Adsorption, desorption and isotopic exchange of cadmium on illite: evidence for complete reversibility

Adsorption, desorption and isotopic exchange of Cd on illite clay have been studied at low Cd concentrations and low ionic strength. The results indicate that under the conditions of the experiments Cd sorption on illite is completely reversible. Long equilibration times (7–8 weeks) were shown to be essential because of slow desorption kinetics.     

Mapping of background air pollution at a fine spatial scale across the European Union

Background

There is a need to understand much more about the geographic variation of air pollutants. This requires the ability to extrapolate from monitoring stations to unsampled locations. The aim was to assess methods to develop accurate and high resolution maps of background air pollution across the EU.

Methods

We compared the validity of ordinary kriging, universal kriging and regression mapping in developing EU-wide maps of air pollution on a 1 × 1 km resolution. Predictions were made for the year 2001 for nitrogen dioxide (NO₂), fine particles < 10 µm (PM₁₀), ozone (O₃), sulphur dioxide (SO₂) and carbon monoxide (CO) using routine monitoring data in Airbase. Predictor variables from EU-wide databases were land use, road traffic, population density, meteorology, altitude, topography and distance to sea. Models were developed for the global, rural and urban scale separately. The best method to model concentrations was selected on the basis of predefined performance measures (R², Root Mean Square Error (RMSE)).

Results

For NO₂, PM₁₀ and O₃ universal kriging performed better than regression mapping and ordinary kriging. Validation of the final universal kriging estimates with results from all validation sites gave R²-values and RMSE-values of 0.61 and 6.73 µg/m³ for NO₂; 0.45 and 5.19 µg/m³ for PM₁₀; and 0.70 and 7.69 µg/m³ for O₃. For SO₂ and CO none of the three methods was able to provide a satisfactory prediction.

Conclusion

Reasonable prediction models were developed for NO₂, PM₁₀ and O₃ on an EU-wide scale. Our study illustrates that it is possible to develop detailed maps of background air pollution using EU-wide databases.     

A practical evaluation of spectrum-based fault localization

Spectrum-based fault localization (SFL) shortens the test–diagnose–repair cycle by reducing the debugging effort. As a light-weight automated diagnosis technique it can easily be integrated with existing testing schemes. Since SFL is based on discovering statistical coincidences between system failures and the activity of the different parts of a system, its diagnostic accuracy is inherently limited. Using a common benchmark consisting of the Siemens set and the space program, we investigate this diagnostic accuracy as a function of several parameters (such as quality and quantity of the program spectra collected during the execution of the system), some of which directly relate to test design. Our results indicate that the superior performance of a particular similarity coefficient, used to analyze the program spectra, is largely independent of test design. Furthermore, near-optimal diagnostic accuracy (exonerating over 80% of the blocks of code on average) is already obtained for low-quality error observations and limited numbers of test cases. In addition to establishing these results in the controlled environment of our benchmark set, we show that SFL can effectively be applied in the context of embedded software development in an industrial environment.     

Diffusion mechanisms of vacancy and doped Si in Al3Ti from first-principles calculations

First-principles calculations were employed to study the migration of vacancy in clean and Si-doped Al₃Ti. The effect of Si doping on the formation of vacancy and the diffusion of doped-Si atom in the Al₃Ti were also investigated. It is found that, under Al-rich condition, the formation energies of Al vacancies in Al₃Ti with Si doping are decreased compared with those in clean Al₃Ti. The preferred migration paths of vacancies are not changed when Si occupies Al site, but the migration energy barriers for the majority of paths are decreased after Si doping. The doped-Si atom on Al site prefers to diffuse via the nearest Al vacancy.     

Energy cultures: A framework for understanding energy behaviours

Achieving a ‘step-change’ in energy efficiency behaviours will require enhanced knowledge of behavioural drivers, and translation of this knowledge into successful intervention programmes. The ‘Energy Cultures’ conceptual framework aims to assist in understanding the factors that influence energy consumption behaviour, and to help identify opportunities for behaviour change. Building on a history of attempts to offer multi-disciplinary integrating models of energy behaviour, we take a culture-based approach to behaviour, while drawing also from lifestyles and systems thinking. The framework provides a structure for addressing the problem of multiple interpretations of ‘behaviour’ by suggesting that it is influenced by the interactions between cognitive norms, energy practices and material culture.     

The effects of expressive writing following first myocardial infarction: A randomized controlled trial.

Objective: To assess the effects of expressive writing on health care utilization, clinical variables and subjective quality of life following first myocardial infarction (MI). Methods: One-hundred and seventy-nine first MI patients were randomized to Intervention (N = 88) or Control (N = 91) groups. The intervention group wrote about their thoughts and feelings in relation to having had an MI. Controls wrote in a neutral way about daily activities. The main outcome measures were health care utilization, physical status and subjective quality of life (QOL), assessed after one, two, and five months. Results: One-hundred and fifty-six (87%) completed the study. Five months post-intervention, the intervention group had significantly fewer recorded medical appointments compared to controls. The number of prescribed medicines decreased over time within the intervention group but increased within the control group. The intervention group attended significantly more rehabilitation sessions, reported fewer cardiac related symptoms and had lower diastolic blood pressure five months post-intervention. There was no significant group by time interaction on reported physical health. The group by time interaction on reported mental health approached significance, those in the intervention group reporting greater improvement. Conclusion: Expressive writing may be a beneficial strategy which could be incorporated into rehabilitation interventions to help individuals adjust after first MI. (PsycINFO Database Record (c) 2011 APA, all rights reserved)     

耳机放大器设计：品质VS效率

在最近几年中,D类放大器因其体积小,效率高,已经进入了消费类音频电子产品、汽车以及便携式音频产品市场.它的效率帮助减小了汽车放大器以及便携式媒体扩展插槽的尺寸,并以较小的波形因子提供了更大的功率,有助实现新式的消费类音频设备.