A Practical Method to Derive Sample Temperature during Nonisothermal Coupled Thermogravimetry Analysis and Differential Scanning Calorimetry Experiments

Nonisothermal thermogravimetry differential scanning calorimetry (TG‐DSC) mounting is intensively used for the determination of kinetic parameters and reaction heat along the chemical transformation of a solid. Nevertheless, when tests are performed with heating rates as high as those encountered in industrial processes, e.g., several tens of K min^–1, there is great uncertainty in the knowledge of the exact sample temperature. In this work, a method to derive a simple mathematical expression is proposed and fully described in order to calculate the real sample temperature throughout a temperature‐ramped test on a commercial apparatus. The furnace temperature and the heat flow signals were used, together with the crucible specific heat and the heating rate. A number of validation tests were performed to derive similar reaction rates for a reference. First‐order kinetic reactions were presented and reconciled over a large range of heating rates from 3 to 50 K min^–1.     

Ecophysiology of ochratoxigenic Aspergillus ochraceus and Penicillium verrucosum isolates. Predictive models for fungal spoilage prevention - a review

Ochratoxin A (OTA) is a secondary metabolite produced by several species of Aspergillus and Penicillium; among them Aspergillus ochraceus and Penicillium verrucosum are two ochratoxigenic species capable of growing in different climates and thus contamination of food crops with OTA can occur worldwide. OTA can be found in a wide range of foods such as cereals, coffee, cocoa, spices, beer, wine, dried vine fruit, grapes and meat products. OTA is toxic to animals, it presents neurotoxic, immunotoxic and nephrotoxic effects. It has been implicated in a human kidney disorder known as Balkan Endemic Nephropathy. This review focuses on the ecophysiology of ochratoxin-producing Aspergillus ochraceus and Penicillium verrucosum, the effect of environmental factors on their germination, mycelial growth, and OTA production. Knowledge of environmental conditions required for sucessive stages of fungal development represent the first step towards preventing mycotoxin formation. Predictive models for different stages of fungal development are presented, which allow prediction of the time before spoilage as a function of the abiotic factors. Finally, the implications of these studies in management of barley, coffee and grapes are described. This can help to identify the critical control points in their production, storage and distribution processes.     

Kinetics of AuSn4 migration in lead-free solders

The relatively fast diffusion of Au atoms in eutectic PbSn matrix is considered one of the contributing factors to the Au embrittlement problem. In this study, we further investigated the Au embrittlement problem in high-Sn solders. Experimentally, Sn3.5Ag (wt.%) spheres with 500-μm diameter were soldered over the Au/Ni soldering pads. It was found that some of the AuSn₄ needles that formed after reflow inside the solder migrated back to the solder/pad interface during thermal aging. However, the migration kinetics in high-Sn solders was slower compared to that in eutectic PbSn. The difference in migration kinetics of AuSn₄ in eutectic PbSn and SnAg was ascribed to the difference in the magnitudes of the Au flux and the Ni flux. In eutectic PbSn, the Au flux was much greater than that of the Ni flux, and the Au and Ni flux were in the same order of magnitude in eutectic SnAg. The relative magnitude of the Au and Ni flux changed in eutectic PbSn and SnAg because the homologous temperatures of PbSn and SnAg were different.     

Functional characteristics of Bi2Sr2Ca2Cu3O10 + δ/ZrN composites

We present the results of investigation of the magnetic, transport, structural, and mechanical properties of composites obtained by introducing finely dispersed zirconium nitride into a matrix of a Bi₂Sr₂Ca₂Cu₃O_{10 + δ} (Bi2223) high-temperature superconductor. It is established that the introduction of ZrN particles in the range of very small concentrations (0.1–0.3 wt %) leads to a significant (more than threefold) increase in the critical current density of Bi2223 and increases the density of the composite, while the microhardness of the superconducting phase remains unchanged.     

Mössbauer study of the Ge two-electron donor centers in PbSe

Mössbauer emission spectroscopy at ⁷³As(⁷³Ge) is used to show that the charge state of the ⁷³Ge antisite defect formed in the anion sublattice after the radioactive transformation of ⁷³As is independent of the position of the Fermi level. In contrast, the ⁷³Ge center in the cation sublattice of PbSe is an electrically active substitutional impurity. For the n-type samples, the spectrum corresponds to the neutral state of the donor center (⁷³Ge²⁺), and for the p-type samples, the spectrum corresponds to the doubly ionized state (⁷³Ge⁴⁺) of this center.     

The characteristics and measuring technique of refractory dissolved organic substances in urban runoff.

It is considered that refractory dissolved organic substances have caused an increase in the COD concentration in Lake Biwa in recent years. We investigated the organic matter in the first flush of stormwater runoff from a road in the watershed area of the lake, and studied the possibility of improvement in the water environment from that aspect. After percolating the stormwater through soil, we analyzed organic substances fractionated by using GPC-TC. And we examined the effect of removal of organic substances by comparing the peak height before and after percolation. In the result of the experiments, we found that soil infiltration reduced the refractory dissolved organic substance and we successfully designed a system for a simple and easy experimental facility to treat urban runoff.     

Steady-state longitudinal vibrations of sectional,physically nonlinear plates

The artile deals with steady-state longitudinal vibrations of plates consisting of curvilinear rings placed one inside the other without interference, under the effect of a harmonic distorting load acting along the outer periphery. The rings are made from different isotropic materials that are physically nonlinear. The problem is solved by the method of successive approximations. In each approximation the sought functions are represented in the form of expansions with respect to a small parameter. Numerical investigations were carried out for plates consiting of two concentrically arranged circular rings.Translated from Problemy Prochnosti, No. 3, pp. 24–27, March, 1991.