Treatment of strongflow wool scouring effluent by biological emulsion destabilisation

The stable oil-in-water emulsion contained in wool scouring effluent was destabilised by aerobic biological treatment as the basis of a potential new effluent treatment process. The de-emulsified wool wax, which is recalcitrant to biodegradation, can then be readily removed by centrifugation. In 12-day batch experiments, 97% of wool wax and 87% of COD were removed after gentle centrifuging at 200 x g, compared to only 6% and 8%, respectively, for sterile controls. Steady-state chemostat experiments under optimum conditions gave essentially complete removal of wool wax and 90% removal of COD at less than 40 h retention time, and demonstrated that the mechanism of pollutant removal was by bioflocculation rather than aerobic degradation. At 100 L pilot scale, 95% of wool wax and 82% of COD were consistently removed over a period of 116 days of continuous operation at 38 h retention time and 30 degrees C, producing a spadable sludge of 5.7 mL/g. Variable influent concentration or filamentous bacteria did not disrupt this process and foaming was readily controlled using a mechanical foam breaker. After a shutdown period of 15 days the process could be restarted easily, achieving normal performance within one retention time. The successful operation of the pilot reactor suggests this process could be developed to full scale and incorporated into an overall treatment package.     

Säurekatalysierte Umsetzungen von Aromaten mit Alkanen und Cycloalkanen. IX. Alkylierungen mit 2,2,4-Trimethylpentan (Isooctan)

Acid-catalyzed Reactions of Aromatic Hydrocarbons with Alkanes and Cycloalkanes. IX. Alkylations with 2,2,4-Trimethylpentane (Isooctane) The non-conventional alkylation of benzene, toluene, ethyl- and isopropylbenzene, fluoro- and chlorobenzene with 2,2,4-trimethylpentane in the presence of acid catalysts is described. The composition of the rather complex reaction mixtures is determined by gas-liquid chromatography and mass spectrometry, tert. butylarenes being the main products beside alkylsubstituted indanes and tetralines. Their formation is interpreted as a competition between fragmentation and isomerization of the alkylating agent. By use of trifluoromethanesulfonic acid or combinations of catalysts from HF or HSO₃F with variant metallic fluorides at lower temperatures the selectivity of the reaction may be partially raised.     

在机床研发中基于职能单位的产品开发理论与实践

通过调查得知,包括虚拟现实技术在机床制造中应用可能性的应用方法、策略和工具在产品开发中的现状.对调查结果进行了讨论,考虑到研究理论的可移植性和对企业内部实战的依赖性.讨论的结果为基础研究领域的命题"基于职能单位的产品开发"提供结论.     

Pressure analysis of the hydromechanical fracture behaviour in stimulated tight sedimentary geothermal reservoirs

Hydromechanical phenomena in fractured sediments are complex. They control the flow in stimulated tight sediments and are crucial for the exploitation of geothermal energy from such rocks. We present the analysis of a cyclic water injection/production (huff–puff) process, a promising method to extract geothermal energy from tight sedimentary reservoirs. It uses a single borehole, which considerably reduces investment costs. A huff–puff test was performed in a 3800-m deep sedimentary formation (borehole Horstberg Z1, Lower Saxony, Germany). The analysis presented herein explains the downhole pressure measurements by a simplified reservoir model containing a single vertical fracture. The model addresses the flow behaviour between the fracture and the rock matrix in a layered formation, and the coupling between fluid flow and the mechanical deformation of the fracture. The latter aspect is relevant to predict the efficiency of the geothermal reservoir because cooled regions resulting from a particular injection/production scheme can be identified. The analysis methods include: (1) the curve-fitting code ODA used for a determination of different flow regimes (radial or linear), (2) an analytical solution for the calculation of the injection pressure, assuming a time-dependent fracture area, and (3) the simulator ROCMAS, which numerically solves the coupling between fluid flow and fracture deformation. Whereas each single approach is insufficient to explain the complete test data, a combination of the results yields an understanding of the flow regimes taking place during the test.     

The effects of food essential oils on cardiovascular diseases: A review

Essential oils (EO) are complex secondary metabolites, which are produced by aromatic plants and identified by their powerful odors. Present studies on EO and their isolated ingredients have drawn the attention of researchers to screen these natural products and evaluate their effect on the cardiovascular system. Some EO, and their active ingredients, have been reported to improve the cardiovascular system significantly by affecting vaso-relaxation, and decreasing the heart rate and exert a hypotension activity. Several mechanisms have been proposed for the role of EO and their main active components in promoting the health of the cardiovascular system. The objective of this review is to highlight the current state of knowledge on the functional role of EO extracted from plants for reducing the risk of cardiovascular diseases and their mechanisms of action. Research on EO has the potential to identify new bioactive compounds and formulate new functional products for the treatment of cardiovascular diseases such as arterial hypertension, angina pectoris, heart failure, and myocardial infarction.     

Using internal domain-specific languages to inherit tool support and modularity for model transformations

Software and Systems Modeling - Model-driven engineering (MDE) has proved to be a useful approach to cope with today’s ever-growing complexity in the development of software systems;...     

Relaxation Pathways in Metallic Glasses

At temperatures below the glass transition temperature, physical properties of metallic glasses, such as density, viscosity, electrical resistivity or enthalpy, slowly evolve with time. This is the process of physical aging that occurs among all types of glasses and leads to structural changes at the microscopic level. Even though the relaxation pathways are ruled by thermodynamics as the glass attempts to re-attain thermodynamic equilibrium, they are steered by sluggish kinetics at the microscopic level. Understanding the structural and dynamic pathways of the relaxing glassy state is still one of the grand challenges in materials physics. We review some of the recent experimental advances made in understanding the nature of the relaxation phenomenon in metallic glasses and its implications to the macroscopic and microscopic properties changes of the relaxing glass.     

Correlation of Ⅲ/Ⅴ semiconductor etch results with physical parameters of high-density reactive plasmas excited by electron cyclotron resonance

Reactive ion etching is the interaction of reactive plasmas with surfaces. To obtain a detailed understanding of this process, significant properties of reactive composite low-pressure plasmas driven by electron cyclotron resonance(ECR) were investigated and compared with the radial uniformity of the etch rate. The determination of the electronic properties of chlorine-and hydrogen-containing plasmas enabled the understanding of the pressure-dependent behavior of the plasma density and provided better insights into the electronic parameters of reactive etch gases. From the electrical evaluation of I(V) characteristics obtained using a Langmuir probe,plasmas of different compositions were investigated. The standard method of Druyvesteyn to derive the electron energy distribution functions by the second derivative of the I(V)characteristics was replaced by a mathematical model which has been evolved to be more robust against noise, mainly, because the first derivative of the I(V) characteristics is used. Special attention was given to the power of the energy dependence in the exponent. In particular, for plasmas that are generated by ECR with EM modes, the existence of Maxwellian distribution functions is not to be taken as a self-evident fact, but the bi-Maxwellian distribution was proven for Ar-and Kr-stabilized plasmas. In addition to the electron temperature, the global uniform discharge model has been shown to be useful for calculating the neutral gas temperature. To what extent the invasive method of using a Langmuir probe could be replaced with the noninvasive optical method of emission spectroscopy, particularly actinometry, was investigated,and the resulting data exhibited the same relative behavior as the Langmuir data. The correlation with etchrate data reveals the large chemical part of the removal process—most striking when the data is compared with etching in pure argon. Although the relative amount of the radial variation of plasma density and etch rate is approximately ?5%, the etch rate shows a slightly concave shape in contrast to the plasma density.     

Correlation of III/V semiconductor etch results with physical parameters of high-density reactive plasmas excited by electron cyclotron resonance

Reactive ion etching is the interaction of reactive plasmas with surfaces. To obtain a detailed understanding of this process, significant properties of reactive composite low-pressure plasmas driven by electron cyclotron resonance (ECR) were investigated and compared with the radial uniformity of the etch rate. The determination of the electronic properties of chlorine-and hydrogen-containing plasmas enabled the understanding of the pressure-dependent behavior of the plasma density and provided better insights into the electronic parameters of reactive etch gases. From the electrical evaluation of I(V ) characteristics obtained using a Langmuir probe, plasmas of different compositions were investigated. The standard method of Druyvesteyn to derive the electron energy distribution functions by the second derivative of the I(V ) characteristics was replaced by a mathematical model which has been evolved to be more robust against noise, mainly, because the first derivative of the I(V ) characteristics is used. Special attention was given to the power of the energy dependence in the exponent. In particular, for plasmas that are generated by ECR with EM modes, the existence of Maxwellian distribution functions is not to be taken as a self-evident fact, but the bi-Maxwellian distribution was proven for Ar-and Kr-stabilized plasmas. In addition to the electron temperature, the global uniform discharge model has been shown to be useful for calculating the neutral gas temperature. To what extent the invasive method of using a Langmuir probe could be replaced with the non-invasive optical method of emission spectroscopy, particularly actinometry, was investigated, and the resulting data exhibited the same relative behavior as the Langmuir data. The correlation with etchrate data reveals the large chemical part of the removal process—most striking when the data is compared with etching in pure argon. Although the relative amount of the radial variation of plasma density and etch rate is approximately ±5%, the etch rate shows a slightly concave shape in contrast to the plasma density.