Motor oil classification by base stock and viscosity based on near infrared (NIR) spectroscopy data

In this paper we have tried to build effective model for classification of motor oils by base stock and viscosity class. Three (3) sets of near infrared (NIR) spectra (1125, 1010, and 1050 spectra) were used for classification of motor oils into 3 or 4 classes according to their base stock (synthetic, semi-synthetic, and mineral), kinematic viscosity at low temperature (SAE 0W, 5W, 10W, and 15W) and kinematic viscosity at high temperature (SAE 20, 30, 40, and 50). The abilities of three (3) different classification methods: regularized discriminant analysis (RDA), soft independent modelling of class analogy (SIMCA), and multilayer perceptron (MLP) - were also compared. In all cases NIR spectroscopy was found to be quite effective for motor oil classification. MLP classification technique was found to be the most effective one.     

Inverse Analysis of Axisymmetrical Compression of HSLA Steel

The objective of the present work is to further explore the problem of selection of the flow stress function which will give the best agreement with experiments for a wide range of the Zener‐Hollomon parameter. Analysis of various flow stress functions was performed, with particular emphasis on the Zerilli‐Armstrong model. Inverse analysis was successfully applied to identify the flow stress model for microalloyed steels deformed in ferrite, two‐phase and austenite regions. Inverse method is applied to interpret the results of the axisymmetrical compression tests performed for HSLA steel samples on a Gleeble 3800 and Split Hopkinson Pressure Bar. Sensitivity analysis is performed based on local and global methods. The objective of the sensitivity analysis in the present study is the evaluation to what extent the selected coefficients in the rheological model influence the result of simulations. In the considered tests this result is represented by two dependent variables, the load and the shape of the sample (barrelling). It is confirmed that the Zerilli‐Armstrong equations should be applied at very high strain rates. Physical meaning is an advantage of this model. Difficulties with identification are the main disadvantage.     

Scale Transition in Steel-Concrete Interaction. II:?Applications

The proposed mode of consideration of the steel-concrete interaction (Part I) is applied to real-life engineering structures. Two structures recently investigated numerically at Vienna University of Technology are considered: (1) the reinforced concrete (RC) cooling tower III Ptolema?s SES (Greece) and (2) a part of the shotcrete tunnel lining installed at the Lainzer tunnel (Austria). In both examples, the uniaxial fracture criterion used in Part I is replaced by the maximum stress (Rankine) criterion. Together with the Drucker-Prager criterion, which is used for the simulation of compressive failure of concrete/shotcrete, it defines the space of admissible stress states in the framework of multisurface plasticity. For the simulation of early-age fracture of shotcrete, consideration of the steel-concrete interaction presented in Part I of this paper is extended towards young shotcrete. Similar to the benchmark problem investigated in Part I of this paper, several analyses with different degrees of consideration of the steel-concrete interaction are performed. The obtained results give insight into the influence of the steel-concrete interaction on the load-carrying behavior of the investigated structures.     

A novel low complexity data demodulation algorithm for pulse position modulation

In this paper, a low complexity data demodulation algorithm is proposed that requires time of arrival information of the received signal exclusively. As an application example, the algorithm is applied to an ultra-wideband impulse radio communication system with pulse position modulation. The algorithm is insensitive to a common time delay for all pulses, that means, it does not require an accurate synchronization between the transmitter and the receiver. For the performance estimation, only a symbol synchronization is assumed, i.e., that there is a priori knowledge which pulse marks the beginning of a received data symbol. The performance of the proposed algorithm is evaluated for straightforward time of arrivals estimators, such as a maximum detector or a threshold detector. It is shown that the proposed algorithm outperforms a least squares algorithm in all considered scenarios. In particular, an increased robustness against additive white Gaussian noise, impulse like noise, and multiuser interference is demonstrated as well as an improved performance for multipath propagation channels.     

Towards mesoscopic thermodynamics: Small systems in higher-order states

A higher-order generalization of the usual thermodynamic formalism is presented for systems with the number of particlesN large in comparison with 1, but sufficiently small that one or many higher-order fluctuations of energy (or other observables) are measurable, directly or indirectly. Then 1 «N «N _A , whereN _A is the Avogadro number, andn2, wheren is the highest order of fluctuations (central statistical moments). The systems are then open, finite and compact, and they have compact boundary surfaces, so that the energy is non-additive and temperatures are non-intensive, in general. Such systems will be called comesoscopic, while a finite or infinite super-system of such systems will be called mesoscopic. Three ideal models of comesoscopic systems are discussed in detail with one or two higher-order temperatures. General conclusions concerning hierarchical composite systems are drawn afterwards.

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Dynamic “Molecular Portraits” of Biomembranes Drawn by Their Lateral Nanoscale Inhomogeneities

To date, it has been reliably shown that the lipid bilayer/water interface can be thoroughly characterized by a sophisticated so-called “dynamic molecular portrait”. The latter reflects a combination of time-dependent surface distributions of various physicochemical properties, inherent in both model lipid bilayers and natural multi-component cell membranes. One of the most important features of biomembranes is their mosaicity, which is expressed in the constant presence of lateral inhomogeneities, the sizes and lifetimes of which vary in a wide range—from 1 to 10³ nm and from 0.1 ns to milliseconds. In addition to the relatively well-studied macroscopic domains (so-called “rafts”), the analysis of micro- and nanoclusters (or domains) that form an instantaneous picture of the distribution of structural, dynamic, hydrophobic, electrical, etc., properties at the membrane-water interface is attracting increasing interest. This is because such nanodomains (NDs) have been proven to be crucial for the proper membrane functioning in cells. Therefore, an understanding with atomistic details the phenomena associated with NDs is required. The present mini-review describes the recent results of experimental and in silico studies of spontaneously formed NDs in lipid membranes. The main attention is paid to the methods of ND detection, characterization of their spatiotemporal parameters, the elucidation of the molecular mechanisms of their formation. Biological role of NDs in cell membranes is briefly discussed. Understanding such effects creates the basis for rational design of new prospective drugs, therapeutic approaches, and artificial membrane materials with specified properties.     

Synthesis of titanium aluminide coatings on aluminum and titanium surfaces by mechanical alloying and subsequent annealing

Intermetallic Ti-Al-based coatings were synthesized by mechanical alloying in a vibratory ball mill and subsequent annealing. A titanium layer was deposited on aluminum specimens and an aluminum layer and aluminum-titanium mixture were deposited on titanium specimens. Under the effect of milling balls, powder particles deposit at the substrates, forming layers that have a very good cohesion with the substrate. During subsequent heating, diffusion layers on the basis of titanium-aluminum phases are synthesized as a result of the chemical interaction between titanium and aluminum. In the case of titanium layer deposited on aluminum, the temperature interval of transformations is 600–650°C; first, a Ti₃Al₅-based phase is formed; then, as diffusion saturation with Al increases, an Al₂Ti-based layer appears; and finally, the Al₃Ti compound is formed. The reaction rates depend on the temperature and the duration of annealing. On titanium with a (Ti + Al) layer deposited on its surface, the Al₃Ti, Al₂Ti, TiAl, and Ti₃Al compounds are formed in a temperature interval of 600–900°C. In the case of deposition a homogeneous aluminum layer on titanium, only Al₃Ti and Ti₃Al phases were observed after annealing.     

Synthesis and crosslinking properties of phenolphtalein dimethacrylate

Summary By reacting esterification of phenolphtalein with methacrylate chloride, phenolphtalein dimethacrylate was obtained. Based on the results of elemental analysis, FTIR, ¹H-NMR and ¹³C-NMR spectra, the structure of the product was proposed. The dimethacrylate was used as new crosslinker to crosslink poly(methyl methacrylate) (PMMA). The influence of the amount dimethacrylate on the crosslink density and some properties of the crosslinked polymers networks such as swelling, mechanical properties (tensile strength and elongation at break) and thermal stability were examined.     

Simple method for estimation of volatile carbonyl compounds in edible oils and fried potato chips

A simple and sensitive method has been devised to determine the amounts of volatile carbonyl compounds in vegetable oils and fried potato chips, using a chemical reaction trap and absorption spectrophotometry. A sample of oil or fried potato chips is heated and simultaneously purged with a flow of nitrogen gas which further bubbles through a tube (trap) containing a hydroxylamine hydrochloride solution. The volatile carbonyl compounds are removed from the sample with the purge gas and retained in the trapping solution as they react to form the less volatile oxime derivatives. These are subsequently estimated by ultraviolet absorption, at wavelength 212 nm for the total oximes and at 272 nm specifically for conjugated diene carbonyl oximes, including furfural if present. Volatile carbonyls can be determined by this method at levels as low as 0.1–0.5 ppm of the sample. The method has been applied to the analysis of samples of canola (low erucic acid rapeseed) oil, cottonseed oil, and potato chips, all before and after storage. The method should be suitable also for other types of fried food.