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51.
Advanced Monte Carlo simulations of the adsorption of chiral alcohols in a homochiral metal‐organic framework
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Zhiwei Qiao Ariana Torres‐Knoop David Dubbeldam David Fairen‐Jimenez Jian Zhou Randall Q. Snurr 《American Institute of Chemical Engineers》2014,60(6):2324-2334
Grand canonical Monte Carlo (GCMC) simulations with configurational biasing were used to study the enantioselective adsorption of four alkanols in a homochiral metal‐organic framework, known as hybrid organic‐inorganic zeolite analogue HOIZA‐1. Conventional GCMC simulations are not able to converge satisfactorily for this system due to the tight fit of the chiral alcohols in the narrow pores. However, parallel tempering and parallel mole‐fraction GCMC simulations overcome this problem. The simulations show that the enantioselective adsorption of the different (R,S)‐alkanols is due to the specific geometry of the chiral molecules relative to the pore size and shape. © 2014 American Institute of Chemical Engineers AIChE J, 60: 2324–2334, 2014 相似文献
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54.
Scott J. Robertson Marina B. Ruggles-Wrenn Randall S. Hay Theodore Shillig Ronald Mitchell Brian Kroeger Logan Gumucio 《Journal of the American Ceramic Society》2020,103(2):1358-1371
A facility for testing SiC fiber tows in static fatigue and creep at elevated temperatures in air and steam was developed. Static fatigue of Hi-Nicalon™-S fibers was investigated at 800°C-1100°C at applied stresses between 115 and 1250 MPa in air, in Si(OH)4(g)-saturated steam, and in unsaturated steam. Fibers tested in Si(OH)4(g)-saturated steam and in air had silica scales throughout the test sections, but those tested in unsaturated steam did not develop scales near the steam injection point. Fiber lifetimes in static fatigue were shortest in unsaturated steam, intermediate in Si(OH)4(g)-saturated steam, and longest in air. Failure strains did not exceed 0.3%. Steady-state strain rates and static fatigue lifetimes are modelled empirically by the Monkman-Grant relationship. Failure mechanisms are discussed. 相似文献
55.
Grain growth of ZnO in the presence of a liquid phase of the ZnO–BaO system has been studied for temperatures from 1300° to 1400°C. The specimens were treated in boiling water and the grains were separated by dissolving the matrix phase in an ultrasonic bath. As a consequence three-dimensional grain size measurements were possible. Microstructural examination shows some grain coalescence with a wide range of neck size ratios and corresponding dihedral angles, however, most grains are isolated. Lognormal grain size distributions show similar shapes, indicating that the growth mechanism is invariant over this time and temperature. All regressions between G n and time for n = 2 and 3 proved statistically significant. The rate constants calculated with the growth exponent set to n = 3 are on the same order of magnitude as in metallic systems. The apparent activation energy for growth is estimated between 355 and 458 kJ/mol. 相似文献
56.
Degradation of Nextel™ 610‐based oxide‐oxide ceramic composites by aluminum oxychloride decomposition products
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Randall S. Hay Kristin A. Keller Larry P. Zawada Nathan S. Jacobson Geoff E. Fair 《Journal of the American Ceramic Society》2018,101(9):4203-4223
Nextel? 610 alumina fibers and alumina‐YAG (yttrium‐aluminum garnet) matrices were used to make oxide‐oxide ceramic matrix composites (CMCs) with and without monazite (LaPO4) fiber‐matrix interfaces. Twelve sequential aluminum oxychloride (AlOCl) infiltrations with 1 hour heat treatments at 1100°C and a final 1 hour heat treatment at 1200°C were used for matrix densification. This matrix processing sequence severely degraded CMC mechanical properties. CMC tensile strengths and interlaminar tensile (ILT) strengths were less than 10 MPa and 1 MPa, respectively. Axial fracture of Nextel? 610 fibers was observed after ILT testing, highlighting the extreme degradation of fiber strength. Extensive characterization was done to attempt to determine the responsible degradation mechanisms. Changes in Nextel? 610 fiber microstructure after CMC processing were characterized by optical microscopy, SEM, and extensively by TEM. In AlOCl degraded fibers, grain boundaries near the fiber surface were wetted with a glass that contained Y2O3/SiO2 or Y2O3/La2O3/P2O5/SiO2, and near‐surface pores were partially filled with Al2O3. This glass must also contain some Al2O3 and initially some chlorine. AlOCl decomposition products were predicted using the FactSage® Thermochemical code, and were characterized by mass spectrometry. Effects of AlOCl precursors on monazite coated and uncoated Nextel? 610 fibers tow and filament strength were evaluated. A mechanism for the severe degradation of the oxide‐oxide CMCs and Nextel? 610 fibers that involves subcritical crack growth promoted by release of chlorine containing species during breakdown of intergranular glasses in an anhydrous environment is proposed. 相似文献
57.
Alkyl and alk-1-enyl glyceryl ethers have been identified in the phospholipids of three insect species, the American cockroach
(Periplaneta americana), the tobacco budworm (Heliothis virescens), and the boll weevil (Anthonomus grandis). Glyceryl ethers were not detected in the neutral lipids. The ethers were found in the phospholipid fraction of whole insects
and in isolated fat body tissue. The ether content varied among the three insect species, and fluctuated during various developmental
stages. Gas liquid chromatographic analysis of the alkyl glyceryl ethers and aldehydes derived from the alk-1-enyl glyceryl
ethers of the cockroach and budworm whowed striking differences in chain length. However, the hydrocarbon side-chain of the
two ether fractions were similar in length for each species. Preliminary evidence indicates that 1-14C-acetate can be incorporated into alkyl ethers but not into alk-1-enyl ethers ofHeliothis pupae.
Presented at the AOCS-AACC joint meeting, Washington, D.C., 1968.
Under contract with the U.S. Atomic Energy Commission. 相似文献
58.
Do-Kyun Kwon Clive A. Randall Thomas R. Shrout Michael T. Lanagan 《Journal of the American Ceramic Society》2004,87(6):1088-1092
The dielectric properties and frequency dispersion associated with a dielectric relaxation were evaluated within the perovskite (1− x )BiScO3 – x Ba(Mg1/3 Nb2/3 )O3 solid solution systems (0.7 ≤ x ≤ 1). With increasing BiScO3 , the room-temperature dielectric permittivity at low frequency (100 Hz) increased up to 115 at x = 0.7, and a dielectric relaxation phenomenon was evident. Relaxation parameters were analyzed using several Arrhenius-type equations, and the microwave dielectric property measurement using rectangular wave-guide method enabled confirmation of the extrapolated value of the Arrhenius plot. The result of the microwave dielectric property measurement was also checked with J -function fitting based on the frequency-dependent Gaussian distribution of the associated dielectric loss data at low frequency. 相似文献
59.
Jing Guo Amanda L. Baker Hanzheng Guo Michael Lanagan Clive A. Randall 《Journal of the American Ceramic Society》2017,100(2):669-677
Cold sintering process (CSP) is an extremely low‐temperature sintering process (room temperature to ~200°C) that uses aqueous‐based solutions as transient solvents to aid densification by a nonequilibrium dissolution‐precipitation process. In this work, CSP is introduced to fabricate microwave and packaging dielectric substrates, including ceramics (bulk monolithic substrates and multilayers) and ceramic‐polymer composites. Some dielectric materials, namely Li2MoO4, Na2Mo2O7, K2Mo2O7, and (LiBi)0.5MoO4 ceramics, and also (1?x)Li2MoO4?xPTFE and (1?x)(LiBi)0.5MoO4?xPTFE composites, are selected to demonstrate the feasibility of CSP in microwave and packaging substrate applications. Selected dielectric ceramics and composites with high densities (88%‐95%) and good microwave dielectric properties (permittivity, 5.6‐37.1; Q × f, 1700‐30 500 GHz) were obtained by CSP at 120°C. CSP can be also used to potentially develop a new co‐fired ceramic technology, namely CSCC. Li2MoO4?Ag multilayer co‐fired ceramic structures were successfully fabricated without obvious delamination, warping, or interdiffusion. Numerous materials with different dielectric properties can be densified by CSP, indicating that CSP provides a simple, effective, and energy‐saving strategy for the ceramic packaging and microwave device development. 相似文献
60.
Seth S. Berbano Jing Guo Hanzheng Guo Clive A. Randall 《Journal of the American Ceramic Society》2017,100(5):2123-2135
The recently developed technique of cold sintering process (CSP) enables densification of ceramics at low temperatures, i.e., <300°C. CSP employs a transient aqueous solvent to enable liquid phase‐assisted densification through mediating the dissolution‐precipitation process under a uniaxial applied pressure. Using CSP in this study, 80% dense Li1.5Al0.5Ge1.5(PO4)3 (LAGP) electrolytes were obtained at 120°C in 20 minutes. After a 5 minute belt furnace treatment at 650°C, 50°C above the crystallization onset, Li‐ion conductivity was 5.4 × 10?5 S/cm at 25°C. Another route to high ionic conductivities ~10?4 S/cm at 25°C is through a composite LAGP ‐ (PVDF‐HFP) co‐sintered system that was soaked in a liquid electrolyte. After soaking 95, 90, 80, 70, and 60 vol% LAGP in 1 M LiPF6 EC‐DMC (50:50 vol%) at 25°C, Li‐ion conductivities were 1.0 × 10?4 S/cm at 25°C with 5 to 10 wt% liquid electrolyte. This paper focuses on the microstructural development and impedance contributions within solid electrolytes processed by (i) Crystallization of bulk glasses, (ii) CSP of ceramics, and (iii) CSP of ceramic‐polymer composites. CSP may offer a new route to enable multilayer battery technology by avoiding the detrimental effects of high temperature heat treatments. 相似文献