An improved hybrid nanocomposites of rice husk derived graphene (GRHA)/Zeolitic imidazolate framework-8 for hydrogen adsorption

In this work, hybrid nanocomposites rice husk derived graphene (GRHA) and zeolitic imidazolate framework-8 (ZIF-8) were prepared for hydrogen adsorption. The main contribution of this study is the simplification of the synthesized GRHA/ZIF-8 hybrid nanocomposites. Besides that, the use of synthesized graphene from rice husk (RH) could help in overcoming environmental issue since disposal of RH is rather challenging. GRHA was obtained through calcining rice husk ash (RHA) at 900 °C for 2 h in a muffle furnace at atmospheric condition while the nanocomposite of GRHA/ZIF-8 was produced in free solvent condition using deionized water at room temperature for only 1 h. The N₂ adsorption-desorption indicated a type I isotherm. Interestingly, it was found that the BET specific surface area (BET_SSA) of GRHA/ZIF-8 showed enhancement up to 3 times higher as compared to pristine GRHA with the addition of 0.2 g of GRHA. From the experimental data, the adsorption of H₂ by nanocomposite GRHA/ZIF-8 obeyed the pseudo-second order kinetic model and intraparticle diffusion model with R² value up to 0.9890 and 0.8087 respectively at 12 bar. Moreover, the GRHA/ZIF-8 possessed highest hydrogen adsorption of 31.84 mmol/g at 12 bar. These impressive results are justified by the combination of ZIF-8's microporosity and GRHA's mesoporosity.     

Removal of Toxic Mercury from Petroleum Oil by Newly Synthesized Molecularly-Imprinted Polymer

In recent years, molecularly-imprinted polymers (MIPs) have attracted the attention of several researchers due to their capability for molecular recognition, easiness of preparation, stability and cost-effective production. By taking advantage of these facts, Hg(II) imprinted and non-imprinted copolymers were prepared by polymerizing mercury nitrate stock solution (or without it) with methacrylic acid (MAA), 2-hydroxyl ethyl methacrylate (HEMA), methanol and ethylene glycol dimethacrylate (EGDMA) as the monomer, co-monomer solvent (porogen) and cross-linker, respectively. Thus, the formed Hg(II) imprinted polymer was characterized by using Fourier transform infrared spectroscopy (FTIR), field emission scanning electron microscopy (FESEM), Brunauer, Emmett and Teller (BET) and thermal gravimetric analysis (TGA). The separation and preconcentration characteristics of Hg(II) imprinted polymer were investigated by solid phase extraction (SPE) procedures, and an optimal pH of 7 was investigated as ideal. The specific surface area of the Hg(II) imprinted polymer was found to be 19.45 m²/g with a size range from 100 to 140 µm in diameter. The maximum adsorption capacity was observed to be 1.11 mg/g of Hg(II) imprinted beads with 87.54% removal of Hg(II) ions within the first 5 min. The results of the study therefore confirm that the Hg(II) imprinted polymer can be used multiple times without significantly losing its adsorption capacity.     

Experimental analysis on a novel low-temperature vacuum drying with induced nucleation technique for dewatering stingless bees honey

Honey spoilage is a major problem in storing stingless bee honey. A new method of honey dewatering was developed using a low-temperature vacuum drying with induced nucleation technique. The research’s objective is to investigate the performance of this method in reducing honey’s water content. Two different dewatering temperatures were applied until honey’s water content reached below 20%. The honey’s chemical compound before–after dewatering from one of the samples was tested using nuclear magnetic resonance (NMR) analysis. The dewatering rate improves significantly with higher temperature. The NMR analysis result found no changes in chemical compound before–after experiment except for ethanol.     

Storage stability,color kinetics and morphology of spray-dried soursop (Annona muricata L.) powder: effect of anticaking agents

Soursop is a tropical fruit that undergoes postharvest deterioration rapidly. Conversion into powder is an ave nue to value-add the fruit as it helps to reduce postharvest losses. Although powder production is not complicated, studies have shown that caking is a common problem often associated with fruit powders. Thus, an addition of a food additive is needed to improve the storage stability of powders. In this study, soursop powder was produced by spray-drying an enzyme-liquefied soursop puree incorporated with either tricalcium phosphate (TCP) or calcium silicate (CS), at three different concentrations (0.5, 1.0, and 1.5% w/w). The control was considered powder without the addition of anticaking agent. Storage stability of the powder packed in aluminum-laminated polyethylene (ALP) pouches was examined at conventional (25 ± 1°C) and accelerated (38 ± 1°C) temperatures for 91 days until lumpiness was observed. Statistical analysis showed that the addition of anticaking agent significantly (p ≤ 0.05) improved the process yield of powder (7.2%). The moisture content, water activity, density, and water solubility index of the powder were significantly affected by storage time, storage temperature, and concentration of the anticaking agents. The critical moisture content, X_c, for control and powder incorporated with either TCP or CS was 0.07 g H₂O/g ds. The total color difference (ΔE) of the powder increased throughout the storage period, followed by a zero-order kinetic reaction. Kinetics-derived Arrhenius model showed that the activation energy (Ea) of color change ranged between 6.5 and 17.3 kJ/mol. Scanning electron microscopy showed that the freshly spray-dried powder was composed of spherical particles with smooth surfaces but these particles tended to agglomerate and form liquid bridges after storage for 91 days. Overall, TCP and CS exhibited a protective effect by lowering moisture adsorption and improved the glass transition temperature of the powder.     

Intermittent Audio Failure Analysis of a Remote Speaker-Microphone for a Two-Way Radio

This paper presents a case study of an intermittent audio failure analysis of a remote speaker-microphone module for a two-way radio. A root cause analysis was undertaken to identify probable causes of the intermittent failure, followed by a series of experiments to determine the strength and the intermittent audio failure load of cable components and the fully assembled cable. The combined experimental and finite element results demonstrated that the main contributor of the intermittent audio failure was the micro surface cracks on the copper conductor strands. In addition, the combination of the component materials and design of the cable have also contributed to the non-uniform state of residual stress induced in the copper conductors which have reduced the ability of the copper conductors to withstand the normal handling load under the influence of micro surface cracks.     

A novel ISO 6983 interpreter for open architecture CNC systems

The International Journal of Advanced Manufacturing Technology - Computer numerical control (CNC) technology is a key technology in machine tools and is also the base of industrial unit...     

Diurnal pattern of global solar radiation in the tropics: a case study in Malaysia

Global solar radiation patterns in Bangi (2°56′7.3″N, 105°47′0.2″E), Malaysia are discussed. The frequency of occurrence of the various solar radiation patterns observed over a 5-year period is derived. These observations will provide useful information for the design of solar energy systems and equipment for installation in tropical countries having a similar global solar radiation pattern.     

Classification of Honey from Its Bee Origin via Chemical Profiles and Mineral Content

Raw honeys from four different bee species, namely the honey bees and stingless bees, were classified based on its chemical profiles, mineral contents and heavy metals. Chemical profiles including proximate composition, predominant sugars, hydroxymethylfurfural content, and diastase activity were determined following official methods while mineral and heavy metals contents were obtained from atomic adsorption spectrometry (AAS) and inductively coupled plasma-mass spectrometry (ICP-MS) measurements, respectively. Both hierarchical cluster analysis and principal component analysis show high possibility of distinguishing honey by its bee species of honey bees (Apis spp.) and stingless bees (Heterotrigona itama) based on distinctive differences in chemical compositions and mineral contents. Potassium and sodium were the major elements in raw honey samples at average of 904.9 and 617.6 mg/kg, respectively. Honey from stingless bee contained more protein, 0.85 g/100 g and less total sugar of fructose and glucose at 24.99 g/100 g. The information of bee speciation origin of honey bees and stingless bees enhances the identity of honey on the product labelling.     

Effect of Particle Size on Direct Compaction of Urea Fertilizer

The effect of particle size on compaction properties and characteristics of urea tablets manufactured from available urea granules (TG tablets) and ground urea powders (TP tablets) was investigated. The compaction properties, namely, plastic work, elastic work, friction work, and maximum ejection pressure were analyzed from the force-displacement profile of the compaction process. Five applied pressures ranging between 37.67 MPa and 188.35 MPa were used to compact the materials using a universal testing machine. Characteristics of the tablets tested were mechanical strength and the release of ammonium ion through dissolution test. The results demonstrated that TG tablets underwent high plastic work and elastic work but low friction work compared to the TP tablets. TG tablets released lower amount of ammonium ion compared to the TP tablets at almost all applied pressures, except at 75.34 MPa. This study provides a valuable data for evaluating the behavior of urea in the form of granules and powders during the compaction process as well as the suitability in choosing the form of raw material for the production of urea tablets.     

Process Noise Parameters of Beamforming Green Nodes

Signals arrive out of phase at the intended receiver from collaborative beamforming (CB) nodes due to the instability in the output frequency signals of the universal software radio peripheral's (USRP) local oscillator (LO). These nodes including the target must synchronize their oscillator frequencies for coherent signal reception. In order to do this, frequencies and phases of the signals should be estimated in software defined radio (SDR) and smoothen with nonlinear filters such as the extended Kalman filter (EKF). The process noise parameters of the NI USRP-2920 nodes will have to be calculated and used with the EKF process noise covariance matrix. These nodes are green communication hardware devices where most of the hardware units are now software defined. This article uses the direct spectrum method to obtain the phase noise values at various frequency offsets of the NI USRP-2920 in order to calculate the power spectral density of fractional frequency fluctuation. By applying the power-law noise model to this obtained value, the generated white frequency noise and random walk frequency noise values are q1=1.9310-21 and q2=5.8610-18, respectively.