for hydrocarbon generation).     

Proposal for st-Routing Protocol

A routing protocol chooses one of the several paths (routes) from a source node to a destination node in the computer network, to send a packet of information. In this paper, we propose a new routing protocol, which we call st-routing protocol, based on st-numbering of a graph. The protocol fits well in noisy environments where robustness of routing using alternative paths is a major issue. The proposed routing protocol provides a systematic way to retry alternative paths without generating any duplicate packets. The protocol works for only those networks that can be represented by biconnected graphs.     

Multicriteria Hydraulic Fracturing Optimization for Reservoir Stimulation

A complete model is presented in this article for design optimization of hydraulic fracturing to enhance reservoir production. The model integrates reservoir properties, various design constraints to avoid induced formation damage, a hydraulically driven fracture geometry model, a hydrocarbon production model, and an economic model in deciding on the optimum values of various treatment parameters. The design constraints are intended to ensure that an optimum design obtained from the model can be executed in the field using the specified surface equipment and without causing uncontrolled fracture growth and/or initiation of multiple secondary fractures. A pseudo-3D fracture model is improved to establish better compatibility relationships between reservoir properties, treatment parameters, and fracture growth. Features of Genetic Algorithm and Evolutionary Operation are combined to develop a robust optimization algorithm that executes complex interactions between the above-mentioned modules to achieve an optimum design. The capability and robustness of the proposed model is demonstrated by applications to a tight-gas reservoir. By trade-off analysis between production/NPV and treatment cost, it is shown that only a 13% sacrifice of the maximum possible production/net present value (NPV) over ten years can save up to 52% of the fracturing treatment cost. Various other design issues are also investigated by sensitivity analyses.