科技论文参考文献著录的规范表达

依据ＧＢ７７１４－８７《文后参考文献著录规则》,对３９０篇来稿所引用的参考文献进行统计,分析了几种不规范的著录方式,并给出正确的表达方法,可为科技论文写作者及科技期刊编缉提供参考。     

Formation of Triterpenoids throughout <Emphasis Type="Italic">Olea europaea</Emphasis> Fruit Ontogeny

Drupes were handpicked from olive (Olea europaea L.) trees, cv chemlali, at 13 distinct stages of fruit development, referred to as weeks after flowering (WAF), and analyzed for their free and esterified sterols and triterpenoids content. These two classes of compounds are synthesized via the acetate/mevalonate pathway and share common precursors up to oxidosqualene (OS). Cyclization of OS in either cycloartenol or beta-amyrin constitutes a branch point between primary (sterol pathway) and secondary (triterpenoid pathway) metabolisms. At the onset of fruit development, i.e., between 12 and 18 WAF, drupes were found to contain high amounts of alpha- and beta-amyrins as well as more-oxygenated compounds such as triterpenic diols (erythrodiol and uvaol) and acids (oleanolic, ursolic and maslinic acids). Concomitantly, sterol precursors were barely detectable. From 21 WAF, when the olive fruit reached its final size and began to turn from green to purple, alpha- and beta-amyrins were no longer present, while 4,4-dimethyl- and 4alpha-methylsterols started to be formed, indicating a redirection of the carbon flux from the triterpenoid pathway towards the sterol pathway. Between 21 and 30 WAF, sterol end products, mainly represented by sitosterol, progressively accumulated and triterpenic diols were replaced by triterpenic acids, essentially maslinic acid. Interestingly, the developing olive fruit was found to accumulate significant amounts of parkeol as an ester conjugate. Whatever the stage of development, triterpenoids represent the major triterpenic compounds of the olive fruit.     

Melt processing of ethylene–vinyl acetate/banana starch/Cloisite 20A organoclay nanocomposite films: structural,thermal and composting behavior

This work shows the preparation of ethylene vinyl acetate copolymer/banana starch/Cloisite 20A organoclay (EVA/starch/C20A) nanocomposites by melt processing. Wide angle X-ray diffraction (WAXD), field emission scanning electron microscopy (FE-SEM), differential scanning calorimetry and thermogravimetric analysis were used to characterize the obtained nanocomposites. Mechanical properties were also determined. In addition, the performance of the nanocomposite films under composting was preliminarily studied; it was conducted using the soil burial test method. Despite knowing that the starch is difficult to process by extrusion, nanocomposite films with high homogeneity were obtained. In this case, C20A organoclay acts as an effective surfactant to make the starch natural polymer compatible with the EVA synthetic polymer. The good compatibility between EVA, starch and C20A clay was also deduced by the formation of intercalated and intercalated-exfoliated structures determined by WAXD and FE-SEM. Physical evidence of the damage in EVA/starch/C20A nanocomposite films after the composting test was observed. It is worth noting that despite the absence of starch, the EVA/C20A nanocomposite film, used as a control, also showed surface damage. This behavior is related to the organic modifier linked to clay C20A, which contains molecules derived from fatty acids that can be used as a food source for microorganisms.

     

Phosphorus–nitrogen-type fire-retardant vinyl ester resin with good comprehensive properties

In this study, a series of fire-retardant vinyl ester resins (VERs) were obtained via the copolymerization of phosphorus–nitrogen-containing acrylate [1,3,5-triglycidyl isocyanurate (TGIC)–acrylic acid (AA)–9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO)] and the widely used vinyl ester resin 901 (901-VER). The influences of the TGIC–AA–DOPO additive amount on 901-VER were comprehensively evaluated via the measurement of the flame retardancy, thermal performance, and mechanical properties. In the case of 30 and 40% TGIC–AA–DOPO, the thermosets acquired limited oxygen index values of 30.8 and 31.7%, respectively, and reached vertical burning (UL-94) ratings of V-1 and V-0, respectively. In addition, their peak heat-release rates, average heat-release rates, total heat release values, average effective heats of combustion, and total smoke productions decreased significantly. These results demonstrated the great progress of 901-VER in fireproofing performance. More importantly, the flame-retardant VER thermosets showed good thermal properties and castings, and glass-fiber-reinforced composites based on the developed fire-retardant VERs possessed comparable tensile strength, flexural strength, and better tensile modulus comparing to those based on neat 901-VER when the TGIC–AA–DOPO amount was no greater than 30%. From an integrated perspective, 901-VER with 30% TGIC–AA–DOPO was the best desired. The excellent flame retardancy, thermal performance, and mechanical properties promise the as-obtained VER important applicable values. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47997.     

Fertilizer recommendations for maize production in the South Sudan and Sudano-Guinean zones of Benin

The present study aims to determine fertilizer (N–P–K) recommendations for maize (Zea mays L.) on Acrisols (south Benin) and Ferric and Plintic Luvisols (centre Benin). Two years (2011 and 2012) experiment was conducted at Dogbo and Allada districts (southern) and Dassa (centre Benin). Six on-farm experiments were carried out to validate fertilizer rates simulated by the DSSAT model. The experimental design in each field was a completely randomized bloc with four replications and ten N–P–K rates: 0–0–0 (control), 44–15–17.5 (standard fertilizer recommendation for maize), 80–30–40, 80–15–40, 80–30–25, 80–30–0, 69–30–40, 92–30–40, 69–15–25 and 46–15–25 kg ha^?1. Treatments 44–15–17.5 and 46–15–25 showed the lowest grain and stover yields. The observed maize grain yields were highly correlated with the estimated grain yields (R² values varied between 80 and 91% for growing season 2011 and between 68 and 94% for growing season of 2012). The NRSME values varied between 12.54 and 22.56% (for growing season of 2011) and between 13.09 and 24.13% (for growing season of 2012). The economic analysis for the past 32 years (1980–2012) including the current experiment showed that N–P–K rates 80–30–25 (at Dogbo), 80–15–40 (at Allada) and 80–30–0 (at Dassa) were the best fertilizer recommendations as they presented the highest grain yields and the best return to investment per hectare. Nevertheless, 80–30–25 is advised for Dassa considering that sustainable maize production will require regular inputs of potassium. The 2 years of field experiments were not sufficient to derive biophysically optimal fertilizer recommendation rates for each site.     

基于螺旋片强化的套管换热器性能

基于RNG k-ε模型对螺旋片强化的套管换热器的传热进行模拟,通过模拟结果与文献中的实验结果进行对比来验证模拟的可行性;分析了Reynolds数为2362～16860范围内的螺旋升角α变化对Nusselt数和摩擦阻力系数f的影响;并考察了等泵功率下的综合传热性能PEC值的变化规律。结果表明：Nu和f的平均误差分别为7.1%和1.3%,证明所采用的研究方法是可行的;α在15°～75°范围内,Nu和f均随着α的减小而增大,特别地,当α小于35°时,f随α的减小剧烈增大;在等泵功率下,PEC值为0.84～1.93;α在15°～45°时,α为35°具有较好的综合传热性能,α为55°、65°和75°时,虽然其PEC值比35°时略高,但其Nu与35°时相比要小很多,实际应用中考虑到传热速率的问题,选择35°的螺旋升角较为合适,此时,PEC值为1.26～1.62。另外,为减小f,提出倾斜螺旋片强化的方法;螺旋升角α为35°、螺旋片倾斜角β为10°时,与普通螺旋片相比,Nu基本一致,甚至略大,而f减小了12.5%～14.5%,此时,PEC值为1.38～1.71;场协同理论也很好地验证了这一结果。     

Microcellular polymeric foams based on 1‐vinyl‐2‐pyrrolidone and butyl‐acrylate with tuned thermal conductivity

Microcellular polymers have been produced by ScCO₂ foaming, based on 1‐vinyl‐2‐pyrrolidone (VP) and butyl‐acrylate (BA). Three different copolymers were prepared, varying the compositions of VP and BA, following a simple radical polymerization process using an UV initiator. The samples a good foaming behavior and also excellent flexibility and handle ability, with expansion ratios between 1.53 and 1.72, and cell sizes in the microcellular range (below 5 µm). However, it was observed that the gas distribution and, consequently, the cellular structure inside the polymer foams was highly dependent on the VP and BA proportions, leading to very different thermal conductivity values, even for similar volume gas fraction values. These results were related to the copolymer nanostructuration, which seems to have an influence in the final pore structure, thus opening the possibility of designing microcellular foams with similar macroscopic characteristics but different thermal conductivity values. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018 , 135, 45872.     

Effect of B2O3 on the structural and in vitro biological assessment of mesoporous bioactive glass nanospheres

In this paper, the boron-containing mesoporous bioactive glass (MBG) nanospheres have been successfully synthesized by modified sol-gel method assisted by surfactant, and the effect of boron substitution on structure and bioactivity was evaluated by combining experiments and ab initio molecular dynamics (AIMD) simulations. All of the samples exhibit regularly uniform mesoporous spherical microstructure with an average size of about 60 nm, and the boron-containing MBGs show higher specific surface area with the value up to 416.20 m²/g. The simulated body fluid (SBF) immersion test confirms that the deposited hydroxyapatite (HA) evidently increases with the increasing of boron content, indicating that the biological behavior has been significantly improved resulting from incorporation of boron. Additionally, our results also reveal that B₂O₃ substitution has positive impact on cell proliferation of human periodontal ligament cells (hPDLCs) at lower extracted concentration. Furthermore, AIMD simulation is employed to understand the relationship between structural changes and in vitro bioactivity in terms of structural information, especially the boron coordination number. The results illustrate that the boron-containing MBG nanospheres with excellent bioactivity are great potential for biomedical applications.     

A Study on the Impact of the Adhesion of Penicillium expansum on the Physicochemical Surface Properties of Cedar Wood

The sessile drop technique was used to investigate the evolution of the physicochemical properties of cedar wood as a function of contact time with the Penicillium expansum spores. The most important finding showed that the impact of different contact periods (2, 4, 6, 8, 10, and 24 hr) on the wood surface were very indicative. In fact, after 2 hr of contact, the results have shown a significant impact of the bioadhesion of spores to the substrate on both the hydrophobic character (θ_W = 108.5°; ΔGiwi = ?28.25 mJ/m²), the electron donor (γ^? = 13.63 mJ/m²), and the electron acceptor (γ⁺ = 4.35 mJ/m²) parameters that were significantly reduced compared to the initial wood (θ_W = 118.5°; ΔGiwi = ?6.29 mJ/m²; γ^? = 32.1 mJ/m²; and γ⁺ = 9.1 mJ/m²). In addition, this decrease of parameters continued over time to stabilize after 10 hr of contact. Indeed, after 24 hr, the acid/base properties were almost zero and the contact angle with water decreased to 30°. Moreover, it was found that the coefficient of correlation (r²) was strong between the contact angle with water, the surface energy, and the electron acceptor character with the contact time parameter with values (r² = 0.65), (r² = 0.79), and (r² = 0.68), respectively.     

Synthesis and dissolution behavior of nanosized silicon and magnesium co-doped fluorapatite obtained by high energy ball milling

Nanosized hydroxyapatite (HA) powders exhibit a greater surface area than coarser crystals and are expected to show an improved bioactivity. In addition, properties of HA can be tailored over a wide range by incorporating different ions into HA lattice. The aim of this study was to prepare and characterize silicon and magnesium co-doped fluorapatite (Si–Mg–FA) with a chemical composition of Ca_9.5Mg_0.5 (PO₄)_5.5(SiO₄)_0.5F₂ by the high-energy ball milling method. Characterization techniques such as X-ray diffraction analysis (XRD), Fourier transformed infrared spectroscopy (FTIR), energy dispersive X-ray spectroscopy (EDX) and transmission electron microscopy (TEM) were utilized to investigate the structural properties of the obtained powders. Dissolution behavior was evaluated in simulated body fluid (SBF) and physiological normal saline solution at 37 °C for up to 28 days. The results of XRD and FTIR showed that nanocrystalline single-phase Si–Mg–FA powders were synthesized after 12 h of milling. In addition, incorporation of magnesium and silicon into fluorapatite lattice decreased the crystallite size from 53 nm to 40 nm and increased the lattice strain from 0.220% to 0.296%. Dissolution studies revealed that Si–Mg–FA in comparison to fluorapatite (FA), releases more Ca, P and Mg ions into SBF during immersion. 175 ppm Ca, 33.5 ppm P and 48 ppm Mg were detected in the SBF containing Si–Mg–FA after 7days of immersion, while for FA, it was 75 ppm Ca, 21.5 ppm P and 29 ppm Mg. Release of these ions could improve the bioactivity of the obtained nanopowder. It could be concluded that the prepared nanopowders have structural properties such as crystallite size (~40 nm), crystallinity degree (~40%) and chemical composition similar to biological apatite. Therefore, prepared Si–Mg–FA nanopowders are expected to be appropriate candidates for bone substitution materials and also as a phase in polymer or ceramic-based composites for bone regeneration in tissue engineering applications.