Lead contamination in tap water of households with children in Lower Saxony, Germany

Lead has numerous acute and chronic adverse effects on human beings. This is especially true for infants and children. The main path of lead ingestion in children can be different according to housing and living situation. The intake of lead through drinking water is commonly due to metal corrosion. The users plumbing can be an important factor. In recent years, many lead pipes in Germany have been replaced by pipes made of an alternative material. The aim of this study is to assess the present state of drinking water contamination and the resulting exposure of infants to lead. For this purpose mothers of new-born babies were offered a free examination of their drinking water. After a written declaration of consent had been obtained and after the infant in question had reached an age of 3 months, a stagnation sample of cold tap-water after overnight stagnation together with a random daytime sample was obtained from the family. The collected samples were analysed by atomic absorption spectrometry for their lead concentration. In total, 1485 samples from households were collected. Of the 1434 stagnation samples, 3.1% had lead concentrations greater than 0.01 mg/l (recommended limit of the WHO) and 0.6% had concentrations above the limit of the German drinking water regulation (0.04 mg/l). The values for the 1474 random daytime samples were 2.1% above 0.01 mg/l and 0.2% greater than 0.04 mg/l, respectively. By region, the areas Bovenden, Friedland, Duderstadt, Northeim and Rosdorf were particularly affected. The highest measured concentrations of lead in the stagnation samples were 0.11 mg/l and 0.15 mg/l in the random daytime samples, respectively.     

A study of the effect of stiffness distribution on nonlinear seismic response of multi-degree-of-freedom structures

The ductility requirement of elastoplastic multi-d.o.f. shear structures is studied by analysing the response obtained through step-by-step integration of the equations of motion for some recorded accelerograms. In view of the high dependence of the structural strength reserve beyond the elastic range on the distribution of plastic deformations in the structure, this paper aims to establish the influence of the stiffness distribution and of the earthquake features on the local ductility demand. Attention is also paid to the analysis of the influence of variation in excitation intensity and duration on the seismic behaviour of the structural models considered. Numerical results show that overall structural ductility alone is not sufficiently representative to evaluate the ultimate state of multi-d.o.f. structures. Local ductility must also be specified in order to create a reliable aseismic design. In this context, the important role played by the distribution of stiffness over the structure is emphasized.     

Interaction of bacteriophage R17 and reovirus type III with the clay mineral allophane

A study has been made of the adsorption of bacteriophage R17 and reovirus type 3 by the amorphous aluminosilicate clay mineral allophane. In agreement with previous studies of virus adsorption to other minerals such as montmorillonite and aluminium hydroxide, the principal factors influencing adsorption were found to be mixing time, pH and the concentrations and isoelectric points of both the virus and the absorbent. However, allophane was found to be a much better adsorbent for reovirus and R17 over the pH range 5–7, the natural pH range of many fresh waters.By using highly purified radioactive reovirus it was possible to follow both the distribution of radioactive virus in a clay suspension and the specific infectivity of the virus. This study revealed that when adsorbed virus was eluted by neutral phosphate solutions it retained its physical integrity but was of a lower specific infectivity.     

Geochemistry of some rare earth elements in groundwater,Vierlingsbeek, The Netherlands

Groundwater samples were taken from seven bore holes at depths ranging from 2 to 41m nearby drinking water pumping station Vierlingsbeek, The Netherlands and analysed for Y, La, Ce, Pr, Nd, Sm and Eu. Shale-normalized patterns were generally flat and showed that the observed rare earth elements (REE) were probably of natural origin. In the shallow groundwaters the REEs were light REE (LREE) enriched, probably caused by binding of LREEs to colloids. To improve understanding of the behaviour of the REE, two approaches were used: calculations of the speciation and a statistical approach.For the speciation calculations, complexation and precipitation reactions including inorganic and dissolved organic carbon (DOC) compounds, were taken into account. The REE speciation showed REE(3+), REE(SO(4))(+), REE(CO(3))(+) and REE(DOC) being the major species. Dissolution of pure REE precipitates and REE-enriched solid phases did not account for the observed REEs in groundwater. Regulation of REE concentrations by adsorption-desorption processes to Fe(III)(OH)(3) and Al(OH)(3) minerals, which were calculated to be present in nearly all groundwaters, is a probable explanation.The statistical approach (multiple linear regression) showed that pH is by far the most significant groundwater characteristic which contributes to the variation in REE concentrations. Also DOC, SO(4), Fe and Al contributed significantly, although to a much lesser extent, to the variation in REE concentrations. This is in line with the calculated REE-species in solution and REE-adsorption to iron and aluminium (hydr)oxides. Regression equations including only pH, were derived to predict REE concentrations in groundwater. External validation showed that these regression equations were reasonably successful to predict REE concentrations of groundwater of another drinking water pumping station in quite different region of The Netherlands.     

Stability analysis of simply-supported rectangular plates under non-uniform uniaxial compression using rigorous and approximate plane stress solutions

The non-classical problem of buckling of a simply-supported rectangular plate due to various types of non-uniform compressive edge loads is analysed here. For each case, the elasticity solution for the internal in-plane stress field is obtained rigorously using a superposition of Airy's stress functions and also approximately using extended Kantorovich method. Subsequently, the convergent buckling loads are obtained using Galerkin's method. Results are presented to highlight the dependence of the total buckling load and the corresponding buckled shape on the edge load distribution, as well as to illustrate the applicability of the approximate plane stress solutions.     

Method of Determining Strength and Deformation Characteristics of Soils from Results of Deep Impression of Rod Plates

The possibility of determining strength and deformation characteristics of soils under field conditions using rod plates is discussed. The mutual relationship between these characteristics is established from results of deep impression of these rods.     

Chloroaromatic formation in incineration processes

The high-temperature reactions of chlorinated hydrocarbons are reviewed with a primary focus on the gas-phase molecular growth chemistry and elementary reaction mechanisms leading to the formation of chlorinated benzenes and chlorinated polycyclic aromatic hydrocarbons. Recent heterogeneous mechanistic studies of the chlorination and condensation of aliphatic hydrocarbons at lower temperatures are also summarized. Copper(II) valent species play an important role as catalyst and reagent. The main thermal pathways for chlorinated dibenzodioxins and furans have been deduced by these laboratory experiments, which try to model the complex reality of the post-incineration zone of municipal and hazardous waste incinerators.     

Procedure for predicting settlements of thawing bases for engineering calculations

It was shown that in order to compute the settlement of thawing cohesive soil under a load in time it is necessary to experimentally determine the consolidation coefficient. A procedure is suggested for determining this coefficient, as well as use of the classical solution of a differential equation for seepage consolidation to describe the settlement of soil, thawing of which can occur according to any law.State All-Union Scientific Research Institute of Roads. Translated from Osnovaniya, Fundamenty i Mekhanika Gruntov, No. 4, pp. 5–7, July–August, 1993.     

A steady-state model for the rotating biological disc reactor

A steady-state model for substrate removal in a rotating biological disc reactor is presented. The model considers the consumption of substrate by micro-organisms in the biofilm attached to the rotating disc, and mass transfer from the attached liquid film to the biofilm. A mass balance on substrate over the liquid in the trough provides an expression for effluent substrate in terms of the microbial kinetic constants, the geometry of the system and the operating conditions. In order to simplify the solution of the equations in the model, first order kinetics are assumed for the rate of microbial growth and substrate utilization. This simplified model can be solved, for example, by using a programmable calculator. The model predicts that the fractional removal of substrate per stage is strongly dependent on the hydraulic loading rate per unit disc area but independent of feed substrate concentration. It predicts constant removal independent of disc size provided the hydraulic loading per unit area is kept constant. The rotational speed has only a slight predicted effect on the rate of substrate removal. The predictions of the model are compared with published data from the literature for both domestic wastewater and some industrial wastes. Trends observed in the field are predicted qualitatively by the model.