High-performance oxygen reduction and evolution carbon catalysis: From mechanistic studies to device integration

The development of high-performance and low-cost oxygen reduction and evolution catalysts that can be easily integrated into existing devices is crucial for the wide deployment of energy storage systems that utilize O2-H2O chemistries,such as regenerative fuel cells and metal-air batteries.Herein,we report an NH3-activated N-doped hierarchical carbon (NHC) catalyst synthesized via a scalable route,and demonstrate its device integration.The NHC catalyst exhibited good performance for both the oxygen reduction reaction (ORR) and the oxygen evolution reaction (OER),as demonstrated by means of electrochemical studies and evaluation when integrated into the oxygen electrode of a regenerative fuel cell.The activities observed for both the ORR and the OER were comparable to those achieved by state-of-the-art Pt and Ir catalysts in alkaline environments.We have further identified the critical role of carbon defects as active sites for electrochemical activity through density functional theory calculations and high-resolution TEM visualization.This work highlights the potential of NHC to replace commercial precious metals in regenerative fuel cells and possibly metal-air batteries for cost-effective storage of intermittent renewable energy.     

Intersubband optical absorption in (In,Ga)N/GaN double quantum wells considering applied electric field effects

Journal of Computational Electronics - In the present paper, we theoretically examine the total absorption coefficient related to inter-conduction subband 1S–2P transitions in symmetric...     

An efficient artificial bee colony algorithm with application to nonlinear predictive control

In this paper a constrained nonlinear predictive control algorithm, that uses the artificial bee colony (ABC) algorithm to solve the optimization problem, is proposed. The main objective is to derive a simple and efficient control algorithm that can solve the nonlinear constrained optimization problem with minimal computational time. Indeed, a modified version, enhancing the exploring and the exploitation capabilities, of the ABC algorithm is proposed and used to design a nonlinear constrained predictive controller. This version allows addressing the premature and the slow convergence drawbacks of the standard ABC algorithm, using a modified search equation, a well-known organized distribution mechanism for the initial population and a new equation for the limit parameter. A convergence statistical analysis of the proposed algorithm, using some well-known benchmark functions is presented and compared with several other variants of the ABC algorithm. To demonstrate the efficiency of the proposed algorithm in solving engineering problems, the constrained nonlinear predictive control of the model of a Multi-Input Multi-Output industrial boiler is considered. The control performances of the proposed ABC algorithm-based controller are also compared to those obtained using some variants of the ABC algorithms.     

Analytic evaluation of the cycle time on networked conflicting timed event graphs in the (Max,+) algebra

This work deals with performance evaluation of Conflicting Timed Event Graph (CTEG), a class of Petri net exhibiting phenomena such as synchronization, parallelism and resources sharing. It is well known that the dynamic of Timed Event Graphs (TEG) admits a linear state space representation in the (Max,+) algebra which makes the analysis and control of this class easier. There is also a possibility of associating conflicts with the TEGs by adding conflict places that are mostly considered as safe; this extended class is called CTEG. We first present an analytic evaluation of the cycle time of CTEG as a function of the cycle time of each TEG and of the timers of the conflict places. Finally, in a more general context, we look for a relaxation of the safety hypothesis on the conflict places in order to model and evaluate the cycle time on CTEGs with multiple shared resources.     

State‐Feedback Control for a Class of Timed Petri Nets Subject to Marking Constraints

The paper contributes with an original method of designing a control for discrete event systems modeled by a class of timed Petri nets. Precisely, this work deals with the closed loop control of Timed Event Graphs (TEGs) under specifications expressed with linear marking constraints. The objective of the controller is to limit the number of tokens in some places of these TEGs. The behavior of TEGs is represented by a system of difference equations that are linear in Min‐Plus algebra and the constraints are described by a set of inequalities, which are also linear in Min‐Plus algebra. A formal approach to design control laws that guarantee compliance with these marking constraints is proposed. For this, two sufficient conditions for the existence of control laws are proposed. The computed controls are causal feedbacks, which can be represented by a set of marked and timed places. The proposed method is illustrated in two applications: a manufacturing production line and an assembly system.     

Porous dye affinity beads for nickel adsorption from aqueous solutions: A kinetic study

We investigated a new adsorbent system, Reactive Red 120 attached poly(2‐hydroxyethyl methacrylate ethylene dimethacrylate) [poly(HEMA–EDMA)] beads, for the removal of Ni²⁺ ions from aqueous solutions. Poly(HEMA–EDMA) beads were prepared by the modified suspension copolymerization of 2‐hydroxyethyl methacrylate and ethylene dimethacrylate. Reactive Red 120 molecules were covalently attached to the beads. The beads (150–250 μm), having a swelling ratio of 55% and carrying 25.5 μmol of Reactive Red 120/g of polymer, were used in the removal of Ni²⁺ ions. The adsorption rate and capacity of the Reactive Red 120 attached poly(HEMA–EDMA) beads for Ni²⁺ ions was investigated in aqueous media containing different amounts of Ni²⁺ ions (5–35 mg/L) and having different pH values (2.0–7.0). Very high adsorption rates were observed at the beginning, and adsorption equilibria were then gradually achieved in about 60 min. The maximum adsorption of Ni²⁺ ions onto the Reactive Red 120 attached poly(HEMA–EDMA) beads was 2.83 mg/g at pH 6.0. The nonspecific adsorption of Ni²⁺ ions onto poly(HEMA–EDMA) beads was negligible (0.1 mg/g). The desorption of Ni²⁺ ions was studied with 0.1M HNO₃. High desorption ratios (>90%) were achieved. The intraparticle diffusion rate constants at various temperatures were calculated as k_20°C = 0.565 mg/g min^0.5, k_30°C = 0.560 mg/g min^0.5, and k_40°C = 0.385 mg/g min^0.5. Adsorption–desorption cycles showed the feasibility of repeated use of this novel adsorbent system. The equilibrium data fitted very well both Langmuir and Freundlich adsorption models. The pseudo‐first‐order kinetic model was used to describe the kinetic data. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100:5056–5065, 2006     

Real‐time temperature and photon transmission measurements for monitoring phase separation during the formation of poly(N‐isopropylacrylamide) gels

Phase separation during the formation of poly(N‐isopropylacrylamide) (PNIPA) hydrogels was investigated using real‐time photon transmission and temperature measurements. The hydrogels were prepared by free‐radical crosslinking polymerization of N‐isopropylacrylamide (NIPA) in the presence of N,N′‐methylenebisacrylamide (BAAm) as a crosslinker in an aqueous solution. The onset reaction temperature T₀ was varied between 20 and 28°C. Following an induction period, all the gelation experiments resulted in exothermic reaction profiles. A temperature increase of 6.5 ± 0.6°C was observed in the experiments. It was shown that the temperature increase during the formation and growth process of PNIPA gels is accompanied by a simultaneous decrease in the transmitted light intensities I_tr. The decrease in I_tr at temperatures below the lower critical solution temperature of PNIPA was explained by the concentration fluctuations due to the inhomogeneity in the gel network. At higher temperatures, it was shown that the gel system undergoes a phase transition via a spinodal decomposition process. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 86: 3589–3595, 2002     

Bacterial Foraging Optimization Algorithm for assembly line balancing

Assembly line balancing is the problem of assigning tasks to workstations by optimizing a performance measure while satisfying precedence relations between tasks and cycle time restrictions. Many exact, heuristic and metaheuristic approaches have been proposed for solving simple straight and U-shaped assembly line balancing problems. In this study, a relatively new optimization algorithm, Bacterial Foraging Optimization Algorithm (BFOA), based heuristic approach is proposed for solving simple straight and U-shaped assembly line balancing problems. The performance of the proposed algorithm is evaluated using a well-known data set taken from the literature in which the number of tasks varies between 7 and 111, and results are also compared with both an ant-colony-optimization-based heuristic approach and a genetic-algorithm-based heuristic approach. The proposed algorithm provided optimal solutions for 123 out of 128 (96.1 %) test problems in seconds and is proven to be promising.     

Synthesis and characterization of poly(ethylene glycol dimethacrylate–1‐vinyl‐1,2,4‐triazole) copolymer beads for heavy‐metal removal

We prepared poly(ethylene glycol dimethacrylate–1‐vinyl‐1,2,4‐triazole) [poly(EGDMA–VTAZ)] beads (average diameter = 150–200 μm) by copolymerizing ethylene glycol dimethacrylate (EGDMA) with 1‐vinyl‐1,2,4‐triazole (VTAZ). The copolymer composition was characterized by elemental analysis and found to contain five EGDMA monomer units for each VTAZ monomer unit. The poly(EGDMA–VTAZ) beads had a specific surface area of 65.8 m²/g. Poly(EGDMA–VTAZ) beads were characterized by Fourier transform infrared spectroscopy, elemental analysis, surface area measurements, swelling studies, and scanning electron microscopy. Poly(EGDMA–VTAZ) beads with a swelling ratio of 84% were used for the heavy‐metal removal studies. The adsorption capacities of the beads for Cd(II), Hg(II), and Pb(II) were investigated in aqueous media containing different amounts of these ions (5–750 mg/L) and at different pH values (3.0–7.0). The maximum adsorption capacities of the poly(EGDMA–VTAZ) beads were 85.7 mg/g (0.76 mmol/g) for Cd(II), 134.9 mg/g (0.65 mmol/g) for Pb(II), and 186.5 mg/g (0.93 mmol/g) for Hg(II). The affinity order toward triazole groups on a molar basis was observed as follows: Hg(II) > Cd(II) > Pb(II). pH significantly affected the adsorption capacity of the VTAZ‐incorporated beads. The equilibrium data were well fitted to the Redlich–Peterson isotherm. Consideration of the kinetic data suggested that chemisorption processes could have been the rate‐limiting step in the adsorption process. Regeneration of the chelating‐beads was easily performed with 0.1M HNO₃. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 4276–4283, 2006