Neighborhood disadvantage moderates associations of parenting and older sibling problem attitudes and behavior with conduct disorders in African American children.

Data from 296 sibling pairs (mean ages 10 and 13 years), their primary caregivers, and census records were used to test the hypothesis that African American children's likelihood of developing conduct problems associated with harsh parenting, a lack of nurturant-involved parenting, and exposure to an older sibling's deviance-prone attitudes and behavior would be amplified among families residing in disadvantaged neighborhoods. A latent construct representing harsh-inconsistent parenting and low levels of nurturant-involved parenting was positively associated with younger siblings' conduct disorder symptoms, as were older siblings' problematic attitudes and behavior. These associations were strongest among families residing in the most disadvantaged neighborhoods. Future research and prevention programs should focus on the specific neighborhood processes associated with increased vulnerability for behavior problems. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Perceived employment barriers and their relation to workforce-entry intent among people with HIV/AIDS.

As treatments have improved health and quality of life for people with HIV/AIDS, many have contemplated workforce reentry. Workforce reentry rarely occurs among people with illness-related disability. The authors mailed a survey that included workforce-entry-related concerns to 1,991 HIV/AIDS clients. Factor analysis extracted 6 areas of concern (benefits loss, work-related health, job skills, discrimination, personal health care, workplace accommodation). Levels of concern generally increased with HIV acuity level and time since last worked. Work-related health concerns predicted consideration of workforce entry, and work-related health concerns and benefits-loss concerns predicted estimated time to return to work. Findings provide quantitative validation of intuitive categories of workforce-entry concerns among people with HIV/AIDS and suggest that concerns may shift with progress toward workforce entry. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Benzylation of thiophene using zinc and iron chloride modified montmorillinite clay

Montmorillinite clays, modified with either Zn(II) or Fe(III) chlorides have been used to catalyze the Friedel-Crafts alkylation of thiophene. High yields (ca. 80%) of 2- and 3-benzylthiophene mixtures were obtained using either catalyst in chlorobenzene or nitrobenzene solvent at 80°C. The ratio of 2–3-products was found to be controlled by their relative stability. Reactions were most rapid in nitrobenzene solution (<5 min) and resulted in formation of the 2-isomer as the only mono-substituted product. This is believed to be the first example in which an alkylation of thiophene has been limited to one regio-isomer.     

Evidence for Remote Effects of Dreissenid Mussels on the Amphipod Diporeia: Analysis of Lake Ontario Benthic Surveys, 1972–2003

The status of invasive dreissenid mussels (Dreissena polymorpha and D. bugensis) and native amphipods (Diporeia spp.) in Lake Ontario was assessed in 2003 and compared with historical data. D. polymorpha (zebra mussels) were rarely observed in 2003, having been displaced by D. bugensis (quagga mussels). D. bugensis expanded its depth range from 38 m depth in 1995 to 174 m in 2003 and this dreissenid reached densities averaging 8,000/m² at all sites < 90 m. During the same time period, Diporeia populations almost completely disappeared from 0–90 m depth, continuing a declining trend from 1994–1997 reported in previous studies. The average density of Diporeia in the 30–90 m depth interval decreased from 1,380/m² to 63/m² between 1997 and 2003. Prior to 2003, areas deeper than 90 m represented a refuge for Diporeia, but even these deep populations decreased, with densities declining from 2,181/m2 in 1999 to 545/m2 in 2003. Two common hypotheses for the decline of Diporeia in the Great Lakes are food limitation and a toxin/pathogen associated with dreissenid pseudofeces. The Diporeia decline in deep waters preceded the expansion of D. bugensis to these depths, and suggests that shallow dreissenid populations remotely influence profundal habitats. This pattern of decline is consistent with mechanisms that act from some distance including nearshore dreissenid grazing and downslope transport of pseudofeces.     

Estimating areal means and variances of forest attributes using the k-Nearest Neighbors technique and satellite imagery

The k-Nearest Neighbor (k-NN) technique has become extremely popular for a variety of forest inventory mapping and estimation applications. Much of this popularity may be attributed to the non-parametric, multivariate features of the technique, its intuitiveness, and its ease of use. When used with satellite imagery and forest inventory plot data, the technique has been shown to produce useful estimates of many forest attributes including forest/non-forest, volume, and basal area. However, variance estimators for quantifying the uncertainty of means or sums of k-NN pixel-level predictions for areas of interest (AOI) consisting of multiple pixels have not been reported. The primary objectives of the study were to derive variance estimators for AOI estimates obtained from k-NN predictions and to compare precision estimates resulting from different approaches to k-NN prediction and different interpretations of those predictions. The approaches were illustrated by estimating proportion forest area, tree volume per unit area, tree basal area per unit area, and tree density per unit area for 10-km AOIs. Estimates obtained using k-NN approaches and traditional inventory approaches were compared and found to be similar. Further, variance estimates based on different interpretations of k-NN predictions were similar. The results facilitate small area estimation and simultaneous and consistent mapping and estimation of multiple forest attributes.     

CONDITIONING COAL GAS WITH REFRIGERATED METHANOL IN A SYSTEM OF PACKED COLUMNS

Experience with the operation of a pilot-scale unit is used to outline potential difficulties in the operation of acid gas removal systems on gases produced from coal. The pilot plant has been used to condition gases produced from subbituminous coal, devolatilized char, peat and lignite. The solvent used in the acid gas removal system has been refrigerated methyl alcohol. Data from this study document accumulation of hydrocarbons, sulfur and nitrogen compounds, and mercury in the circulating solvent.