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491.
Many studies on electronic voting evaluate their usability in the context of simple elections. Complex elections, which take place in many European countries, also merit attention. The complexity of the voting process, as well as that of the tallying and verification of the ballots, makes usability even more crucial in this context. Complex elections, both paper-based and electronic, challenge voters and electoral officials to an unusual extent. In this work, we present two studies of an electronic voting system that is tailored to the needs of complex elections. In the first study, we evaluate the effectiveness of the ballot design with respect to motivating voters to verify their ballot. Furthermore, we identify factors that motivate voters to verify, or not to verify, their ballot. The second study also addresses the effectiveness of the ballot design in terms of verification, but this time from the electoral officials’ perspective. Last, but not least, we evaluate the usability of the implemented EasyVote prototype from both the voter and electoral official perspectives. In both studies, we were able to improve effectiveness, without impacting efficiency and satisfaction. Despite these usability improvements, it became clear that voters who trusted the electronic system were unlikely to verify their ballots. Moreover, these voters failed to detect the “fraudulent” manipulations. It is clear that well-formulated interventions are required in order to encourage verification and to improve the detection of errors or fraudulent attempts.  相似文献   
492.
The hybrid cellular automaton (HCA) algorithm was inspired by the structural adaptation of bones to their ever changing mechanical environment. This methodology has been shown to be an effective topology synthesis tool. In previous work, it has been observed that the convergence of the HCA methodology is affected by parameters of the algorithm. As a result, questions have been raised regarding the conditions by which HCA converges to an optimal design. The objective of this investigation is to examine the conditions that guarantee convergence to a Karush-Kuhn-Tucker (KKT) point. In this paper, it is shown that the HCA algorithm is a fixed point iterative scheme and the previously reported KKT optimality conditions are corrected. To demonstrate the convergence properties of the HCA algorithm, a simple cantilevered beam example is utilized. Plots of the spectral radius for projections of the design space are used to show regions of guaranteed convergence.  相似文献   
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Hot topics     
Renaud P 《Chimia》2010,64(5):292
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496.
Renaud P 《Chimia》2012,66(6):361
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497.
Sintering of CeO2 is studied in situ by high temperature scanning environmental microscopy (HT-ESEM) at T = 1400 °C. The morphological modifications of a single grains population are recorded for 6 h. Kinetic parameters are extracted from image series. The local grain growth determined from the single population studied in situ is compared to the general grain growth obtained by classical ex situ technique. Using HT-ESEM for sintering study is validated. The grain boundary velocities range between 0 and 5 μm h−1, with a mean value of about 1 μm h−1. The migration of the intragranular surface pores is described. Their velocities range between 0.4 and 1.2 μm h−1 and depend on pore diameters: the smaller the pore, the faster the pore velocity. The time required to fill a pore that arises at the sample surface is determined as a function of pore diameter. The time for pore elimination dependence with the pore diameters is also established.  相似文献   
498.
When a drop sits on a highly liquid-repellent surface (super-hydrophobic or super-omniphobic) made of periodic micrometer-sized posts, its contact-line can recede with very weak mechanical retention providing that the liquid stays on top of the microsized posts. Occurring in both sliding and evaporation processes, the achievement of low-contact-angle hysteresis (low retention) is required for discrete microfluidic applications involving liquid motion or self-cleaning; however, careful examination shows that during receding, a minute amount of liquid is left on top of the posts lying at the receding edge of the drop. For the first time, the heterogeneities of these deposits along the drop-receding contact-line are underlined. Both nonvolatile liquid and particle-laden water are used to quantitatively characterize what rules the volume distribution of deposited liquid. The experiments suggest that the dynamics of the liquid de-pinning cascade is likely to select the volume left on a specific post, involving the pinch-off and detachment of a liquid bridge. In an applied prospective, this phenomenon dismisses such surfaces for self-cleaning purposes, but offers an original way to deposit controlled amounts of liquid and (bio)-particles at well-targeted locations.  相似文献   
499.
Au/CeO2 solids with different gold contents were prepared using the impregnation method. Electron microscopy (SEM and TEM) studies indicated the formation of both nanoparticles and large gold particles on the surface of the ceria support. SEM and XRD analyses revealed that the number and size of large particles increases with the gold content in the solid. The XPS technique showed that 90% of the total gold is in the metallic form Au0 while the remaining 10% were cationic gold species Au+. These latter were formed following calcination under dry air at 400 °C and are located in the proximity of the O2− and/or Cl present on the support. These Au+ species are present at the edge of gold particles and they were reduced into metallic gold when the solid was vacuum treated (5–7.10−4 mbar) at 400 °C for 1 h. When air was adsorbed at room temperature on the latter vacuum treated solids, two EPR signals were obtained. The first one was assigned to O2 species whereas attributing the second signal was difficult and required a more detailed investigation that will be presented in a forthcoming work.  相似文献   
500.
The electrolytic reduction mechanisms of K2SiF6 and K2TiF6 solutions in LiF-KF and LiF-NaF-KF eutectic mixtures have been studied at temperatures between 550 and 850°C. The reduction of K2SiF6 proceeds by two successive electron transfers, $$Si(IV) + 2e \to Si(II) + 2e \to Si$$ coupled with an antidisproportionation reaction $$Si(IV) + Si \underset{{k_b }}{\overset{{k_b }}{\longleftrightarrow}} 2Si(II)$$ Very pure thin silicon layers, up to 300 μm thick, were obtained on a silver substrate. The cathodic reduction of TiF 6 2? ions occurs in two well separated reversible steps, $$TiF_6^{2--} + e \to TiF_6^{3--} + 3e \to Ti + 6F^--$$ Adherent coatings of pure titanium were found to be linked to the copper substrate by an interdiffusion sublayer comprising Ti2Cu, TiCu, Ti2Cu3 and TiCu4 which were formed in a narrow potential domain preceding titanium deposition.  相似文献   
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