The point-characteristic function, wavefronts, and caustic of a spherical wave refracted by an arbitrary smooth surface

The aim of this paper is to obtain expressions for the k-function, the wavefront train, and the caustic associated with the light rays refracted by an arbitrary smooth surface after being emitted by a point light source located at an arbitrary position in a three-dimensional homogeneous optical medium. The general results are applied to a parabolic refracting surface. For this case, we find that when the point light source is off the optical axis, the caustic locally has singularities of the hyperbolic umbilic type, while the refracted wavefront, at the caustic region, locally has singularities of the cusp ridge and swallowtail types.     

Highly Active Catalyst from [PdCl2(NH2(CH2)12CH3)2] on NH4ZSM-5

A palladium catalyst highly active for the cyclohexene hydrogenation has been obtained by heterogenisation of [PdCl₂(NH₂(CH₂)₁₂CH₃)₂] on zeolite NH₄ZSM-5. TOF is more than twenty times higher than for the homogeneous catalyst or the activated carbon heterogenised complex. Changes in the electronic state of palladium have been observed by XPS analysis. Palladium reduction is produced upon heterogenisation on the NH₄ZSM-5 zeolite.     

Could Radiotherapy Effectiveness Be Enhanced by Electromagnetic Field Treatment?

One of the main goals in radiobiology research is to enhance radiotherapy effectiveness without provoking any increase in toxicity. In this context, it has been proposed that electromagnetic fields (EMFs), known to be modulators of proliferation rate, enhancers of apoptosis and inductors of genotoxicity, might control tumor recruitment and, thus, provide therapeutic benefits. Scientific evidence shows that the effects of ionizing radiation on cellular compartments and functions are strengthened by EMF. Although little is known about the potential role of EMFs in radiotherapy (RT), the radiosensitizing effect of EMFs described in the literature could support their use to improve radiation effectiveness. Thus, we hypothesized that EMF exposure might enhance the ionizing radiation effect on tumor cells, improving the effects of RT. The aim of this paper is to review reports of the effects of EMFs in biological systems and their potential therapeutic benefits in radiotherapy.     

Natural Majorization of the Quantum Fourier Transformation in Phase-Estimation Algorithms

We prove that majorization relations hold step by step in the Quantum Fourier Transformation (QFT) for phase-estimation algorithms. Our result relies on the fact that states which are mixed by Hadamard operators at any stage of the computation only differ by a phase. This property is a consequence of the structure of the initial state and of the QFT, based on controlled-phase operators and a single action of a Hadamard gate per qubit. The detail of our proof shows that Hadamard gates sort the probability distribution associated to the quantum state, whereas controlled-phase operators carry all the entanglement but are immaterial to majorization. We also prove that majorization in phase-estimation algorithms follows in a most natural way from unitary evolution, unlike its counterpart in Grover's algorithm. PACS: 03.67.-a, 03.67.Lx     

Acrylic-phosphate glasses composites as self-curing controlled delivery systems of antibiotics

New antibiotic delivery systems based on self-hardening methyl methacrylate (MMA)/polymethyl methacrylate (PMMA) systems and phosphate glasses (PG) in the system P₂O₅–CaO–Na₂O have been developed. Self-curing formulations were prepared by mixing the solid component containing PMMA beads, different proportions of PG (30–70 wt %) and vancomycin (5 wt %) as antibiotic, with the liquid component made of MMA monomer. Dough and setting times increased with the content of PG but peak temperature decreased to values well below to guarantee the chemical stability of the antibiotic drug, gentamicin or vancomycin. Mechanical properties of the PMMA/PG composites were evaluated in compression test giving rise to values of compressive strength in the range of 100 MPa. The release of vancomycin was analyzed in vitro by immersion of samples in phosphate buffer of pH=7.4. Release profiles were influenced by the content of PG present in the cement. An initial burst of drug release was observed in all cases. The composites with 70 wt % PG released nearly the total amount of drug loaded in a period of 45 days, and those containing 60 wt % PG released the 70% of the vancomycin in the same period of time. However, either the control of the composite with 30 wt % PG released only the 30% of the drug in 10–15 days. The surface of the drug-loaded composites before and after release experiments was analyzed by ESEM. The deposition of some aggregates at certain points of the surface was detected for the specimens immersed in buffer phosphate after 45 days. This material was characterized by FTIR and Raman spectroscopy as an amorphous phosphate formed by calcium ortho and pyrophosphates, and indicates an interaction between the hydrated layer at the place of the glass and the surrounding medium.     

Acrylic bone cements incorporating polymeric active components derived from salicylic acid: curing parameters and properties

A methacrylic monomer derived from salicylic acid, 5-hydroxy-2-methacrylamido benzoic acid, 5-HMA, was incorporated with 2-hydroxyethyl methacrylate, (HEMA), in different proportions to the liquid phase of classical bone cement formulations. The monomer 5-HMA shows the ability to form molecular complexes with calcium atoms in order to improve osteointegration in the application of bone cement formulations used for the fixation of joint prostheses such as knee and hip. Kinetic parameters, peak temperature and setting time of the bone cement formulations prepared were determined, obtaining lower peak temperature values when 5-HMA was incorporated, with respect to classical acrylic bone cements based on PMMA. Mechanical and thermal properties as well as surface energy values, have been determined for all cured bone cement formulations. © 1998 Kluwer Academic Publishers     

Secure Electronic Payments Based on Mobile Agents

The SET protocol for secure electronic payments, in particular its purchasing phase, is intended for users connected to the Internet during the entire transaction. This requirement cannot be easily met in high communication costs and/or low bandwidth settings, typically found in mobile computing environments.In this paper we describe SET/A, a system that works according to the SET rules for purchasing operations without forcing the user to be connected during the entire transaction. This is achieved by sending an agent to the merchant's server carrying all the data necessary to order and pay the goods (products, services or information). The paper shows that this can be achieved safely and efficiently, providing an alternative way for Internet payments using the SET protocol. We give our first impressions on SET/A usage by describing a prototype implementation based on a mobile agent system called AgentSpace, as well as a detailed example of what we consider a realistic application of the system.     

Comparison of burnt area estimates derived from satellite products and national statistics in Europe

Burnt area maps based on satellite observations are frequently used in calculations related to fire regime, such as those of carbon dioxide emissions. Nevertheless, burnt area estimates between products vary widely, and validation against independent data is scarce, especially for Europe. Here we compare two active fire maps (the ATSR World Fire Atlas and the Moderate Resolution Imaging Spectroradiometer (MODIS) Active Fire Product) and two fire scars maps (the L3JRC and the MODIS Burned Area Product) to independent national statistics taken from 22 European countries between 1997 and 2008. We also tested the coincidence between satellite products derived by calculation of the fraction of active fires that were confirmed by a subsequent drop in reflectance. As a large proportion of fire pixels (between 40% and 66%, depending on the product) is located on urban land or crop fields, filtering out fires located on these land uses greatly improves the agreement between satellite-based burnt area estimates and national statistics and it also improves the coincidence between satellite products. The MODIS Active Fire Product appears to be most suitable for use as a proxy for burnt area patterns, showing a high correlation to national statistics (R² = 0.9), relatively low spatial and temporal heterogeneity and only a slight underestimation of the total burnt area (19 000 ha year^–1). Unfiltered products show cases of substantial wildfire overestimation in all products, mainly attributable to anthropogenic activity, in the case of active fire products, and drought-induced vegetation dieback, in that of fire scar maps. Thus, filtering out fires on anthropogenic land uses seems to be essential when analysing patterns of forest fires from satellite observations. However, if agricultural fires are to be included, a combination of MODIS Active Fire and MODIS Burned Area products is recommended. We obtained that such combination shows low temporal and spatial heterogeneity and the highest coincidence between satellite products (25%), although the correlation to national statistics is not very high (R² = 0.67) and clearly underestimates the total burnt area (187 000 ha year^–1).     

Adding clicks to bricks: A study of the consequences on customer loyalty in a service context

With the explosion of the Internet many firms are incorporating technology into their marketing and operations and are adopting a multichannel strategy. The impact of this strategy has been especially high in the services area, which has traditionally relied on close, personal contact between customers and employees. This study explores how overall customer loyalty is built as a consequence of the value provided by each channel (offline and online). It also analyzes the moderating role of complexity of services used and customers’ Internet access in the service value–loyalty link. The model is tested with a sample of 302 multichannel financial services customers who use both the offline (traditional) and the online channel. Results show that offline perceived service value increases online perceived value; offline value has a stronger effect on overall loyalty than online value; and online service complexity and Internet adoption moderate the influence of service value on overall loyalty. Implications for management and theory are discussed.