A direct stiffness analysis of a composite beam with partial interaction

The use of the conventional semi-analytical stiffness method in finite element analysis, in which interpolation polynomials are used to develop the stiffness relationships, leads to problems of curvature locking when beam-type elements are developed for composite members with partial interaction between the materials of which it is comprised. The curvature locking phenomenon that occurs for composite steel–concrete members is quite well reported, and the general approach to minimizing the undesirable ramifications of curvature locking has been to use higher-order polynomials with increasing numbers of internal nodes. This paper presents an alternate formulation based on a direct stiffness approach rather than starting from pre-defined interpolation polynomials, and which does not possess the undesirable locking characteristics. The formulation is based on a more general approach for a bi-material composite flexural member, whose constituent materials are joined by elastic shear connection so as to provide partial interaction. The stiffness relationships are derived, and these are applied to a simply supported and a continuous steel–concrete composite beam to demonstrate the efficacy of the method, and in particular its ability to model accurately both very flexible and very stiff shear connection that causes difficulties when implemented in competitive semi-analytical algorithms. Copyright © 2004 John Wiley & Sons, Ltd.     

A kinetic modelling study of ethane cracking for optimal ethylene yield

Current generation steam cracking plants are considered to be mature. As a consequence it is becoming more and more important to know whether the underlying mechanistic cracking process offers still scope for further improvements. The fundamental kinetic limits to cracking yields have recently been researched in detail for different feed stocks with a new synthesis reactor model, d-RMix, incorporating a large scale mechanistic reaction scheme, SPYRO^® [M.W.M. van Goethem, S. Barendregt, J. Grievink, J.A. Moulijn, P.T.J. Verheijen “Model-based, thermo-physical optimisation for high olefin yield in steam cracking reactors”, Chemical Research and Engineering Developments 88 (2010) 1305–1319]. Mathematical optimization revealed for ethane cracking a maximum ethylene yield of about 67 wt%. with a linear-concave optimal temperature profile along the reaction coordinate with a maximum temperature between 1200 and 1300 K. Further mechanistic analysis of these results showed that the linear-concave shape not only suppresses the successive dehydrogenation and condensation reactions of ethylene, but mainly reduces the role of the ethane initiation reaction to form two methyl radicals.     

Alterations of the glucose metabolism in a triose phosphate isomerase-negative Saccharomyces cerevisiae mutant

The absence of triose phosphate isomerase activity causes an accumulation of only one of the two trioses, dihydroxyacetone phosphate, and this produces a shift in the final product of glucose catabolism from ethanol to glycerol (Compagno et al., 1996). Alterations of glucose metabolism imposed by the deletion of the TPI1 gene in Saccharomyces cerevisiae were studied in batch and continuous cultures. The Deltatpi1 null mutant was unable to grow on glucose as the sole carbon source. The addition of ethanol or acetate in media containing glucose, but also raffinose or galactose, relieved this effect in batch cultivation, suggesting that the Crabtree effect is not the primary cause for the mutant's impaired growth on glucose. The addition of an energy source like formic acid restored glucose utilization, suggesting that a NADH/energy shortage in the Deltatpi1 mutant could be a cause of the impaired growth on glucose. The amount of glycerol production in the Deltatpi1 mutant could represent a good indicator of the fraction of carbon source channelled through glycolysis. Data obtained in continuous cultures on mixed substrates indicated that different contributions of glycolysis and gluconeogenesis, as well as of the HMP pathway, to glucose utilization by the Deltatpi1 mutant may occur in relation to the fraction of ethanol present in the media.     

Detailed kinetic modeling of the thermal degradation of lignins

The aim of this kinetic work is to provide a better understanding of the pyrolysis of lignin and biomasses not only in terms of devolatilazation rate but also of the volatile species released. The complexity of both lignin structure and its degradation mechanism meant that a lumping approach suitable for handling the huge amount of initial, intermediate and final products had to be used. Despite these simplifications, the proposed semi-detailed kinetic scheme involves about 100 molecular and radical species in 500 elementary and lumped reactions. It has already been proved that this lignin devolatilization model correctly predicts the degradation rates and the detail of the released products. This work constitutes an initial yet significant step towards deriving a complete kinetic scheme of biomass devolatilization.     

Stochastic and recursive estimation of the hygro-thermo-chemical-mechanical parameters of concrete through Monte Carlo analysis and extended Kalman filter

Structural and Multidisciplinary Optimization - Hygro-thermo-chemical-mechanical models, used to determine the variations over time of temperature, relative humidity and shrinkage induced...     

A wide range kinetic modeling study of the pyrolysis and combustion of naphthenes

The aim of this paper is to analyze and discuss the kinetics of the pyrolysis and combustion of naphthenes. The primary propagation reactions of cyclohexane and methylcyclohexane are presented to extend the validity of a semi-detailed kinetic model for the pyrolysis and oxidation of hydrocarbons. Naphthenes are relevant species as reference components in liquid fuels and surrogate blends. A lumped approach is used to reduce the complexity of the overall scheme in terms of species and reactions. Particular attention is devoted to the role of the isomerization or internal abstraction of H atoms in competition with β−decomposition ones. Primary oxidation and decomposition reactions of the cyclohexyl radical are discussed to explain and justify this lumping procedure. The modeling predictions are compared with different sets of measurements. The validation of the low temperature oxidation mechanism of cyclohexane is based on the ignition delay times obtained both in the rapid compression machine at Lille and in closed vessels. Jet-stirred reactors at different pressures and stoichiometric ratios also confirm the reliability of the overall mechanism of oxidation. The comparisons between the model’s predictions and the measurements relating to the pyrolysis and oxidation of methylcyclohexane in the Princeton turbulent flow reactor further support this extension of the kinetic scheme to naphthenes. Finally, the agreement with the oxidation experiments using mixtures of toluene + methylcyclohexane is a primary and simple example of the model’s ability to deal with the combustion of real fuels or surrogate blends.     

Time analysis of structural concrete elements using the equivalent displacement method

This paper presents a modelling technique referred to as the equivalent displacement method (EDM) which describes the behaviour in time of structural concrete elements, such as reinforced concrete beams and composite beams with full shear interaction, accounting for time effects, such as creep, of the concrete component. The time-dependent behaviour of the concrete is modelled using the algebraic representations, such as the age-adjusted effective modulus method (AEMM), while the steel joist and reinforcement are assumed to behave in a linear-elastic fashion. The main advantage of the EDM method is that it requires only one analysis to obtain the deformation state of the structural system at one step in time based on the AEMM methods, instead of the two required by available modelling techniques (i. e. one performed at timet ₀ and one performed one step in timet). The EDM method is then applied to the analysis of structural concrete elements using the stiffness analysis and the results obtained based on this modelling technique are validated against other modelling methods. The advantages of using the EDM method in design applications are also illustrated.

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Résumé Cet article présente une méthode appelée méthode de déplacement équivalent (EDM), qui décrit le comportement temporel des éléments de béton, par example les poutres en béton armé et les poutres mixtes à interaction complète, tenant compte des effets temporaux, tel que le fluage du béton. Le comportement temporel du béton est modelé par représentation algébrique, tel que la méthode age ajusté du module effectif (AEMM), tandis que la poutre d'acier et les renforts sont supposés linéaire et élastique. L'avantage majeur de la méthode EDM est qu'elle n'exige qu'une seule analyse pour obtenir l'état de déformation du système à un point temporel (méthode EDM), au lieu des deux points exigés par les méthodes courantes, en temps t₀ et l'autre à t. La méthode EDM est ensuite appliquée à l'analyse des éléments structurels en béton, utilisant l'analyse de raideur, et les résultats obtenus par cette méthode sont vérifiés par d'autres méthodes. Les avantages de l'utilisation de la méthode EDM dans les applications du dessein sont aussi illustrés.

     

Control by nutrients of growth and cell cycle progression in budding yeast, analyzed by double-tag flow cytometry

To gain insight on the interrelationships of the cellular environment, the properties of growth, and cell cycle progression, we analyzed the dynamic reactions of individual Saccharomyces cerevisiae cells to changes and manipulations of their surroundings. We used a new flow cytometric approach which allows, in asynchronous growing S. cerevisiae populations, tagging of both the cell age and the cell protein content of cells belonging to the different cell cycle set points. Since the cell protein content is a good estimation of the cell size, it is possible to follow the kinetics of the cell size increase during cell cycle progression. The analysis of the findings obtained indicates that both during a nutritional shift-up (from ethanol to glucose) and following the addition of cyclic AMP (cAMP), two important delays are induced. The preexisting cells that at the moment of the nutritional shift-up were cycling before the Start phase delay their entrance into S phase, while cells that were cycling after Start are delayed in their exit from the cycle. The combined effects of the two delays allow the cellular population that preexisted the shift-up to quickly adjust to the new growth condition. The effects of a nutritional shift-down were also determined.     

Displacement‐based formulations for composite beams with longitudinal slip and vertical uplift

This paper describes three novel displacement‐based formulations for the analysis of composite beams with a flexible connection which is capable of deforming along the longitudinal axis of the member as well as vertically, i.e. transverse to the interface connection. For completeness, the analytical model which forms the basis of the proposed modelling technique is presented in both its weak and strong forms. The three novel finite element formulations are derived and tested using different structural systems; their nodal freedoms include the vertical and axial displacements as well as the rotations at each element end of both layers. Curvature locking problems are observed to occur for one of these elements and the origin of this behaviour is demonstrated analytically. Two applications are then proposed adopting a bi‐linear constitutive relationship for the vertical interface connection to reflect the more realistic case in which, already in the linear‐elastic range of the materials forming the cross‐section and of the longitudinal interface connection, two vertical connection stiffnesses are required, i.e. one to model the event of separation between the layers and one when one bears against the other one. Copyright © 2005 John Wiley & Sons, Ltd.     

Monitoring of melting refreezing cycles of snow with microwave radiometers: the Microwave Alpine Snow Melting Experiment (MASMEx 2002-2003)

A study of the melting cycle of snow was carried out by using ground-based microwave radiometers, which operated continuously 24 h/day from late March to mid-May in 2002 and from mid-February to early May in 2003. The experiment took place on the eastern Italian Alps and included micrometeorological and conventional snow measurements as well. The measurements confirmed the high sensitivity of microwave emission at 19 and 37 GHz to the melting-refreezing cycles of snow. Moreover, micrometeorological data made it possible to simulate snow density, temperature, and liquid water content through a hydrological snowpack model and provided additional insight into these processes. Simulations obtained with a two-layer electromagnetic model based on the strong fluctuation theory and driven by the output of the hydrological snowpack model were consistent with experimental data and allowed interpretation of both variation in microwave emission during the melting and refreezing phases and in discerning the contributions of the upper and lower layers of snow as well as of the underlying ground surface.