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971.
Phosphorus was added to Fe-50 wt.% Ni in the form of a coated composite powder via an electroless plating process. Addition
of phosphorus to Fe-50 wt.% Ni facilitated increases in density and grain size, both of which were beneficial to magnetic
performance. Because of the homogeneous distribution of phosphorus in the powder, the optimal phosphorus addition was much
lower than for those using Fe3P as the phosphorus precursor. The optimal phosphorus addition was close to its maximum solubility in Fe-50 wt.% Ni (about
0.5 wt.%), above which precipitation of excessive phosphorus in the form of iron nickel phosphide, (Fe,Ni)3P, effectively degraded the magnetic properties of Fe-50 wt.% Ni. Without the addition of phosphorus, good magnetic properties
could be achieved only when the sintering temperature was high enough (>1200 °C) to result in a high sintered density and
large grains in the sintered structure. 相似文献
972.
Pil-Ryung Cha Ho-Seok Nam Dae-Yeong Jeon Jong-Kyu Yoon 《Metals and Materials International》2002,8(1):119-127
This study presents a simple and robust algorithm for the optimal design of the system with coupled complex transport phenomena:
the transport phenomena comprise fluid flow, heat and mass transfer. The (1+1)-Evolution Strategy method is adopted as the optimization method. In order to analyze the transport phenomena in the complex geometry generated
during the optimization procedure, thefinite volume method with a boundary fitted curvilinear coordinate system is used. To confirm the validity of the present method, the optimal
design for the inner shape of the simplified two-dimensionalSubmerged Entry Nozzle in the continuous slab caster is conducted. It is shown that the resulting design of the nozzle is consistent with the purpose
and constraints of the design. 相似文献
973.
Mingru Zhang Jianqing Qian Haicheng Gu 《Journal of Materials Engineering and Performance》2007,16(5):635-639
Metallographic structures of carbide-free bainite steel wheel rim are mainly composed of supersaturated lath ferrite and retained
austenite film among bainitic ferrite laths. It is suspected that supersaturated ferrite and retained austenite are likely
to decompose under the influence of temperature change and mechanical stress. Stability of wheel rim structure is studied
by means of x-ray diffraction, dye microscopy, and micro-hardness test. When the samples are tempered in the range of 150-350 °C,
the retained austenite films are at the state of relative stability. Fifty percent of retained austenite is decomposed when
the sample is tempered at 400 °C. Microhardness increases when the sample is tempered at 150 °C. The decrease in hardness
is mild when the samples are tempered from 200 to 500 °C. The mechanical stability of retained austenite film is studied with
tensile sample under the effect of tensile stress. The retained austenite appears to be stable in low and middle degree of
deformation, and decomposition occurs at great amount of deformation. Diffraction peak of carbide is not found in all above
experiments. The steel enriched silicon prevents the carbide precipitation during the transformation. It indicates the carbide-free
bainite wheel steels have an excellent thermal and mechanical stability. 相似文献
974.
Patricia Muñoz-Escalona Shreyes Melkote Kai Liu 《Journal of Materials Engineering and Performance》2005,14(5):582-590
In recent years, the finite element method (FEM) has become the main tool for simulating the metal cutting process because
research based on trial and error is time consuming and requires high investment. Early studies were done by different investigators.
In this research AISI 52100, hardened steel (62 HRC) was selected for an orthogonal machining process as well as metal cutting
simulation using the software DEFORM-2D. This software is based on a forging process and has been adapted to an orthogonal
machining process. The results of simulated cutting forces were compared with experimental cutting force data to validate
the orthogonal cut simulation. Also, the surface roughness was measured, and the influence of the stress, strain, and temperature
on the surface roughness was studied. 相似文献
975.
Tanya Kmecko Xiaoyu Wang Patty Wisian-Neilson 《Journal of Inorganic and Organometallic Polymers and Materials》2007,17(2):413-421
Summary The surface reactivity of poly(methylphenylphosphazene), PMPP, and its derivatives containing silane, PMPP-SiH, and alcohol,
PMPP-OH, substituents was investigated. These polymers were fabricated into films by casting from THF solutions and reactions
were carried out at the interface between solid film samples and solutions. The surface of PMPP was successfully modified
by deprotonation under dilute conditions followed by reactions with RMe2SiCl [where R = CH=CH2, and H]. While surfaces of PMPP-OH were not readily modified, those containing Si-H groups reacted with oxygen when heated
and with carbon tetrachloride. The polymer surfaces were examined by contact angle measurements, attenuated total reflectance
infrared spectroscopy (ATR-IR), and scanning electron microscopy (SEM).
We dedicate the paper to Christopher W. Allen in recognition of his outstanding contributions to inorganic ring and polymer
chemistry. 相似文献
976.
The influence of nonsolvent, crystallinity of the polymer film, and addition of dodecane (a poor solvent for the polymer and for the nonsolvent) on the morphology of polylactides films has been investigated and was related to phase separation behavior. Both amorphous poly‐DL ‐lactide (PDLLA) and crystalline poly‐L ‐lactide (PLLA) were dissolved in dichloromethane, and subsequently films were made by immersion in nonsolvent baths. PDLLA gave dense films without any internal structure, since the structure was not solidified by crystallization or glassification. PLLA films show varying structure depending on the nonsolvent. With methanol, asymmetric morphologies were observed as a result from combined liquid‐liquid demixing and crystallization, while with water symmetric spherulitic structures were formed. As a next step, dodecane was added, which is not miscible with the nonsolvent, and we found it to have a strong influence on the morphology of the films. The PDLLA films with dodecane did not collapse: a closed cell structure was obtained. In PLLA films, dodecane speeds up phase separation and induces faster crystallization in the films, and the porosity, size of the pores, and interconnectivity increased. When the PLLA solutions were subjected to a heat pretreatment, crystallization could be postponed, which yielded a cellular structure around dodecane, which did not contain spherulites anymore. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 104: 959–971, 2007 相似文献
977.
E. I. Basaldella J.C. Tara G. Aguilar Armenta M. E. Patiño Iglesias 《Journal of Porous Materials》2007,14(3):273-278
Samples of mesoporous silica SBA-15 were prepared under hydrothermal conditions where Cu cations were incorporated to the
structure by impregnation in order to compare the adsorption behavior in the presence and absence of this element. The adsorption/desorption
equilibrium isotherms of propylene, propane, and N2 were measured to evaluate their usefulness in the propane/propylene separation.
All the adsorption isotherms of SBA-15 measured in the absence of Cu cations were described by the Freundlich equation, while
the adsorption isotherms of propane on Cu/SBA-15 were better represented by the Henry equation and those of propylene were
satisfactorily described by the Langmuir model in the range P < 100 Torr. The adsorption uptake of propylene increased and that of propane decreased in Cu/SBA-15 as compared to the amounts
observed in the SBA-15 sample. The presence of Cu atoms in the adsorbent lattice increased the selectivity towards propylene.
Under some working conditions the adsorbed amount of propylene in Cu/SBA-15 sample was totally reversible and the propane
uptake, negligible. 相似文献
978.
ESCA (electron spectroscopy for chemical analysis) studies of β-C2S in the early stages of hydration have yielded valuable information on the chemical changes on the hydrating surface. These changes are less pronounced than, but very similar to, those noted for C3S. The data indicate that, although β-C2S hydrates more slowly than C3S, the same hydration mechanism applies to both. The studies also suggest surface hydroxylation as a first step in the hydration process. 相似文献
979.
Luis A. Pérez-Maqueda José Manuel Criado Concepción Real 《Journal of the American Ceramic Society》2002,85(4):763-768
A new method for the kinetic analysis of the initial stage of sintering for constant-heating-rate data has been proposed. Unlike all of the methods previously reported in the literature, this new method proposed here allows the simultaneous determination of the activation energy and the kinetic model from a single dilatometric curve recorded under a linear-heating-rate program. The proposed method has been tested with simulated sintering curves and experimental results have been obtained for the sintering of a rutile sample. 相似文献
980.
The solubility parameter of poly(ethylene oxide) at 25°C has been determined using the method developed by DiPaola-Baranyi and Guillet, by the extrapolation of the values of the interaction parameter χ, at high temperatures, ranging from 70°–90°, 90°–110° and 110°–130°C down to 25°C. The values of the solubility parameter obtained, depending on the temperature ranges employed, are 9.8, 9.9 and 10.1, respectively. 相似文献