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71.
Force-balance experiments in conjunction with the Johnson-Kendall-Roberts (JKR) theory have been used to determine the work of adhesion between solid systems. It has been shown that deficiencies in understanding the deformation behavior can lead to erroneous results. A modified procedure for determining the work of adhesion by force-balance experiments and JKR theory using normal displacement behavior has been introduced to address these deficiencies. This procedure involves improved experiental and data analysis protocols and has been applied to give more precise work of adhesion values for PDMS poly(dimethylsiloxane)-PDMS, PDMS-F(fluorinated silicon) and PDMS-Si (silicon) systems. The work of adhesion determinations are consistently less than those estimated by contact angle measurements. 相似文献
72.
Finite mixtures are often used to perform model based clustering of multivariate data sets. In real life applications, such data may exhibit complex nonlinear form of dependence among the variables. Also, the individual variables (margins) may follow different families of distributions. Most of the existing mixture models are unable to accommodate these two aspects of the data. This paper presents a finite mixture model that involves a pair-copula based construction of a multivariate distribution. Such a model de-couples the margins and the dependence structures. Hence, the margins can be modeled using different families. Again, many possible dependence structures can also be studied using different copulas. The resulting mixture model (called DVMM) is then capable of capturing a broad family of distributions including non-Gaussian models. Here we study DVMM in the context of clustering of multivariate data. We design an expectation maximization procedure for estimating the mixture parameters. We perform extensive experiments on the basis of a number of well-known data sets. A detailed evaluation of the clustering quality obtained by DVMM in comparison to other mixture models is presented. The experimental results show that the performance of DVMM is quite satisfactory. 相似文献
73.
Fuel cells wherein zinc particles form a negative electrode and a gas-diffusion electrode (air electrode) is the positive electrode, are under development. Such cells are dependent on the regeneration of the zinc particles (and electrolyte). This paper describes experiments on electrolytic cells equipped with spouted bed cathodes for use in this application. Experiments have been carried out on laboratory scale cells to determine the operability of cells for growing 'seed particles in the range from 0.4 to 1 mm to measure cell voltage and current efficiency (and thereby energy consumption rate), and to identify a suitable material that could be used as a diaphragm (separating the spouted bed from the oxygen evolving anode). A larger cell, capable of producing up to 10 kg Zn per day, was designed and built. The larger cell was run successfully fifteen times and showed cell voltages and energy consumption rates comparable with those of smaller cells. 相似文献
74.
Platinum-based catalysts, for the electro-oxidation of methanol, have been made by thermal decomposition of chloride precursors onto titanium mesh. The catalysed electrodes were successfully operated in acidic methanol electrolytes. Electrochemical characterisation has been carried out using cyclic voltammetry, electrochemical impedance spectroscopy and galvanostatic polarisations. A complete analysis of the electrochemical results showed that the preliminary performance of the catalysed titanium mesh was comparable to that achieved with carbon-supported PtRu catalysts. The catalysts formed on titanium mesh by thermal decomposition also exhibited dimensional stability. Catalysed titanium mesh therefore appears to be a promising alternative to carbon-supported catalysts for certain fuel cell applications. 相似文献
75.
X‐ray photoelectron spectroscopy (XPS) was used to study the hydrolytic aging of polypropylene according to the pHs of degrading buffer solutions and the time of aging. The study was concentrated over periods of 3, 6, and 9 months for values of pH close to the real environments of use of the material (pH of 6, 7, and 8). The polypropylene underwent an oxidation of its polymeric matrix, independently of the range of pH values, by the production of C? OH, C?O, and O?C? O groups. These chemical functions were observed in high resolution XPS spectra around C1s and O1s peaks. Beginning with these results and from mechanisms of (photochemical, thermal, and others) aging proposed in the literature, it was then possible to propose mechanisms of hydrolytic ageing of polypropylene. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 92: 3830–3838, 2004 相似文献
76.
The effects of short carbon fibers on static and dynamic properties of thermoplastic elastomeric blends of natural rubber (NR) and high density polyethylene (HDPE) have been studied. Both mechanical and dynamic properties are dependent on fiber concentration. The fiber aspect ratio ranges from 20 to 30. Adhesion between fiber and matrix is evident from the SEM photomicrographs of the failed composites and from variation of relative damping properties. Fiber orientation occurring during processing causes anisotropy in the physical properties. In composites with longitudinally oriented fibers, tensile failure occurs by both fiber pullout and breakage, while in composites with transversely oriented fibers, matrix failure dominates. The incorporation of fibers into the matrix lowers the tan δmax value, but no change in glass transition temperature is observed. 相似文献
77.
Various softwood and hardwood bark residues, primary sludges and softwood sawdust residues were processed by vacuum pyrolysis in a laboratory scale batch reactor. The pyrolysis oil, water, charcoal, and gas were recovered and analyzed. The pyrolysis oils were analyzed in details for their content in phenolic compounds after derivatization to their acetyl derivatives. The influence of temperature, heating rate, feedstock bed thickness, particle size and feedstock water pretreatment on the yield of phenols was investigated. The highest yield of phenols was obtained when hardwood bark was soaked in water for 48 hours and pyrolyzed at a temperature of 450°C and a heating rate of 10°C/min. Pyrolysis performance was evaluated in terms of total phenolic yield and composition. 相似文献
78.
Experimental investigations have been carried out for spherical and non-spherical particles using beds comprised of single-sized particles and mixtures in the size and particle density ranges of 439 to 1524 μm and 1303 to 4948 kg/m3, respectively. Five conical fluidizers with varying apex angles of 8.86, 14.77, 19.60, 32.0 and 43.2 degrees were used. Experimental values of minimum velocity and bed pressure drop with air as the fluidizing medium have been compared with their respective values obtained from different models available in the literature. Deviations for each chosen model have been presented. 相似文献
79.
Timothy J. Bunning Hong G. Jeon Ajit K. Roy Kristen M. Kearns Barry L. Farmer Walter W. Adams 《应用聚合物科学杂志》2003,87(14):2348-2355
The thermal and mechanical properties of polyurethane‐infiltrated carbon foam of various densities were investigated. By combining the high thermal conductivity of the carbon foam with the mechanical toughness of the pure polyurethane, a mechanically tough composite (relative to the unfilled foam) that could be used at higher temperatures than the polyurethane's degradation was formed. Both the tensile strength and the modulus increased by an order of magnitude for the composites compared to unfilled foam, while the compressive and shear strengths and moduli of the composites approached values exhibited by pure polyurethane. At both 300 and 400°C, the rectangular blocks of pure polyurethane lost their mechanical integrity due to decomposition in air. Thermogravimetric analysis confirms substantial initial weight loss above 290°C. Filled carbon foam blocks, however, maintain their mechanical integrity at both 300 and 400°C indefinitely, although the bulk of the rectangular block mass is polyurethane. Three different carbon foam densities are examined. As expected, the higher density foams show greater heat transfer. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 87: 2348–2355, 2003 相似文献
80.
The gasification of biomass derived char obtained via vacuum and atmospheric pyrolysis of Populus tremuloides has been studied in the ranges of 725–960°C and 0.1 to 6 MPa. CO2 was used as the oxidizing gas. The results show that char reactivity is influenced by the preheating rates and that pressure effects are significant between 850°C and 950°C. A correlation based on the expression: df/dt = k0{exp(-E/RT)}(1 - f)afβPyCO2 was used to fit the experimental data. In general, vacuum pyrolysis derived char showed a higher reactivity than atmospheric pyrolysis chars. An explanation based on a higher oxygen content of the vacuum pyrolysis char is suggested. 相似文献