Surface evaluation and electrochemical behaviour of doped silane pre-treatments on galvanised steel substrates

The present work aims at evaluating the surface morphology and the corrosion resistance of galvanised steel substrates pre-treated with bis-[triethoxysilylpropyl] tetrasulfide silane (BTESPT) solutions doped with cerium nitrate or zirconium nitrate. The silane pre-treatment leads to the formation of a silane coating in the metallic surface. The surface morphology of this coating was studied by atomic force microscopy (AFM) and scanning electron microscopy (SEM).     

The shortening fraction of myocardial fibers and its layered distribution, as derived from cine-MR imaged left ventriculograms. An approach for evaluating globar left ventricular function

PURPOSE: To evaluate the mean shortening fraction and its SD through the wall calculated from multiple cine-MR views, as an estimate of left ventricular globar function. MATERIAL AND METHODS: The average myocardial fiber shortening fraction was calculated by means of a simple truncated ellipsoid nested shell model. Left ventricular parameters, acquired by cine-MR imaging, from 20 healthy volunteers served as input. Fiber angles, ventricular torsion and a gradient increase in wall thickening from epicard to endocard were part of the model. RESULTS: The average fiber shortening fraction was 0.203 (0.158-0.246) +/- 0.021 diastolic lengths. It varied only moderately with variations in fiber angle values and not at all when the torsion angles were varied within physiological limits. The average shortening fraction correlates well with the systolic increase in chamber oblonguity (k = 0.837), with the ejection fraction (k = 0.877), and even better with the calculated wall thickening (k = 0.973). The average epicardial shortening fraction 0.169 (0.142-0.202) +/- 0.016 increased gradually through the wall to the endocardial value 0.250 (0.212-0.290) +/- 0.024. The increase in chamber length-width ratio from diastole to systole reduced the SD of the shortening fraction through the wall layers to a minimum. CONCLUSION: The fiber shortening fraction expresses the layered contraction of the myocardial wall, the wall thickening, and also the endocardial wall motion. The ejection fraction expresses only the latter. The shortening fraction and its SD through the wall may prove a valuable additional tool for estimating ventricular globar function.     

Adaptive critic methods for stochastic systems with input-dependent noise

In this paper, a novel dual heuristic programming (DHP) adaptive-critic-based cautious controller is proposed. The proposed controller avoids the pre-identification training phase of the forward model by taking into consideration model uncertainty when calculating the control law. It is suitable for linear and nonlinear, deterministic and stochastic control systems that are characterized by functional uncertainty. Convergence of the proposed DHP adaptive critic method to the correct value of the cost function is proven by evaluating analytically the correct value of the cost function, which satisfies the Bellman equation, and compares it to that calculated by the proposed method in a simple linear quadratic example. Moreover, the performance of the proposed cautious controller is demonstrated on linear one-dimensional and multidimensional examples.     

Static and low-frequency noise characterization in submicron MOSFETs for memories cells applications

In this paper, we present the extraction of oxide traps properties of n-metal-oxide-semiconductor (N-MOS) field effect transistors with W×L=0.5×0.1 μm² using low-frequency (LF and random telegraph signal) noise and static I(V) characterizations. The impact of oxide thickness, on static and noise parameters is analyzed. Static measurements on N-MOS devices with different tunnel oxide thickness show anomalies (a significant increase in V_t values for low temperature and kink effect) attributed to traps located in the oxide. From LF noise analysis we find that 1/f noise stems from carrier number fluctuations. The slow oxide trap concentration deduced from the noise data is about 10¹⁵ eV/cm³ in agreement with the state-of-the-art gate oxides. Finally, drain current RTS amplitude as large as 10% have been observed.     

Triacylglycerols and Phospholipids Composition of Caper Seeds (<Emphasis Type="Italic">Capparis spinosa</Emphasis>)

The goal of this study is to evaluate for the first time the composition of triacylglycerols (TAG) using ESI-TOF-MS and phospholipids species using HPLC–ESI-TOF-MS of two Capparis spinosa seed oil populations. Results show that LOO, LOP, LLO, OOO, PLL and POO were the major molecular species of triacylglycerol detected in caper seeds; where L represents linoleic acid; O, oleic acid; and P, palmitic acid. The TAG composition was significantly different among the two C. spinosa populations. In Ghar el Melh population, LOO (15.7%) was detected as the dominant TAG molecular species, followed by LOP (13.2%), LLO (12.0%) and OOO (11.4%); while, the dominant fraction was LLO (14.2%) followed by LOO (14.1%), LOP (11.5%) and PLL (10.5%) in Chouigui samples. The major component in the phospholipids fraction was phosphatidylinositol (ca. 54–91%), followed by phosphatidylglycerol, phosphatidylethanolamine and phosphatidic acid. A variety of molecular species within each class were identified. The major component in all phospholipids species contains a C-18:1 lipid chain. C16:0/C18:2-PI (ca. 28–31%) was the most abundant PI. PG species were mainly C18:2/C18:1-PG (25–32%). The major PE was C18:1/C18:1-PE (44–75%). The major PA species was C18:1/C18:1-PA (22–24%).     

Modeling and Simulation of a PMSG-based Marine Current Turbine System under Faulty Rectifier Conditions

This paper deals with the modeling and simulation of a permanent magnet synchronous generator (PMSG)-based marine current turbine (MCT) under faulty rectifier conditions. The modeling of the generator is established in the synchronous rotating d-q reference frame. The control of the speed, the d-axis current, and the q-axis current are achieved using proportional integral (PI) correctors. The faulty mode deals with the study of single and multiple open-switch damages appearing in the pulse width modulation (PWM) power rectifier. Simulations are carried out to highlight the proposed PMSG-based MCT performance in both cases using MATLAB/Simulink environment.     

Spectral Discretization of the Axisymmetric Vorticity,Velocity and Pressure Formulation of the Stokes Problem

We consider the Stokes problem in a three-dimensional axisymmetric bounded domain with non standard conditions which involve the normal component of the velocity and tangential component of the vorticity. We reduce the three-dimensional problem into a two-dimensional one and we write a variational formulation of it with three independent unknowns: the vorticity, the velocity and the pressure. Then we propose a discretization by spectral methods which relies on this formulation. A detailed numerical analysis leads to optimal error estimates for the three unknowns and numerical experiments confirm the interest of the discretization.     

Esterification of fatty acid over Tunisian acid activated clay: kinetic study

Tunisian acid activated clay was investigated as catalyst in the esterification of stearic acid with ethyl alcohol, carried out in a semi-continuous reactor. Kinetic study shows that the reaction is first order with respect to acid concentration. The activation energy found was 21 kJ/mol. This result suggests that the reaction process was controlled by a diffusional step. A kinetic model, giving the apparent constant rate as a function of temperature and catalyst concentration, has been established. This equation has been then successfully applied for a complex mixture of fatty acid.     

A Survey of Industry Advisory Board Operation and Effectiveness in Engineering Education

Voluntary boards composed primarily of industry practitioners who give aid and advice are almost universal in engineering education programs, though there has been little published research on this subject. Based on a survey of 90 engineering school directors and advisory board members, this research characterizes the operation, makeup, and effectiveness of advisory boards. The study shows that effective boards have a clear understanding of their role and limitations in influencing curriculum, encourage engagement with students, have formal procedures for involvement in ABET accreditation, and are well coordinated with the larger educational institution. Boards can be effective with or without involvement in fundraising, but it is essential that fundraising expectations be clearly understood and agreed upon by the school and the board. Boards composed largely of members with close ties to the institution, generally alumni, will be more engaged as advocates of the program and will contribute more financially.