Direct synthesis of nitrogen-rich carbon sheets via polybenzoxazine as highly active electrocatalyst for water splitting

In this work, we propose a novel nitrogen-rich carbon sheets (N-CSs), with conceivable use as efficient catalysts for hydrogen evolution reaction (HER). N-CSs are directly synthesized from polybenzoxazine (PBz) by carbonization followed by KOH activation. PBz was prepared from eugenol, melamine, and paraformaldehyde through ring-opening polymerization. FT-IR and NMR spectroscopy confirmed the corresponding chemical structures of the new benzoxazine monomer. The morphology, structure and surface properties of the N-CSs are investigated by Raman spectroscopy, wide-angle X-ray diffraction, and X-ray photoelectron spectroscopy. The catalytic activity of N-CSs towards HER is thoroughly investigated by electrochemical techniques. In N-CSs, it is established that nitrogen gratified electrocatalytic activity, and hence nitrogen atoms should enhance the electrocatalytic properties by increasing the active sites. As the kinetic current is stabilized by the outer nitrogen atom as such, HER is proposed to proceed on these active sites by the Volmer-Heyrovsky mechanism. The N-CSs show outstanding catalytic activity towards HER with lowest onset-potential (?10 mV_RHE) and Tafel slope (45 mV dec^?1) in 0.5 M H₂SO₄ aqueous electrolyte.     

Thin Layer Drying of African Breadfruit (Treculia africana) Seeds: Modeling and Rehydration Capacity

African breadfruit (ABF) seeds are underutilized plant resources, which have been reported to have high potential for novel food and industrial uses. The kinetics of moisture removal during air drying of the whole (WS) and dehulled (DS) seeds was studied at temperatures of 40–70 °C. Five empirical models were tested for predicting the experimental data. Drying of ABF seeds followed an exponential decay pattern, while drying predominantly took place during the falling rate periods. All the drying models predicted the experimental data above 90% accuracy while the Henderson–Pabis model gave the best fit (0.95 < r ² < 0.99) at most of the experimental conditions. Effective moisture diffusivity, D _eff, ranged from 3.65 to 7.15 × 10⁻⁹ m²/s and 3.95 to 6.10 × 10⁻⁹ m²/s for WS and DS, respectively. D _eff showed significant dependence on the moisture content (p < 0.01). Rehydration capacity of DS was not significantly affected by drying temperature while that of WS increased with drying temperature.     

Optimal Scheduling of Casting Sequence Using Genetic Algorithms

Scheduling a casting sequence involving a number of orders with different casting weights and satisfying due dates of is an important optimization problem often encountered in foundries. In this article, we attempt to solve this complex, multi-variable, and multi-constraint optimization problem by using different implementations of genetic algorithms (GAs). In comparison with a mixed-integer linear programming solver, GAs with problem-specific operators are found to provide faster (with a subquadratic computational time complexity) and more reliable solutions to very large (more than 1 million integer variables) casting sequence optimization problems. In addition to solving the particular problem, the study demonstrates how problem-specific information can be introduced in a GA for solving complex real-world problems.     

Appreciating similarities and valuing differences: The Miville-Guzman Universality-Diversity Scale.

Universal-diverse orientation was defined as an attitude of awareness and acceptance of both the similarities and differences that exist among people. A 45-item scale developed to measure the construct was administered to 4 separate samples (ns?=? 93, 111, 153, and 135). Internal consistency and retest reliability for the Miville-Guzman Universality-Diversity Scale (M-GUDS) ranged from .89 to .95. The M-GUDS significantly correlated in theoretically predicted ways with measures of racial identity, empathy, healthy narcissism, feminism, androgyny, homophobia, and dogmatism (the last 2 correlations were negative). The M-GUDS displayed discriminant validity by failing to correlated with Scholastic Achievement Test Verbal Scores, although mixed results were obtained with social desirability. In summary, the data suggest considerable reliability and initial construct validity for the M-GUDS. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Effect of temperature and frequency on the dielectric properties of cellulose nanofibers from cotton

The present work has been carried out to evaluate the dielectric properties and ac-electrical conductivity of cellulose nanofibers. The cellulose nanofibers (CNF) described in this work are the ones extracted from cotton via a simple acid hydrolysis method and are characterized with X-ray diffraction analysis (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FTIR), and UV–Visible diffuse reflectance spectroscopy. The optical band gap of CNF found out using the Kubelka–Munk plot is 3.30 eV. The dielectric constant, dielectric loss, and ac-electrical conductivity of the prepared CNF have been investigated in the temperature range from 30 °C to 300 °C and in the frequency range from 50 Hz to 5 MHz. The synthesized system exhibits a higher dielectric constant value for all temperatures in the low-frequency (0.1 kHz) region and a frequency-independent behavior above 10 kHz. In the high-frequency region, the dielectric constant is independent of temperature. Also, the study shows that the conductivity increases with increasing frequency and temperature. The maximum values of ac-conductivity at room temperature (30 °C) and high temperature (300 °C) are found to be 4.58?×?10^–5 S/cm and 2.26?×?10^–4 S/cm, respectively. In brief, the studies point to the application potential of CNF for future flexible electronics.

     

CP2: Cryptographic privacy protection framework for online social networks

In Online Social Networks (OSNs), users interact with each other by sharing their personal information. One of the concerns in OSNs is how user privacy is protected since the OSN providers have full control over users’ data. The OSN providers typically store users’ information permanently; the privacy controls embedded in OSNs offer few options to users for customizing and managing the dissipation of their data over the network. In this paper, we propose an efficient privacy protection framework for OSNs that can be used to protect the privacy of users’ data and their online social relationships from third parties. The recommended framework shifts the control over data sharing back to the users by providing them with flexible and dynamic access policies. We employ a public-key broadcast encryption scheme as the cryptographic tool for managing information sharing with a subset of a user’s friends. The privacy and complexity evaluations show the superiority of our approach over previous.     

Detection of mosaic virus disease in cassava plants by sunlight-induced fluorescence imaging: a pilot study for proximal sensing

Cassava mosaic disease (CMD) is a prominent virus infection that causes considerable crop damage and yield reduction. Early detection of crop damage by remote sensing could be a useful tool for initiating remedial measures to reduce further crop damage. This article presents a non-destructive method for detection and classification of CMD infection, based on the red:far-red chlorophyll (chl) fluorescence image ratio. This pilot study was carried out in 14 varieties of potted cassava plants (Manihot esculenta Crantz) with a multispectral imaging system (MSIS) consisting of an electron multiplying charge coupled device (EMCCD) camera. Sunlight-induced chl fluorescence (SICF) images of plant leaves were recorded using the MSIS at the Fraunhofer lines of O₂-B at 687 nm and O₂-A at 759.5 nm and their off-lines at 684 and 757.5 nm. The recorded images were analysed using the Fraunhofer line discrimination (FLD) technique to extract the SICF from the solar reflectance in the recorded images. The chl fluorescence image ratio (red:far-red, F₆₈₇:F₇₆₀) was computed and correlated with the laser-induced chl fluorescence (LICF) ratio (F₆₈₅:F₇₃₅) determined by point monitoring, chl content variation, and the net photosynthetic rate (P_n). The scatter plot of the F₆₈₇:F₇₆₀ image ratio showed good discrimination between different levels of CMD infection as evidenced by the high sensitivity and specificity values. It is observed that the fluorescence image ratio (F₆₈₇:F₇₆₀) has a good correlation with P_n (coefficient of determination (R²) = 0.85), chl content (R² = 0.82), and the LICF ratio (F₆₈₅:F₇₃₅) (R² = 0.80), thereby highlighting the potential of the SICF image ratio in the discrimination of CMD infection. The results clearly indicate that changes in the red:far-red fluorescence image ratio due to CMD stress can easily be detected at an early stage and the technique has great potential for monitoring the health of crops and vegetation from proximal sensing platforms.     

Properties,Classification and Management Implications of Soils of Illela Sand Dunes,Northwestern Nigeria

Soils representative of the stabilised Illela sand dunes in northwestern Nigeria were examined in the field and additional properties of four pedons determined in the laboratory. The soils are deep, dark-brown and sandy throughout their profile. Organic carbon contents are very low, less than 2 g kg⁻¹, and with the siliceous parent material the consequence is low amounts of available nutrients, particularly Ca, K, Mg and N. However, P is moderate to high due to the occurrence of phosphatic nodules at depth. Available micronutrients, Cu, Zn, Mn and Fe, are generally above the critical limits and are adequate for most crops. The high bulk density and low porosity constituted largely of macroporosity impart low water-holding capacity to the soils. Quartz is the dominant mineral in the sand and silt fractions while kaolinite dominates the clay fraction of the soils. According to the USDA Soil Taxonomy and FAO/UNESCO systems of soil classification, all pedons are classified as Ustic Quartzipsamments or Ferralic Arenosols, except four pedon 2 which is classified as Arenic Haplustult or Haplic Acrisol. From the general characteristics of the soils, it is recommended that proper organic matter management via the incorporation of crop residues into the soil, the use of organic manure and crop rotation involving legumes, will greatly enhance the productivity of the soils.     

Positron-defect profiling in Cd<Subscript>1−x</Subscript>Zn<Subscript>x</Subscript>Te wafers after saw cutting

Near-surface damage induced by saw cutting of ingots of Cd_1−xZn_xTe was investigated by positron-defect depth profiling. The damage extends to several micrometers depth and depends on the cutting apparatus. The samples were polished and etched repeatedly, followed each time by positron-depth profiling. New subsurface damage created during the polishing process is observed. No new damage is observed after etching. Positron-depth profiling is suggested as a diagnostic tool to monitor the quality of sample surfaces.