镀液流速对碳化硅微粒与铜共沉积的影响

本文利用易于控制流速的旋转圆盘电极研究了SiC微粒与Cu的共沉积。得出了在不同镀液流动速度下镀得的复合镀层中微粒含量与镀液中微粒浓度以及与电流密度之间的关系曲线,进而探讨了镀液流速对Cu-SiC共沉积的影响。镀液流速通过影响微粒与阴极之间的弱吸附影响微粒在阴极表面的停留,从而对Cu-SiC复合电沉积过程产生很大影响。     

Rapid pyrolysis of brown coal and oil shale

A brown coal, peat and oil shale were subjected to a rapid pyrolysis process and medium-heat-value gases together with tar were collected. The char residue was of high activity and suitable for gasification to create a two-stage gasification system. The coal-tar is used for manufacturing liquid fuels and chemicals.     

温度对工业汽轮机运行的影响

由于温度的变化，而引起机组热应力的变化，这是工业汽轮机运行中最主要的变化，它对机组的安全和运行影响非常大。     

含磷氯和氮的化合物对软质PU泡沫塑料的阻燃作用

较全面地研究了含磷和氯(或氮)的化合物对软质聚氨酯泡沫塑料的阻燃作用,表明:(1)磷与氯或氨复配的协同阻燃效应能明显提高其阻燃效率,当其阻燃剂用量为11%—12%时,PU软泡的阻燃性达到GB10800—89阻燃一级;(2)使含磷氮阻燃基团结合在PU分子中,能降低阻燃剂的逃失性,从而提高材料阻燃耐久性,为阻燃技术的研究指出一条新途径。     

沉淀铁催化剂上F-T合成反应的研究

制备了物相组成为 Quartz- Si O2 ,Hermatite- Fe2 O3 和 Fe2 O3 - Iron Oxide的沉淀铁催化剂 ,研究了该催化剂作用上固定床积分反应器中费托合成反应特性 .发现 2 .6MPa,80 0 h-1,H2 /CO=2 /3,2 60℃～ 2 90℃时 ,随着温度的升高 ,CO和 H2 的转化率增大 ,CO2 选择性减小 ;40 0 h-1,65 0 h-1,80 0 h-1低空速和 2 4 0 0 h-1,32 0 0 h-1,40 0 0 h-1,640 0 h-1高空速时 ,随着空速的升高 ,H2转化率、CO转化率选择性下降 ,CO2 的选择性升高 ;2 80℃ ,2 .6MPa,H2 /CO进料比 2 /3,1 /1 ,2 /1时 ,随着 H2 /CO进料比的增加 ,CO转化率 ,H2 /CO利用比和 CH4选择性都增加 ,H2 转化率和 CO2选择性减小 .     

Electrochemical performance of nanocrystalline Li3V2(PO4)3/carbon composite material synthesized by a novel sol–gel method

A novel sol–gel method based on V₂O₅·nH₂O hydro-gel was developed to synthesize nanocrystalline Li₃V₂(PO₄)₃/carbon composite material. In this route, V₂O₅·nH₂O hydro-gel, NH₄H₂PO₄, Li₂CO₃ and high-surface-area carbon were used as starting materials to prepare precursor, and the Li₃V₂(PO₄)₃/carbon was obtained by sintering precursor at 750 °C for 4 h in flowing argon. The sol–gel synthesis ensures homogeneity of the precursors and improved reactivity. The sample was characterized by XRD, SEM and TEM. X-ray diffraction results show Li₃V₂(PO₄)₃ sample is monoclinic structure with the space group of P2₁/n. The TEM image indicates that the Li₃V₂(PO₄)₃ particles modified by conductive carbon are about 70 nm in diameter. The Li₃V₂(PO₄)₃/carbon system showed that the discharge capacities in the first and 50th cycle are about 155.3 and 143.6 mAh/g, respectively, in the range of 3.0–4.8 V. The sol–gel method is fit for the preparation of Li₃V₂(PO₄)₃/carbon composite material which may offer some favorable properties for commercial application.     

EFFECT OF PORE DIFFUSION ON DEACTIVATING RATES OF SECOND ORDER REACTION

The research and development of catalysts, the design and operation of catalytic reactors are complicated by the phenomenon of catalyst deactivation which is affected by various factors. In this paper, the effect of internal mass transfer resistance in the second order catalytic reaction system of uniform independent deactivation on both reaction and deactivation rates of straight cylindrical pore model has been discussed. In addition, the quantitative relations between effectiveness factor and Thiele modulus in second order reaction and first order deactivation system have been correlated     

注塑模微机CAD系统

本文介绍了一个微机上运行的注塑模ＣＡＤ系统，此系统主要解决了四个难点，浇注系统设计，冷却系统分析，型腔，型芯的曲面造型设计，装配图和零件工作图的设计绘制，经厂家实际运用证明，该系统使用方便，结果正确，能提高设计效率，降低生产成本。     

Acidic and catalytic properties of niobic acid crystallized at low temperature

Niobic acid was crystallized at 120 °C for 48 h, which showed the largest acid amounts at higher acid strengths. The crystallized niobic acid calcined at 300 °C was found to show higher activity than uncrystallized niobic acid and niobic acid washed with water or treated with sulfuric acid or phosphoric acid for the dehydration of isopropanol and the esterification of ethanol with acetic acid.