Application of thionine-nafion supported on multi-walled carbon nanotube for preparation of a modified electrode in simultaneous voltammetric detection of dopamine and ascorbic acid

A modified carbon-paste electrode (CPE) is prepared by incorporating thionine-nafion supported on multi-walled carbon nanotube (MWCNT). The electrochemical behavior of dopamine (DA) and ascorbic acid (AA) on the surface of the modified electrode is investigated by cyclic voltammetry (CV). The results show that thionine effectively immobilized in the matrix of the paste by using an appropriate mixture of nafion/MWCNT under the ultrasonic condition. On the other hand, presence of nafion enhances the stability of the thionine supported by MWCNT in the composite electrode and improves the reproducibility of the surface of the modified electrode under renewing process by polishing. The results of cyclic and differential pulse voltammetric investigations show that the modified electrode possesses an efficient electrocatalytic activity for the electrochemical oxidation of DA and AA and a peak potential separation nearly 379 mV is resulted for two compounds. The prepared modified electrode does not show any considerable response toward the electro-oxidation of sulfhydryl compounds, such as, cysteine, penicillamine and glutathione, revealing a good selectivity for voltammetric response to AA and DA in clinical and pharmaceutical preparations. The effective electrocatalytic property, excellent peak resolution and ability for masking the voltammetric responses of the other biologically reducing agents, make the modified electrode suitable for simultaneous and sensitive voltammetric detection of sub-micromolar amounts of AA and DA.     

Voltammetric studies of a cobalt(II)-4-methylsalophen modified carbon-paste electrode and its application for the simultaneous determination of cysteine and ascorbic acid

A carbon-paste electrode (CPE) chemically modified with the cobalt(II)-4-methylsalophen (CoMSal) as a Schiff base complex was used as a highly sensitive and fairly selective electrochemical sensor for simultaneous determination of minor mounts of ascorbic acid (AA) and cysteine. This modified electrode shows very efficient electrocatalytic activity for anodic oxidation of both AA and cysteine via substantially decreasing of anodic overpotentials for both compounds. The mechanism of electrochemical oxidation of both AA and cysteine using CoMSal-modified electrode was thoroughly investigated by cyclic voltammetry and polarization studies. Results of cyclic voltammetry (CV) and differential pulse voltammetry (DPV) using this modified electrode show two well-resolved anodic waves for the oxidation of AA and cysteine, which makes it possible for simultaneous determination of both compounds. A linear range of 1 × 10⁻⁴ to 5 × 10⁻⁷ M for cysteine in a constant concentration of 1 × 10⁻⁴ M AA in buffered solution (as a background electrolyte) was obtained from DPV measurements using this electrode. The linear range, which is obtained for AA in the presence of 1 × 10⁻⁴ M cysteine, was in the range of 1 × 10⁻⁴ to 1 × 10⁻⁶ M. The modified electrode has good reproducibility (RSD ≤ 2.5%), low detection limit (sub-micromolar) and high sensitivity for the detection of both AA and cysteine with a very high stability in its voltammetric response. Differential pulse voltammetry using the modified electrode exhibited a reasonable recovery for a relatively wide concentration range of cysteine spiked to a synthetic human serum sample.     

Rheological/thermal properties of poly(ethylene terephthalate) modified by chain extenders of pyromellitic dianhydride and pentaerythritol

Due to low molecular weight and wide molecular weight distribution, polyethylene terephthalate (PET) shows weak melt strength properties. In this study, the synergistic effect of using different types of chain extenders and catalyst on rheological behavior of PET has been investigated. Long-chain branching is known as a suitable method for developing the structure of PET during reactive melt processing. Thus, pyromellitic dianhydride (PMDA) and pentaerythritol (PENTA) were added to the fiber grade PET. The best formulation was determined based on rheological results, which revealed an improvement in both storage modulus and complex viscosity of PMDA-modified samples. Samples containing 1.5% PMDA and 0.5% PENTA exhibited the best rheological properties. Also, dibutyltin dilaurate (DBTDL) acted as an accelerator for chain extension reaction during reactive melt blending. Subsequently, the rheological properties were improved by increasing the chain extending rate. Moreover, thermal properties such as crystallization and melting temperatures and the degree of crystallinity for modified PET were investigated by differential scanning calorimetry.     

Increasing power efficiency in the design of a low power and low phase noise CMOS LC oscillator

This study developed a local oscillator (LO) with low phase noise and low power consumption. The proposed oscillator core comprises a pair of cross‐coupled transistors, which are fed by another pair of transistors that injects current at moments close to the peak of output voltage. The position of the current injection transistors, which are inserted in series with the cross‐coupled transistors, affects the waveform of current injected into an inductive–capacitive (LC) tank. Installing a capacitor on the source node of the cross‐coupled transistors increases the current injected into the LC tank and thereby augments the output voltage amplitude and power efficiency of the LO. The resonator phase shift and Q can be corrected by adjusting the source capacitance, which filters noise. These changes reduce the phase noise to ?123.4 dBc/Hz at a frequency offset of 1 MHz and improve oscillator performance with a figure of merit equal to ?193.5 dBc/Hz. To evaluate the LC tank, a 5 GHz LO was simulated at 1.8 V power supply and 2.5 mW power consumption. The simulation was conducted using a practical 0.18 complementary metal–oxide–semiconductor model manufactured by the Taiwan Semiconductor Manufacturing Company. The simulation results confirmed the analytical findings.     

Novel FGbSA: Fuzzy-Galaxy-based search algorithm for multi-objective reconfiguration of distribution systems

Reconfiguration according to different criteria is an important problem in distribution systems. This paper presents a new method for optimal multi-objective reconfiguration of distribution system based on the Galaxy-based Search Algorithm (GbSA). To avoid the convergence problem, the input and output data are normalized in the same range using fuzzy sets. The main objectives of the proposed algorithm have been considered as power loss reduction, voltage profile improvement and increase of the system load balancing. The proposed technique has been investigated using the IEEE 33-bus test system and a real distribution network i.e. Tai-Power 11.4-kV distribution system. The obtained results revealed the superiority of the proposed fuzzy-GbSA method in terms of accuracy compared to the GbSA and other intelligent search algorithms such as Genetic Algorithm (GA) or Particle Swarm Optimization (PSO). Furthermore, the proposed algorithm efficiently converged to the optimum solution compared to the other intelligent counterpart algorithms.     

Computer aided detection and classification of acute lymphoblastic leukemia cell subtypes based on microscopic image analysis

Acute lymphoblastic leukemia (ALL) is a cancer that starts from the early version of white blood cells called lymphocytes in the bone marrow. It can spread to different parts of the body rapidly and if not treated, would probably be deadly within a couple of months. Leukemia cells are categorized into three types of L1, L2, and L3. The cancer is detected through screening of blood and bone marrow smears by pathologists. But manual examination of blood samples is a time‐consuming and boring procedure as well as limited by human error risks. So to overcome these limitations a computer‐aided detection system, capable of discriminating cancer from noncancer cases and identifying the cancerous cell subtypes, seems to be necessary. In this article an automatic detection method is proposed; first cell nucleus is segmented by fuzzy c‐means clustering algorithm. Then a rich set of features including geometric, first‐ and second‐order statistical features are obtained from the nucleus. A principal component analysis is used to reduce feature matrix dimensionality. Finally, an ensemble of SVM classifiers with different kernels and parameters is applied to classify cells into four groups, that is noncancerous, L1, L2, and L3. Results show that the proposed method can be used as an assistive diagnostic tool in laboratories.     

Investigation of cure advancement in dual-cure polyurethane-acrylate coatings over metal substrates

In the present study, a polyurethane acrylate (PUA) system cured via a thermal–UV (dual-cure process) was developed. The system selected for this work was a two-pack polyurethane acrylate with polyester polyol as the main component and urethane monoacrylate (UMA) as hardener. The polyester polyol was synthesized in a way to provide a final film coating containing both a suitable flexibility and high surface hardness. The thermal and photochemical curing behavior of the resin was studied via the chemorheology technique and the real-time FTIR. The Boltzmann sigmoidal model was implemented and well-fitted to the data obtained from the chemorheology measurements. The comparison between two reactive diluents, butanediol diacrylate (BDDA) and trimethylolpropane triacrylate (TMPTA) showed that BDDA reacts faster than TMPTA in the thermal curing condition. Nevertheless, the network buildup is stronger when TMPTA is used. The photopolymerization is also faster for the case of TMPTA. However, its final double bond conversion is restricted to a lower amount due to steric hindrance and higher viscosity of the system.     

The effect of agarose content on the morphology,phase evolution,and magnetic properties of CoFe2O4 nanoparticles prepared by sol‐gel autocombustion method

Hard‐magnetic CoFe₂O₄ nanoparticles were produced with the sol‐gel autocombustion route using agarose and citric acid as a neutral organic gel and combustion agent. For this purpose, the obtained gel is annealed at 800°C for 3 hours and then the spinel structure of the samples was confirmed by X‐ray diffraction (XRD). In addition, the existence of metal‐oxygen complexes in the gel and nanoparticles was investigated by Fourier transformation infrared (FTIR) spectra. Furthermore, FESEM images showed that semispherical and rod‐like particles were obtained by variation in agarose contents. For the rod‐like sample with 2.5 g agarose, the saturation magnetization and coercivity were measured equal to 71.7 emu/g and 10076.84 Oe, respectively.     

Mechanistic investigation of nonisothermal suspension polymerization of vinyl chloride

Vinyl chloride suspension polymerization using different temperature trajectories was carried out in a pilot scale batch reactor. Detailed understanding of the conversion at which the primary particles become motionless (X_m) and the key effects of X_m on morphology development of PVC grains were provided. Motionless conversion is estimated for poly(vinyl chloride) (PVC) grains prepared with different temperature trajectories by cold plasticizer absorption measurements. The porosity of PVC grains (prepared isothermally and nonisothermally) shows a maximum at a certain conversion that is considered motionless conversion. With increasing monomer conversion, the cold plasticizer uptake decreases dramatically with conversions greater than motionless conversion until the monomer phase is completely exhausted (X_f) and continues to slightly decrease after X_f. The decrease in cold plasticizer absorption is more pronounced for PVC grains produced nonisothermally by lower initial temperature. The results obtained by scanning electron microscopy and Brabender^® plastography showed that the changes in internal structure and fusion behavior of PVC grains after X_m would be much lower when early aggregates of primary particles are formed. Scanning electron microscopy photographs indicate that applying the variable temperature with negative slope accelerates networking between the primary particles inside the polymerizing monomer droplets. The Brabender^® plastograph measurements indicate a lower time and temperature of fusion and a higher degree of gelation for nonisothermally produced resin in which the temperature trajectory follows a greater negative slope. J. VINYL ADDIT. TECHNOL., 24:84–92, 2018. © 2015 Society of Plastics Engineers     

Cost-effective multi-pulse AC-DC converter with lower than 3% current THD

In this paper, a new multi-pulse clean power converter topology is presented with lower than 3% input current total harmonic distortion (THD). The topology is based on the combination of a 36-pulse converter and a pulse doubling circuit. The 36-pulse converter consists of a “polygon” autotransformer and two 18-pulse diode bridge rectifiers. Pulse doubling circuit consists of zero-sequence-blocking transformer (ZSBT) and tapped interphase transformer (IPT). The important advantage of the proposed AC-DC converter is considerable reduction in burdens of the magnetic parts with respect to the nominal load rating. It provides more economical solution to achieve harmonic mitigation in electric power systems as compared with other 72-pulse AC-DC converters. The simulation and experimental results show that the input current THD is less than 3% using the proposed topology. The results indicate a significant reduction in the total cost and volume of the proposed 72-pulse configuration in comparison with similar configurations. Also, it is shown that the proposed converter rating is about 44% of the DC load power.