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121.
Selvakannan PR Mandal S Pasricha R Sastry M 《Journal of nanoscience and nanotechnology》2003,3(5):372-374
Protocols for the synthesis of gold nanoparticles are increasingly focusing on controlling the morphology of the nanocrystals. We demonstrate in this article the facile, one-step synthesis of gold nanotapes that are readily dispersible in organic media. This is accomplished by the spontaneous reduction of aqueous chloroaurate ions by hexadecylaniline molecules present in chloroform at the static interface between water and chloroform. The hexadecylaniline molecules cap the gold nanotapes thus formed, rendering them hydrophobic and dispersible in a range on nonpolar and weakly polar organic solvents. Possible reasons for the growth of gold nanotapes are discussed. 相似文献
122.
123.
NMR Quantum Information Processing 总被引:1,自引:0,他引:1
124.
Kim H.H. Chandrasekhar S. Burrus C.A. Jr. Bauman J. 《Solid-State Circuits, IEEE Journal of》2001,36(5):769-776
A transimpedance amplifier packaged with an InP p-i-n photodiode has been demonstrated for 10-Gb/s SONET receiver. The shunt feedback transimpedance amplifier is fabricated in 0.25-μm modular Si BiCMOS technology. The transimpedance of 55 dBΩ is achieved at a bandwidth of 9 GHz by applying shunt peaking and filter termination at the input. The optical sensitivity of -17 dBm was measured at 10 Gb/s for a bit-error rate of 10-12 相似文献
125.
126.
Pathological Gait Detection Based on Multiple Regression Models Using Unobtrusive Sensing Technology
Chakraborty Saikat Jain Shaili Nandy Anup Venture Gentiane 《Journal of Signal Processing Systems》2021,93(1):1-10
Journal of Signal Processing Systems - Analysis of human gait to detect walking abnormality has recently gained growing interest. It carries profound impact in medical diagnosis and rehabilitation... 相似文献
127.
The accurate experimental determination of pharmaceutical compound solubilities at various temperature and pressure ranges in supercritical carbon dioxide (ScCO2) is a challenging and time‐consuming task. Therefore, prediction or correlations of solute solubilities are essential for implementation of ScCO2 technologies to pharmaceutical industries. Solubilities of 41 pharmaceutical compounds in ScCO2 are correlated by an empirical model, which is developed based on the degree of freedom analysis. Its correlating ability is compared with existing solubility models elaborated by other authors and evaluated in terms of global mean absolute relative deviation, sum of squares due to error, root mean square deviation, R2, and Adj. R2. The proposed model is found to correlate better than existing models. 相似文献
128.
Sikander Rafiq Zakaria Man Saikat Maitra Abdulhalim Maulud Farooq Ahmad Nawshad Muhammad 《Korean Journal of Chemical Engineering》2011,28(10):2050-2056
Asymmetric Flat sheet polysulfone-polyimide (PSF-PI) blended polymeric membranes (with PI content from 5–20%) have been fabricated
following phase inversion technique. The membranes have been thoroughly characterized by the measurement of porosity, mechanical
properties and also by SEM, FTIR and DSC analyses. With the increase in the PI content, the mechanical properties of the membranes,
like Young’s modulus, tensile strength and elongation at break, increased. SEM investigations revealed that the surfaces of
fabricated blended membranes possessed adequate homogeneity and their cross-sections showed non-porous top and diminutive
porous substructure. From DSC analyses it has been observed that different compositions of the blended membranes exhibited
single glass transition temperatures, implying proper compatibility of the polymers. The permeance of CO2 and CH4 through the membrane increased with the increase in PI content and it gradually decreased with the increase in the feed pressure
in the range of 2–10 bar. Under the present investigation, the membrane with 20% PI content exhibited the maximum selectivity
for the separation of CO2/CH4 gas mixes. 相似文献
129.
K. Paramesh N. Lakshmana Reddy M.V. Shankar T. Chandrasekhar 《International Journal of Hydrogen Energy》2018,43(8):3957-3966
It is estimated that the fossil fuel reserves are going to deplete continuously due to extensive usage. In order to cope with this crisis, it is necessary to increase the efforts towards production of biofuels such as biological hydrogen (H2). It is well-known fact that the biological hydrogen is a clean and ideal energy and liberates high amount of energy per unit mass. Several groups are working for the large scale production of H2 chemically and also using photosynthetic organisms, but output is not satisfactory. The best way to achieve enhancement of H2 is through altering the photosynthetic process by applying various stress conditions or by natural selection. In the process of selection, Chlorococcum minutum was found with improved H2 output when compared to model green alga Chlamydomonas reinhardtii in a massively parallel and competitive high-throughput screen of different green algae. Both the species belongs to class chlorophyceae of green algae and live in fresh water conditions. In extent various light, pH and temperature conditions were applied and achieved the enhancement of H2 production in this species under in vitro settings. Augmented hydrogenase activity was found in Chlorococcum minutum when compared to model alga and this may be one of the reason behind improved H2 output. Hence this species may be considered as one of the best species with respect to H2 production and also this work may be useful for future renewable energy research. 相似文献
130.
Dr. Rhushikesh A. Kulkarni Chloe A. Briney Dr. Daniel R. Crooks Sarah E. Bergholtz Dr. Chandrasekhar Mushti Dr. Stephen J. Lockett Dr. Andrew N. Lane Dr. Teresa W.-M. Fan Dr. Rolf E. Swenson Dr. W. Marston Linehan Dr. Jordan L. Meier 《Chembiochem : a European journal of chemical biology》2019,20(3):360-365
Dysregulated metabolism can fuel cancer by altering the production of bioenergetic building blocks and directly stimulating oncogenic gene-expression programs. However, relatively few optical methods for the direct study of metabolites in cells exist. To address this need and facilitate new approaches to cancer treatment and diagnosis, herein we report an optimized chemical approach to detect the oncometabolite fumarate. Our strategy employs diaryl tetrazoles as cell-permeable photoinducible precursors to nitrileimines. Uncaging these species in cells and cell extracts enables them to undergo 1,3-dipolar cycloadditions with endogenous dipolarophile metabolites such as fumarate to form pyrazoline cycloadducts that can be readily detected by their intrinsic fluorescence. The ability to photolytically uncage diaryl tetrazoles provides greatly improved sensitivity relative to previous methods, and enables the facile detection of dysregulated fumarate metabolism through biochemical activity assays, intracellular imaging, and flow cytometry. Our studies showcase an intersection of bioorthogonal chemistry and metabolite reactivity that can be applied for biological profiling, imaging, and diagnostics. 相似文献