Das digitale geologische Strukturmodell Bitterfeld als neuer Baustein in der Sanierungsforschung

Identification, assessment and remediation of a large-scale groundwater contamination requires a profound knowledge of the geological structure to predict the fate of contaminants in the subsurface. Within the SAFIRA-project, a model sector of the Bitterfeld/Wolfen area was chosen to transfer the structural geological data of the Tertiary and Quarternary aquifer units into a digital geological model. Using 125 selected drillholes as a base of 28 networked cross-sections, small-scale lithological and structural heterogeneities, in particular of the Quarternary layers, could be assigned to 31 litho-stratigraphic sedimentation units and depicted using a 10 × 10 m GIS grid. An assignment of hydraulic parameters to individual sedimentary bodies allows a combination with flow and transport models. The structural model was generated by combining gridding sections and additional point and lateral information of sediment distribution and allows -beyond visualisation purposes- volumetric calculations of distinct sedimentary units, which are relevant for an assessment of retardation processes in the remaining lignite seam. The present structural model is the base for a “Spatial Model Bitterfeld” and anables further investigations on the environmental impact of different scenarios.     

Ziele und Methoden der elektrochemischen Verfahrens- und Reaktionstechnik

Objectives and methods of electrochemical process and reaction engineering . Electrolysis processes are distinguished from ?normal”? chemical processes in several respects: (1) The electrical energy consumed is expensive and assumed the role of an expensive raw material. (2) Mass transfer in electrolytes is sluggish and limits space time yield to relative low values. (3) The rate of reaction is dictated by the applied electrode potential and this determines the cell voltage and energy efficiency of electrolysis processes. Effective electrocatalysts diminish energy consumption per unit mass of product. (4) The relatively poor electrical conductivity of electrolytes leads to construction of special closely spaced cells with narrow cell gaps. It is important to select the operation conditions of, e. g. organo-electrosyntheses to minimise the efforts involved in isolation and purification of the product.     

Auf dem Weg zu idealen Programmierwerkzeugen – Bestandsaufnahme und Ausblick

Zusammenfassung  Angeregt durch Robert W. Floyds Turing-Award-Lecture ,,The Paradigms of Programming“ von 1979 [6] und motiviert durch die Unzufriedenheit des Praktikers mit dem Stand der Softwaretechnik aus vielen Industrieprojekten, versucht dieser Beitrag eine Bestandsaufnahme der Programmiertechnik und identifiziert die Defizite aus Sicht der Grundprinzipien des Konstruktionsprozesses. Mit der Objektorientierung sind, besonders in den letzten Jahren, viele neue Programmiersprachen entstanden, die sowohl Wert auf schnelle Entwicklungszyklen als auch auf Erweiterbarkeit legen. Die heute haupts?chlich verwendeten Sprachen und Umgebungen sind von diesen Zielen weit entfernt. Das Entwickeln von Software ist zum einen zu kompliziert und zum anderen schmerzt die ,,semantische Lücke“ zwischen den ausdrückbaren und den erforderlichen Konzepten. Neue, viel versprechende Programmiersprachen, die sich durchweg auf Metaprogrammierung stützen, um die erforderliche semantische Erweiterbarkeit der Sprachen zu erreichen, deuten die Richtung zukünftiger Entwicklungen an.     

Integration von Sach- und Dienstleistungen – Ausgewählte Internetquellen zur hybriden Wertschöpfung

The article presents results of an internet research on product-service systems. Web sites showing interesting practical examples and studies available online are presented to point out the practical relevance of innovative combinations of products and services. The multiplicity of research projects found on the internet shows that this phenomenon is also discussed intensively in research. These projects have been categorized by analyzing their web sites. Furthermore, the results of the internet research highlight a high diversity of terms for describing the concept of product-service systems. As a consequence, orientation in this subject area is hindered.     

Potentials of precision machining processes for the manufacture of micro forming molds

Molds for micro forming processes require specific functional surfaces to provide optimized tribological condition for forming processes. Such topographies with microscopic dimensions can for instance be generated by lithographical methods. However, a main disadvantage of these processes is their low flexibility, e.g. changing the structures to be generated causes extensive adaptations in the manufacturing process. Therefore, mechanical precision machining processes like micro milling, micro grinding and micro polishing are appropriate processes for the manufacture of micro molds of manifold shapes and with well suited micro topographies.     

Thesen und Trends – Mit funktionalen Oberflächen in die Zukunft

Propositions and Trends – With Functional Surfaces into the Future Functional surfaces are the key to innovative products. Already today the properties, lifetime, and costs for most industrial and consumer products are determined by functionalised surfaces. Three Fraunhofer Institutes supported by the BMBF investigated the actual state of the art of production technology regarding functional surfaces, their future perspectives and the research and development demand. The results are published in the study “Production technology for the generation of functional surfaces” available at info@ist.‐ fraunhofer.de and the essentials are summarised in this article.     

Anaerobic biodegradability and treatment of grey water in upflow anaerobic sludge blanket (UASB) reactor

Feasibility of grey water treatment in an upflow anaerobic sludge blanket (UASB) reactor operated at different hydraulic retention time (HRT) of 16, 10 and 6h and controlled temperature of 30 degrees C was investigated. Moreover, the maximum anaerobic biodegradability without inoculum addition and maximum removal of chemical oxygen demand (COD) fractions in grey water were determined in batch experiments. High values of maximum anaerobic biodegradability (76%) and maximum COD removal in the UASB reactor (84%) were achieved. The results showed that the colloidal COD had the highest maximum anaerobic biodegradability (86%) and the suspended and dissolved COD had similar maximum anaerobic biodegradability of 70%. Furthermore, the results of the UASB reactor demonstrated that a total COD removal of 52-64% was obtained at HRT between 6 and 16 h. The UASB reactor removed 22-30% and 15-21% of total nitrogen and total phosphorous in the grey water, respectively, mainly due to the removal of particulate nutrients. The characteristics of the sludge in the UASB reactor confirmed that the reactor had a stable performance. The minimum sludge residence time and the maximum specific methanogenic activity of the sludge ranged between 27 and 93 days and 0.18 and 0.28 kg COD/(kg VS d).     

Influence of the Gas Atmosphere on the Composition and Phase Development of Polymer-Derived SiOC-Ceramics

Silicon oxycarbide (SiOC)-based ceramics were synthesized by pyrolysis of a commercial polysiloxane containing MoSi₂ and ceramic filler particles. The influence of different gas atmospheres on the chemical composition and on the phase formation of the filled Si–O–C ceramic during the pyrolysis process up to elevated temperatures of above 1200°C has been studied. The pyrolysis gas composition in the furnace during pyrolysis was measured with an in situ gas analyzer. Both the core and the surface of bulk samples were investigated with respect to composition in order to take the changes on the rim area of the specimens into account. The influence of hydrogen gas on the compositional gradient of the resulting ceramic material was derived from samples investigated by polarization microscopy, X-ray diffraction (XRD), and micro-XRD (μ-XRD).     

Dynamical Quantum Phase Transitions

A sweep through a quantum phase transition by means of a time-dependent external parameter (e.g., pressure) entails non-equilibrium phenomena associated with a break-down of adiabaticity: At the critical point, the energy gap vanishes and the response time diverges (in the thermodynamic limit). Consequently, the external time-dependence inevitably drives the system out of equilibrium, i.e., away from the ground state, if we assume zero temperature initially. In this way, the initial quantum fluctuations can be drastically amplified and may become observable—especially for symmetry-breaking (restoring) transitions. By means of several examples, possible effects of these amplified quantum fluctuations are studied and universal features (such as freezing) are discussed.