A new approach to the mechanism of chlorine evolution: Separate examination of the kinetic steps using ac impedance on a rotating thin ring electrode

In the absence of a bulk diffusion effect, it is shown for the first time that the impedance spectra for the chlorine evolution reaction on a rotating thin ring electrode comprise three consecutive semicircles in the capacitive half of the complex plane. The first (highest frequency) semicircle is due to the charge-transfer resistance for chloride discharge and the simultaneous chlorine adsorption coupled to the double-layer capacitance. The second semicircle (around 5 Hz) is due to the adsorption and desorption of a chlorine intermediate. The third (lowest frequency, around 0.5 Hz) semicircle is due to the relaxation of surface oxygen species. The impedance data allow the steps of the overall reaction to be examined individually. On a Pt surface the rate of chloride discharge and simultaneous chlorine adsorption (the admittance of the first semicircle) is first order with respect to chloride concentration and has a potential-dependence close to 58 mV/decade. The rate of the adsorption and desorption process (the admittance of the second semicircle) is second order with respect to chloride concentration, and has a potential dependence close to 30 mV/decade. The time constant for the adsorption/desorption processes is ca 20 ms, independent of electrode potential in the range studied. These features are consistent with a mechanism in which a faster discharge reaction (Cl⁻ Cl_ad + e) is followed by a slower surface combination reaction (2Cl_ad → Cl₂), but inconsistent with mechanisms in which ion + atom desorption is predominant, the initial chloride discharge is slow, or a unipositively charged chlorine species is involved.     

Teachers' brief nonverbal behaviors in defined instructional situations can predict students' evaluations.

Can a few seconds of high school teachers' nonverbal (NV) behavior predict students' ratings of these teachers (SRT)? Yes, but NV-SRT relations varied among various instructional situations. NV behaviors while administering the class and using the board were unrelated to SRT. Positive judgments of NV behavior while disciplining the class and interacting with students were positively related to SRT. NV behaviors in frontal teaching were negatively related to SRT. The most negative NV-SRT relations were found for teachers' differential NV behavior toward high- versus low-achieving students. Teacher differentiality and SRT have rarely been investigated in high school. The structure of SRT seems to differ between high school and college, and students' anger about teachers' differentiality strongly predicted their evaluations. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Automatic labeling and characterization of objects using artificial neural networks

Existing NASA supported scientific databases are usually developed and managed by a team of database administrators whose main concern is the efficiency of the databases in terms of normalization and data search constructs. The populating of the database is usually done in a manual fashion by row and column as the data become available, and the data dictionary is usually defined by the same team (at times with little input from the end science user). This process is tedious, error prone and self-limiting in terms of what can be described in a relational Data Base Management System (DBMS). The next generation Earth remote sensing platforms [i.e., Earth Observing System (EOS)] will be capable of generating data at a rate of over 300 Megabits per second from a suite of instruments designed for different applications. What is needed is an innovative approach that creates object-oriented data-bases that segment, characterize, and catalog, and are manageable in a domain-specific context, and whose contents are available interactively and in near-real-time to the user community. This paper describes work in progress that utilizes an artificial neural net approach to characterize satellite imagery of undefined objects into high-level data objects. The characterized data is then dynamically allocated to an object-oriented database where it can be reviewed and accessed by a user. The definition, development, and evolution of the overall data system model are steps in the creation of an application-driven knowledge-based scientific information system.     

Nonsimultaneous auditory masking in the budgerigar (Melopsittacus undulatus).

Compared the frequency resolving power of 3 male budgerigar birds and 3 humans on several nonsimultaneous masking procedures in which one pure tone was used to mask another. Similar patterns of frequency selectivity were found for all 3 masking procedures (forward, backward, and combined forward/backward) for both species. Budgerigars showed considerably greater frequency resolving power on all 3 procedures than humans. Budgerigars also showed differences in frequency resolving power across masking conditions, but human Ss did not. Results indicate that the budgerigar auditory system may be even more highly tuned than was previously thought and suggest fundamental differences between the mechanisms of frequency selectivity of birds and humans. (19 ref) (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

The economic impact of uncertainties associated with energy-saving technologies

We will analyze the economic sensitivity of new energy-saving technologies to weather, future energy price, and system lifetime uncertainties. Graphical rate of return analysis is employed. A representative residential solar water heating investment is analyzed to illustrate the impact of uncertainties. The wide range of reasonable rates of return found suggests some considerations for policy makers and some areas of future research.     

Optimal control of auxiliary heating of passive-solar-heated buildings

Previous papers have demonstrated that low-cost off-peak electricity can be used to provide auxiliary heating for a passive-solar-heated residence. This paper describes the development of optimal control strategies for the operation of this auxiliary heating system. The temperature in the residence throughout the day as determined by computer simulation is presented for several optimal and conventional control strategies. The optimal control strategies improved the temperature control in the building compared to the conventional strategies. All strategies were shown to depend heavily on weather prediction. Computer simulations showed that errors in weather prediction had a small effect on heating cost and a large effect on being able to maintain the desired indoor temperature.     

Some nitrosoamino acids in bacon adipose tissue and their contribution to the total N-nitroso compound concentration

Zusammenfassung Der Gehalt an Nitrosoaminosäuren und ihr Anteil an den Gesamt-N-Nitrosoverbindungen im Fettgewebe von rohem Schinkenspeck wurde untersucht. In 80% der Proben wurde ein Gehalt an Nitrosoaminosäuren von bis zu 0,2 mg/kg festgestellt. Scheinbare Gesamt-N-Nitrosoverbindungen waren in allen Proben in einer Konzentration von 0,4 bis 3,7 mg (N-NO)/kg vorhanden. Die eigentlichen Nitrosoaminosäuren machen nur etwa 1% der scheinbaren Gesamt-N-Nitrosoverbindungen aus. Die Mehrzahl der scheinbaren Gesamt-N-Nitrosoverbindungen im Fettgewebe findet sich im nichtlöslichen Bindegewebe, wobei der verbleibende Rest chloroformlöslich ist.Summary The levels of nitrosoamino acids and apparent total N-nitroso compounds in the adipose tissue of raw bacon have been examined. Nitrosoamino acids were detected in 80% of the samples in levels of up to 0.2 mg/kg. Apparent total N-nitroso compounds were present in all samples in concentrations of between 0.4 and 3.7 mg (N-NO)/kg. Nitrosoamino acids accounted for approximately only 1 % of the apparent total N-nitroso compounds. The majority of the apparent total N-nitroso compounds in the adipose tissue were associated with the insoluble connective tissue fraction, with the remainder present as chloroform soluble species.

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Einige Nitrosoaminosäuren im fettgewebe von Schinkenspeck und ihr anteil an der Konzentration der Gesamt-N-Nitrosoverbindungen

     

Vers une méthodologie de validation trans-culturelle de questionnaires psychologiques: Implications pour la recherche en langue fran?aise.

Proposes a cross-cultural validation methodology that allows for the validation of French versions of English psychological scales. The 7 basic steps in the method are described: (1) preparation of a preliminary French version; (2) evaluation and modification of the preliminary version; (3) evaluation of the experimental French version in a pretest; (4) evaluation of content and concomitant validity; (5) evaluation of reliability; (6) evaluation of construct validity; and (7) preparation of norms for the French version. Examples of each step are presented. (English abstract) (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Effect of backward priming on word recognition in single-word and sentence contexts.

Backward priming was investigated under conditions similar to those used in lexical ambiguity research. Ss received prime-target word pairs that were associated either unidirectionally (BABY-STORK) or bidirectionally (BABY-CRY). In Exp 1, targets were presented 500 ms following the onset of visual primes, and Ss made naming or lexical decision responses to the targets. Forward priming was obtained in all conditions, while backward priming occurred only with lexical decision. In Exp 2, primes were presented auditorily, either in isolation or in a sentence. Targets followed the offset of the primes either immediately or after 200 ms. Backward priming occurred with both response tasks, but only when the prime was an isolated word. Backward priming decreased over time with the naming task, but not with lexical decision. These results suggest that the locus of the backward priming effect is different for the 2 response tasks. Results support a context-independent view of lexical access. (PsycINFO Database Record (c) 2010 APA, all rights reserved)