The discovery of hidden facial images in the paintings of Vincent Van Gogh and Paul Gauguin by using computer graphics enhancement techniques

For nine short weeks in 1888, Vincent Van Gogh and Paul Gauguin lived and worked together in the city of Arles. Using computer graphics enhancement analyses, some of the paintings they did during this period revealed hidden facial images. One full hidden figure in a painting by Van Gogh and five camouflaged facial images in the works of Paul Gauguin were uncovered using computer graphics techniques. With the exception of one painting by Gauguin, these concealed images have not been previously reported.     

A Bayesian alternative to parametric hypothesis testing

Summary A unified approach to parametric hypothesis testing from a decision-theoretical viewpoint is proposed. A measure of the discrepancy between two models is incorporated as part of the utility function. Specifically, the Kullback logarithmic divergence is considered as such a measure. Under certain conditions, when using this measure of discrepancy there is correspondence with the classical solutions.     

Mild Stereoselective Intermolecular Acetoxylation and Azidation of α‐C−H Bonds in Tröger's Bases

Introduction of oxygen and nitrogen into organic molecules is one of the fundamental strategies for their functionalization. Traditional approaches rely on the formation of an activated intermediate, which is then modified in a subsequent step. Here we report a simple direct oxidative α‐acetoxylation and azidation of α‐C−H bonds in Tröger's base analogues promoted by N‐bromosuccinimide (NBS) and palladium(II)acetate [Pd(OAc)₂] under mild conditions. This approach is pivotal on NBS oxidizing the carbon atoms next to the nitrogen atoms in the presence of Pd(OAc)₂ followed by a reaction with oxygen‐ or nitrogen‐centred nucleophiles such as KOAc or NaN₃ to yield either the mono‐ and bisacetoxylated or azidated Tröger's base derivatives in a stereo‐ and chemoselective manner. The obtained products can be efficiently modified to access synthetically meaningful structures.

     

Effect of binder system on the thermophysical properties of 3D-printed zirconia ceramics

Fabrication of 3D-printed ceramic parts with high complexity and high spatial resolution often demands low wall thickness as well as high stiffness at the green state, whereas printing simpler geometries may tolerate thicker, more compliant walls with the advantage of a rapid binder-burn-out and sintering process. In this work, the influence of the binder system on the thermophysical properties of 3D-printed stabilized zirconia ceramics was investigated. Samples were fabricated with the lithography-based ceramic manufacturing (LCM) technology using two different photosensitive ceramic suspensions (LithaCon 3Y230 and LithaCon 3Y210), with the same ZrO₂ powder. A significant difference in stiffness in the green state (~3 MPa vs. ~32 MPa for LithaCon 3Y230 and LithaCon 3Y210, respectively) was measured, associated with a rather loose or a linked network formed in the binder due to photopolymerization. Both materials reached high relative densities, that is, >99%, exhibiting a homogeneous fine-grained microstructure. No significant differences on the coefficient of thermal expansion (11.18 ppm/K vs. 11.17 ppm/K) or Young's modulus (207 GPa vs. 205 GPa) were measured, thus demonstrating the potential of tailoring binder systems to achieve the required accuracy in 3D-printed parts, without detrimental effects on material's microstructure and thermophysical properties at the sintered state.     

Ultra-Robust Flexible Electronics by Laser-Driven Polymer-Nanomaterials Integration

Polyethylene terephthalate (PET) is the most widely used polymer in the world. For the first time, the laser-driven integration of aluminum nanoparticles (Al NPs) into PET to realize a laser-induced graphene/Al NPs/polymer composite, which demonstrates excellent toughness and high electrical conductivity with the formation of aluminum carbide into the polymer is shown. The conductive structures show an impressive mechanical resistance against >10000 bending cycles, projectile impact, hammering, abrasion, and structural and chemical stability when in contact with different solvents (ethanol, water, and aqueous electrolytes). Devices including thermal heaters, carbon electrodes for energy storage, electrochemical and bending sensors show this technology's practical application for ultra-robust polymer electronics. This laser-based technology can be extended to integrating other nanomaterials and create hybrid graphene-based structures with excellent properties in a wide range of flexible electronics’ applications.     

Performance analysis of the domestic water meter park in water supply network of Ibarra,Ecuador

Apparent losses are one of the most important components of non-revenue water and mainly caused by water meter under-registration. This paper studies the performance of a water meter park from a developing country water utility in Ibarra city, Ecuador. The study includes three major aspects: water meter error curve reconstruction with seven different flow rates; water meter evaluation as a function of class, manufacturer and totalized registered volume, use of two water consumption patterns for weighted error determination and their influence on water balance and performance indicators analysis. Results indicate that 44% of analyzed meters works at optimal conditions. Weighted error obtained by using two different consumption patterns indicates a 0.95% difference, which has an important impact on water balance and performance indicator results. This detailed analysis of water meters can help to develop a more efficient water meter replacement strategy and to estimate apparent water loss volume more accurately.     

Mathematical Morphology on the Spherical CIELab Quantale with an Application in Color Image Boundary Detection

Mathematical morphology is a theory with applications in image processing and analysis. This paper presents a quantale-based approach to color morphology based on the CIELab color space in spherical coordinates. The novel morphological operations take into account the perceptual difference between color elements by using a distance-based ordering scheme. Furthermore, the novel approach allows for the use of non-flat structuring elements. An illustrative example reveals that non-flat dilations and erosions may preserve more features of a color image than their corresponding flat operations. Furthermore, the novel non-flat morphological operators yielded promising results on experiments concerning the detection of the boundaries of objects on color images.     

Ground Movements around Corners of Excavations: Empirical Calculation Method

This paper presents an empirical methodology that allows calculation of ground displacements behind corners of retained cut excavations. The increased stiffness of a retaining wall at the corner of an excavation normally leads to a corresponding reduction in ground movements behind the retaining wall. These “corner effects” derived from retained cut excavations can only be assessed at present by using three-dimensional numerical analysis or empirical methods. Significant cost and time can be taken carrying out three dimensional analysis, which, additionally, is not normally carried out at an early stage of the design of a project. Furthermore, numerical analysis must be undertaken by a competent person with appropriate training. An inappropriate analysis can yield to misleading and counterproductive results. This constitutes an expensive requirement on practitioners that often resort to more conservative designs which ignore corner effects. The methodology of adjusting calculated ground movements around corners of excavations described in this paper is simple to use and easy to program into software or spreadsheets. It can be used in conjunction with two-dimensional numerical analysis and also for calculating displacements in early stages of projects when numerical analysis has not yet been undertaken. This allows for more informed early discussion with third parties where approvals are sought on a given project.     

X-ray diffraction from intact tau aggregates in human brain tissue

We describe an instrument to record x-ray diffraction patterns from diseased regions of human brain tissue by combining an in-line visible light fluorescence microscope with an x-ray diffraction microprobe. We use thiazine red fluorescence to specifically label and detect the filamentous tau protein pathology associated with Pick's disease, as several labs have done previously. We demonstrate that thiazine red-enhanced regions within the tissue show periodic structure in x-ray diffraction that is not observed in healthy tissue. One observed periodicity (4.2 ?) is characteristic of cross-beta sheet structure, consistent with previous results from powder diffraction studies performed on purified, dried tau protein.