Native plant proteins such as gluten, zein, soy and pea protein were chemically modified by acylation reactions using palmitic acid chloride and alkenyl‐substituted succinic anhydrides, respectively. The goal of this work was the development of novel, biodegradable protein materials, which are processable by thermoplastic shaping in extruders. Structures and properties of modified plant proteins were characterized by elementary analysis, IR, DSC, TGA, water retention analysis, and tensile tests. The biodegradability of the acylated protein derivatives has been demonstrated. It can be concluded that the chosen plant proteins are suitable for acylation reactions leading to fusible thermoplastic materials with improved water‐resistance. However, resultant extruded articles possess mostly high brittleness combined with low tensile strength. An improved processability and mechanical performance of the acylated products can be achieved by addition of only 10% glycerol.
In this study a mathematical model of heat and mass transfer performance of a wavy fin-and-tube heat exchanger under wet surface condition is presented. The heat exchanger is a counterflow heat exchanger in which humid air and liquid are flowing in opposite direction. A water film that causes evaporative cooling of the humid air is circulated on the humid air side. The heat and mass transfer equations are first derived for fully wet heat exchanger and then by defining a wettability parameter, these equations are obtained for partially wet heat exchanger. In modeling, values of Lewis number and wettability parameter are not necessarily specified as unity. The temperature distributions of humid air, liquid and water film, and relative humidity distribution of humid air are obtained numerically. The theoretical results are found to be in good agreement with the available experimental measurements. 相似文献
Decades ago, we and many other groups showed a nucleo-cytoplasmic translocation of La protein in cultured cells. This shuttling of La protein was seen after UV irradiation, virus infections, hydrogen peroxide exposure and the Fenton reaction based on iron or copper ions. All of these conditions are somehow related to oxidative stress. Unfortunately, these harsh conditions could also cause an artificial release of La protein. Even until today, the shuttling and the cytoplasmic function of La/SS-B is controversially discussed. Moreover, the driving mechanism for the shuttling of La protein remains unclear. Recently, we showed that La protein undergoes redox-dependent conformational changes. Moreover, we developed anti-La monoclonal antibodies (anti-La mAbs), which are specific for either the reduced form of La protein or the oxidized form. Using these tools, here we show that redox-dependent conformational changes are the driving force for the shuttling of La protein. Moreover, we show that translocation of La protein to the cytoplasm can be triggered in a ligand/receptor-dependent manner under physiological conditions. We show that ligands of toll-like receptors lead to a redox-dependent shuttling of La protein. The shuttling of La protein depends on the redox status of the respective cell type. Endothelial cells are usually resistant to the shuttling of La protein, while dendritic cells are highly sensitive. However, the deprivation of intracellular reducing agents in endothelial cells makes endothelial cells sensitive to a redox-dependent shuttling of La protein. 相似文献
Identification, assessment and remediation of a large-scale groundwater contamination requires a profound knowledge of the geological structure to predict the fate of contaminants in the subsurface. Within the SAFIRA-project, a model sector of the Bitterfeld/Wolfen area was chosen to transfer the structural geological data of the Tertiary and Quarternary aquifer units into a digital geological model. Using 125 selected drillholes as a base of 28 networked cross-sections, small-scale lithological and structural heterogeneities, in particular of the Quarternary layers, could be assigned to 31 litho-stratigraphic sedimentation units and depicted using a 10 × 10 m GIS grid. An assignment of hydraulic parameters to individual sedimentary bodies allows a combination with flow and transport models. The structural model was generated by combining gridding sections and additional point and lateral information of sediment distribution and allows -beyond visualisation purposes- volumetric calculations of distinct sedimentary units, which are relevant for an assessment of retardation processes in the remaining lignite seam. The present structural model is the base for a “Spatial Model Bitterfeld” and anables further investigations on the environmental impact of different scenarios.相似文献
The article presents results of an internet research on product-service systems. Web sites showing interesting practical examples and studies available online are presented to point out the practical relevance of innovative combinations of products and services. The multiplicity of research projects found on the internet shows that this phenomenon is also discussed intensively in research. These projects have been categorized by analyzing their web sites. Furthermore, the results of the internet research highlight a high diversity of terms for describing the concept of product-service systems. As a consequence, orientation in this subject area is hindered. 相似文献
Molds for micro forming processes require specific functional surfaces to provide optimized tribological condition for forming processes. Such topographies with microscopic dimensions can for instance be generated by lithographical methods. However, a main disadvantage of these processes is their low flexibility, e.g. changing the structures to be generated causes extensive adaptations in the manufacturing process. Therefore, mechanical precision machining processes like micro milling, micro grinding and micro polishing are appropriate processes for the manufacture of micro molds of manifold shapes and with well suited micro topographies. 相似文献