Craze yielding and fracture mechanism in PE/PS/PE laminated films

The change in polystyrene (PS) layer thickness, which has been simultaneously determined during post-yield deformation, shows that crazing is the basic mechanism of toughening in all laminated films, and that shear deformation supplements the contribution of crazing especially for samples with high polyethylene (PE) volume fractions. Crazes formed in PS layers in the laminated films are slender and regular compared with the short and lenticular crazes formed in bulk PS film. When PE volume fraction increased, craze advance speed decreased because of the reduction of the stress concentration effect at craze tips. The life-time of the first mature craze to be formed at a given strain rate increased with PE volume fraction because the PE supporting the mature crazes could effectively inhibit craze rupture and blunt out the propagating crack by absorbing the stored elastic energy in the PS layer that would have been dissipated as fracture surface energy.     

Study of dielectric properties of RbNO3 single crystals

Dielectric properties, dielectric constant (k), dielectric loss (tan δ) and a.c. conductivity (σ) in the solution-grown single crystals of RbNO₃ are presented from room temperature to about 200°C covering the frequency range 10² to 10⁵ Hz. A broad peak observed in tan δ-frequency data between 10³ and 10⁵Hz is thought to be due to impurity-vacancy dipoles. The sudden rise of three parameters near 160°C is attributed to the known phase transition from trigonal to CsCl structure.     

Optical properties of graphite-like carbon films

A model of the electronic structure of graphite-like carbon films, describing the semiconductor properties of this material, is presented. Spectra of optical constants of microcrystalline carbon films in the region λ = 0.4–8.0 μm were studied by the spectral ellipsometry and IR reflection methods. A number of distinctive features of the spectra, associated with both the appearance of C---C- and C---H_n-type bonds and direct energy gaps, were found. Analysis of the optical data using the proposed model makes possible a common interpretation of our results and literature data. Values of a parameter Θ, which is an averaged qualitative parameter of structural distortions within carbon microcrystallites as compared with crystalline graphite, are determined from comparison of theoretical results and experimental data.