Numerical analysis of multilayered CFRP retrofitted RC beams with partial interaction

This paper presents a theoretical model to simulate the behaviour of RC beams strengthened with multilayered CFRP matrix allowing for inter-layer slip. An element of the composite beam is assumed to be subjected to a system of forces that satisfy equilibrium and compatibility of deformations. The inter-layer slip is allowed for by relating the differential strain at the interfaces between the CFRP layers and the concrete to the longitudinal shear flow at the corresponding interface through the shear stiffness of the adhesive layer. The basic differential equations are derived in terms of displacement variables and solved numerically using finite differences. The results of the numerical simulation included slip values along the interfaces, maximum slip values, stresses and strains and deflections. The results compare reasonably well with experimental findings.     

Investigation of the parameters that influence the accuracy of bond defect detection in CFRP bonded specimens using IR thermography

Infra-red (IR) testing has emerged as a promising non-destructive method (NDM) to detect and effectively observe bond defects in composite materials. This paper presents the findings of an investigation of carbon fiber-reinforced polymer (CFRP) fabrics and laminates externally bonded to concrete and steel members. Various kinds of artificial bond defects at the CFRP-substrate bond surface were investigated in specimens with single- as well as multi-layer CFRP fabrics. Particular emphasis was placed on the use of different heating modules in the IR nondestructive testing. This was implemented by generating different thermal waves within the CFRP-substrate bond surface. The results show that substrate material type and methods of surface preparation have a marked influence on the type of heating modules that produce the best detection capability. The results also show that the number of CFRP layers has a considerable effect on the effectiveness of bond identification and the accuracy of the IR images.     

Structural transition of a homopolymer in solvents mixture

The present work is aimed at studying the thermodynamic behaviour of a polymer in solvents mixture. Dynamic light scattering is used to measure the hydrodynamic radius of polyvinylpyrrolidone (M_w = 360,000 g/mol), in water/methanol solvents mixture, versus the mixed solvents composition at 25 °C. Then, we show that the polymer conformation adopts the Coil–Globule–Coil structure when the methanol molar fraction X_A is varied. This transition is attributed to solvent quality change which result from water and methanol complex formation. The polymer contraction rate calculated for each composition takes its maximum value at X_A = 0.17. Hildebrand theory assuming the solvents mixture as an equivalent solvent was used to analyze the change in mixed solvents quality. These changes can be attributed to dispersive forces in solvents mixture.     

Fabrication and characterization of nano-particles-enhanced epoxy

Epoxy has been widely used as adhesives in retrofitting structures with carbon fiber reinforced polymer (CFRP). In this study, different weight fractions of multi-walled carbon nanotubes (MWCNTs) and Silicon Carbide nanopowder (SiC) will be dispersed into epoxy to produce toughened adhesives that can effectively improve the CFRP/structure bonding performance. The preliminary experimental results indicate that adding 2 wt.% MWCNTs into Araldite-420 will increase its ultimate strength by 17% and its elastic modulus by 14%. On the other hand, Araldite-420’s elastic modulus will increase by nearly 50% when 1.0 wt.% of SiC powder is added. Ultrasonic mixing may increase the elastic modulus of Sikadur-30 but reduce its strength and ductility regardless of the amount of nanoparticles dispersed. No significant effect of nano-particle infusion on the glass transition temperature of the epoxies was found. The mechanism of nanoparticles infusion effects on the mechanical properties of the epoxies is also examined using SEM.     

Analysis of Test Specimens for Cohesive Near-Bond Failure of Fiber-Reinforced Polymer-Plated Concrete

The failure mechanisms of reinforced concrete (RC) members change due to the application of externally bonded fiber-reinforced polymer reinforcement. Although an extensive literature is available describing the failure mechanisms of poststrengthened flexural systems, brittle failure modes caused by bond failure, such as midspan debonding and end peeling, need to be further investigated in order to identify and quantify the fracture processes that result in bond failure. Simplified experimental tests have been designed to idealize the bond between the laminate and the RC member. However, it is unclear how the simplified test results can be related to the actual flexural debonding failures. This paper investigates and compares two bond failure tests: a simplified test (or simple shear test) and a recently proposed shear/normal test. After discussing the characteristics of both tests and how they relate to the midspan debonding and end peeling failures, the shear/normal test is studied in more detail using a nonlinear finite-element fracture mechanics program. The program accounts for cohesive localized and distributed concrete crack damage and is capable of describing the geometrical discontinuities that induce different brittle failure mechanisms. The numerical results compare well with available experimental data and help explain the crack formation and propagation pattern up to specimen failure. Parametric studies are presented to elucidate the influence of different material parameters on the failure mechanisms.     

Municipal solid waste compost application improves productivity, polyphenol content, and antioxidant capacity of Mesembryanthemum edule

Organic wastes were successfully used as soil amendment to improve agrosystems productivity. Yet, the effectiveness of this practice to enhance plant antioxidant capacities has received little attention. Here, we assess the effect of municipal solid waste (MSW) compost (at 40 t ha(-1)) on growth, polyphenol contents and antioxidant activities of Mesembryanthemum edule. MSW compost application significantly increased the soil contents of carbon, nitrogen, calcium, phosphorus and potassium. This was associated with higher nutrient (N, P, and K) uptake, which likely led to the significant improvement of the plant biomass and relative growth rate (RGR) (+93% on average) as compared to the control. In the same way, the fertilizing effect of the added organic matter significantly enhanced the antioxidant potential M. edule, assessed by radical scavenging activity, iron reducing power and β-carotene bleaching capacity. This was associated with significantly higher antioxidant contents, mainly total phenols and flavonoids. Heavy metal (Pb, Cd, Cu, and Zn) concentrations were slightly increased upon compost application, but remained lower than phytotoxic values. Overall, our results point out that short-term MSW compost application at 40 t ha(-1) is efficient in enhancing the productivity together with the antioxidant potentiality of M. edule without any adverse environmental impact.     

Prediction Models for Debonding Failure Loads of Carbon Fiber Reinforced Polymer Retrofitted Reinforced Concrete Beams

This study focuses on debonding failure in reinforced concrete beams with carbon fiber reinforced polymer composite bonded on the soffit using the wet lay-up method. An experimental study, which involved 26 tests, was carried out. The experiments showed two failure modes: Intermediate span debond and end debond. The first failure is the result of the high bond stress near the tip of a flexure-shear crack, whereas the second type of failure is due to the high shear stress developed in the weakest concrete layer at the tension reinforcement level. The experiments have shown that U-straps can be effective in preventing intermediate span and end debond. Based on experimental observations, two simple and practical theoretical models were developed and verified with the experimental data, together with a large database of other existing tests.     

Salt effect on phenolics and antioxidant activities of Tunisian and Canadian sweet marjoram (Origanum majorana L.) shoots

BACKGROUND: Two varieties of Origanum majorana (Canadian and Tunisian) were evaluated for their phenolic, flavonoid and tannin contents, individual phenolic compounds and antioxidant activities under NaCl constraint. RESULTS: The results showed a significant variability in phenolic composition and antioxidant behavior between the two varieties under salt stress. The phenolic composition of methanolic extracts was determined by reversed‐phase high‐performance liquid chromatography. Amentoflavone was the predominant flavonoid compound; in addition, trans‐2‐hydrocinnamic acid became the major phenolic acid with salt treatment of the Tunisian variety. In the control, Canadian variety extract was characterized by high levels of gallic acid and amentoflavone. However, under 75 mmol L^?1 NaCl, gallic acid content doubled, whereas amentoflavone content was maintained in the Canadian variety. Stimulation of phenolic acid biosynthesis was observed in these two varieties under salt treatment despite the fact that shoots of the Tunisian variety showed higher antioxidant activities compared to those from the Canadian variety. Tunisian O. majorana might have developed tolerance to salinity and avoided tissue damage by activating enzymes involved in the galactosylation of quercetin into quercetin‐3‐galactoside and quercetin‐3‐rhamnoside. CONCLUSION: Our results confirmed the tolerance of Tunisian O. majorana plants. Copyright © 2012 Society of Chemical Industry     

Chemical composition and antimicrobial activity of the essential oils from four Ruta species growing in Algeria

Antimicrobial properties of plants essential oils have been investigated in order to suggest them as potential tools to overcome the microbial drug resistance and the increasing incidence of food borne diseases problems. The aim of this research is to study the antibacterial and antifungal effects of four traditional plants essential oils, Ruta angustifolia, Ruta chalepensis, Ruta graveolens and Ruta tuberculata, against standard bacterial and fungal strains. The chemical compounds of the oils were examined by GC/MS. Results revealed a powerful antifungal activity against filamentous fungi. Aspergillus fumigatus and Cladosporium herbarum are the most sensitive strains to these oils with MIC values less than 3.5 μg ml⁻¹ for certain oils, reaching 7.8 μg ml⁻¹ for other. GC/MS essay exhibited ketones as the most abundant constituent of these oils except for R. tuberculata essential oil which has a completely different composition, monoterpenes alcohols being the most abundant. These compositions explain their potential antifungal activity.