Characterization of the chemically deposited hydroxyapatite coating on a titanium substrate

Bioactive hydroxyapatite (HA) coating on titanium (Ti) implant can be used as a drug delivery device. A controlled release of drug around the implant requires the incorporation of drug into the coating material during the coating process. HA coating was prepared using a two-step procedure in conditions suitable for simultaneous incorporation of the protein-based drug into the coating material. Monetite coating was deposited on Ti substrate in acidic condition followed by the transformation of the monetite coating to HA. X-ray diffraction (XRD) confirmed the formation of the monetite phase at the first step of the coating preparation, which was transformed into HA at the second step. Fourier transform infrared spectroscopy demonstrated typical bands of a crystallized carbonated HA with A- and B-type substitution, which was confirmed by the XRD refinement of the structural parameters. Scanning electron microscope was used to observe the morphology of monetite and HA coatings. Adhesion of the coatings was measured using a scratch tester. The critical shearing stress was found to be 84.20 ± 1.27 MPa for the monetite coating, and 44.40 ± 2.39 MPa for the HA coating.     

Simulation of microbial mass and its variation in biofilm systems using STELLA

Biofilm systems have been extensively used for treating different types of wastewater. Difficulty in determination of microbial mass in fixed‐film reactors has been always the greatest problem in evaluating effects of loading rates on the microbial population in such reactors. For this reason, the effect of operating parameters such as organic loadings on the available microbial mass in the system and solids retention time (SRT) have not been discussed in detail. In this study an innovative methodology was developed to simulate the quantity of microbial mass in an aerated submerged fixed‐film reactor (ASFFR) reactor. After determination of kinetic parameters, a dynamic model was developed using STELLA, popular dynamic modeling software, to simulate the microbial mass in the reactor at run time. The pilot plant study was performed with two different surface media and at different loading rates from 2.37 to 19.56 g m^?2 d^?1. Furthermore, the effect of different organic loadings on the accumulation of microbial mass and SRT have been studied and the relevant mathematical relationships were presented. This method makes the evaluation of biofilm system simple and practical without taking samples to quantify microbial mass in reactors. Copyright © 2006 Society of Chemical Industry     

Study on automatic control of arc gap in robotic TIG welding

This paper presents a method for automatic control of arc length in tungsten inert gas (TIG) welding process using the arc voltage. By using this method, the role of operator in arc length control is played by an automatic control system based on a predefined arc voltage value for any special welding operation. A dynamic model for feed-rate mechanism and the relation between variations of arc length and voltage are described in details. Using a proportional-integral controller, variations of arc length in welding path is compensated with an automatic feed-rate mechanism in a normal direction to the welding path. By keeping the voltage constant during the process, a stable weld with higher quality and better appearance is obtained specially in welding of uneven surfaces. Theoretical and practical investigations show that the suggested method is able to control the TIG welding process successfully. Test results show that an accurate weld is obtained without the interference of the operator, and by comparing the predefined values of arc voltage with what is practically obtained, the welding gap is automatically adjusted.     

A numerical investigation of various phase change models on simulation of saturated film boiling heat transfer

There is a great variety of two‐phase models in numerical simulations. The performance of each model complicates the numerical simulation of boiling. The challenge of the right choice of heat and mass transfer models makes this type of problem more complicated. In this research work, the volume of the fluid two‐phase model has been used to simulate the film boiling of saturated liquid. The geo‐reconstruction method also reconstructs the interface of two phases. The models of the sharp interface, Lee and Tanasawa have been employed among the available models for calculating the phase change rate and the source terms of the equations. The Numerical solver of the phase‐change is verified through the Stefan one‐dimensional vaporizing problem. Correct empirical coefficients used in both Lee and Tanasawa models are presented. Bubble detachment time, flow pattern, the periodic Nusselt number, and the bubble form have been investigated in all three phase change models. Two Berenson and Klimenko experimental correlations have been used for verification of Nusselt number derived from simulations. The Nusselt number shows a proper fit with the Klimenko's Nusselt number. Obtained Nusselt number demonstrates the Lee model is more precise than other phase change models in simulating of film boiling on the flat plate.     

Hydrocracking and hydrodesulfurization of diesel over zeolite beta-containing NiMo supported on activated red mud

NiMo nanocatalysts supported on activated red mud with different zeolite beta contents were successfully prepared by impregnation technique. Their hydrocracking and hydrodesulfurization activities were evaluated with two different kinds of diesel feed (iso diesel and heavy diesel) in a fixed bed reactor at ambient pressure and 500 °C. Physico-chemical properties of synthesized samples were characterized using the methods of XRF, XRD, FESEM, BET, FTIR and NH₃-TPD. The results indicated that zeolite incorporation resulted in a significant increase in specific surface area (BET result) and acidic strength (TPD result) of nanocatalysts. FESEM analysis confirmed that the particles size of zeolite-containing NiMo/ARM was less than 100 nm and the average size of particles was about 30 nm. Hydrocracking results illustrated that incorporation of zeolite beta improved cracking activity considerably. In addition, NiMo nanocatalyst containing 37.5 wt% of zeolite had the highest yields of desirable products (naphtha, kerosene and diesel) and the highest conversion. Moreover, the flash point and viscosity of the liquid product decreased notably the nanocatalysts with 37.5 wt% and 12.5 wt% of zeolite were able to remove approximately 96% and 72% of the sulfur content of iso diesel and heavy diesel, respectively.     

Finding Mobility Pattern of Movable Target in Wireless Sensor Networks by Crowdsourcing Designed Mechanism

Wireless Personal Communications - Target tracking in wireless sensor networks is one of the well-known applications of such networks. The use of sensor-based electronic devices is becoming...     

Automatic detection of depression symptoms in twitter using multimodal analysis

The Journal of Supercomputing - Depression is the most prevalent mental disorder that can lead to suicide. Due to the tendency of people to share their thoughts on social platforms, social data...     

A low pressure SWCNT-ENM sandwich membrane system for the removal of PPCPs from water

While carbon nanotubes are known as efficient adsorbents for removal of a number of contaminants from water, the possibility of their leaching into drinking water has prevented their application in water treatment. In this study, single walled carbon nanotubes (SWCNT) were sandwiched between two electrospun nanofibre membranes (ENM). The relatively small pore size of the ENM prevented the mechanically entangled nanotubes from passing through and contaminating the water. The performance of the SWCNT-ENM was evaluated in a lab-scale setup for the removal of PPCPs. For this purpose, a feed solution spiked with known concentrations of six PPCPs was passed through the membrane system. The target substances included acetaminophen (ACT), bezafibrate (BZF), iopromide (IOP), diclofenac (DCF), carbamazepine (CBZ), and sulphamethoxazole (SMX). The same test was also conducted using a single contaminant (ACT). Results demonstrated a decrease in the overall percent removal of PPCPs as feed flow rate and PPCP concentration increased. For multi-component feeds containing equal amounts of the aforementioned PPCPs, the overall percent removal decreased from 90.8% to 71.0% when increasing the feed concentration from 30 to 600 μg/L. Experiments using sandwiched powdered activated carbon (PAC) showed that the dynamic adsorption capacity of PPCPs by SWCNT-ENM was higher than that of PAC-ENM, and remained unaffected by the feed composition. In addition, the high porosity of this novel membrane allowed for flow of water with low resistance such that the trans-membrane pressure was found to be as low as 4 kPa at a pure water flux of 330 L/m²h.     

The Enhancement of Mine Waste Stability Using Biocementation

Journal of Mining Science - There are large amounts of waste deposits around mines and mineral processing plants, and their instability is one of the major concerns in mining industries. One of the...