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91.
Muhammad Salman Makshoof Athar Umar Farooq Huma Nazir Anam Noor Saba Nazir 《Korean Journal of Chemical Engineering》2013,30(6):1257-1264
The present study concentrated on the use of an agro-waste biodegradable sorghum biomass in its simple and modified forms for the binding of Cr (III) ions. A relatively new method of modification was adopted using urea under microwave irradiation. FTIR analysis showed the presence of oxygen and nitrogen bearing functional groups in unmodified (UMS) and modified (MS) sorghum biomass. The appearance of new bands and shifts in the peaks confirmed the modification. The influence of different process parameters such as the adsorbent dose, solution pH, contact time, agitation speed and initial metal ion concentration was studied thoroughly to evaluate optimum conditions for adsorption. Maximum adsorption for Cr (III) ions occurred at pH 5.0–6.0 using UMS and MS. Langmuir, Freundlich, Temkin, and Dubinin-Radushkevich isotherm models in a non-linear fashion were used to explain the phenomenon. Maximum adsorption capacity was 7.03 and 16.36 mg of Cr (III) per gram of UMS and MS, respectively. Adsorption mechanism was explored by pseudo-first- and pseudo-second-order kinetic models, and it was found that the process followed pseudo-second-order kinetics. Thermodynamic study indicated the process favorability. The study concluded that urea modification under microwave irradiation produces a non-toxic and more effective adsorbent for Cr (III) remediation by inducing new nitrogen bearing functional groups to sorghum biomass. 相似文献
92.
93.
Salman R. Salman 《Polymer-Plastics Technology and Engineering》2013,52(1-2):115-122
Photooxidative aging of high-impact polystyrene sheets at 25°C was followed for different intervals of 25, 40, 50, 75, and 80 h. Five different types of samples were used, viz. virgin, and recycled once, twice, three, and four times. The optical properties of exposed samples exhibited changes as a result of discoloration. The transmittance and reflection deceases whereas absorbance increases with increasing recycling of high-impact polystyrene. 相似文献
94.
The crystallization behaviour of lithia calcia silicate system containing MgO, SrO, and Al2O3 has been investigated using DTA, XRD and SEM. The coefficient of thermal expansion and Vicker's microhardness of the obtained products were also evaluated. The main crystalline phases formed after different heat-treatments were lithium metasilicate, wollastonite, diopside, β-spodumene ss, pseudo-wollastonite, Sr2SiO4, Sr2Mg(Si2O7) and μ-(Ca,Sr)SiO3. The wollastonite structure can accept considerable amount of strontium to form wollastonite strontium solid solution, while there is no solid solution of strontium in pseudo-wollastonite. 相似文献
95.
Synthesis and characterization of novel curcumin based polyurethanes varying diisocyanates structure
Kashif Mahmood Iqra Noreen Muhammad Riaz Mohammad Zuber Mahwish Salman Saima Rehman Khalid Mahmood Zia 《Journal of Polymer Research》2016,23(11):233
In this research work, novel polyurethanes (PUs) based on blends of curcumin/1,4-butane diol (BDO) by varying the structure of diisocyanates were prepared following step growth polymerization. Structural study of blends and various diisocyanates based PU through Fourier Transform Infrared (FTIR) spectroscopy confirmed the incorporation of curcumin into the backbone of the PU. The scanning electron microscopic (SEM) study confirmed the well dispersion of incorporated curcumin and homogeneity of surface of synthesized samples. The SEM results also indicated that surface morphology of synthesized samples much dependent on diisocynates structure. Moreover SEM images inferred that phase separation is more pronounced in aromatic diisocyanate based PU. The anti-bacterial and anti-fungal tests were performed against different strains in order to determine the biocompatibility of the curcumin based PU. The antimicrobial activity results revealed that the material having aromatic diisocyanate are more biocompatible than the aliphatic diisocyanates in the PU structure. On the whole, this work is actually a step towards the generation of novel biocompatible materials preferably useful for biomedical applications. 相似文献
96.
Deepak Rajawat Salman Siddique Sandeep Shrivastava Sandeep Chaudhary Trilok Gupta 《火与材料》2018,42(7):834-842
The residual properties of concrete subjected to elevated temperature are of importance to assess the stability of the structure. This paper investigates the performance of concrete containing white ware ceramic sand exposed to elevated temperature. Concrete mixes containing 0%, 50%, and 100% ceramic sand were prepared. The specimen were exposed to elevated temperatures of 200°C, 500°C, and 800°C for a duration of 60 minutes. Their residual mechanical properties (compressive strength, split tensile strength), ultra sonic pulse velocity, and mass change for different cooling regimes were investigated and compared among specimen. The results showed that incorporation of ceramic sand in concrete mixes improved the resistance against elevated temperature of hardened concrete. 相似文献
97.
A tabu search algorithm for order acceptance and scheduling 总被引:1,自引:0,他引:1
We consider a make-to-order production system, where limited production capacity and order delivery requirements necessitate selective acceptance of the orders. Since tardiness penalties cause loss of revenue, scheduling and order acceptance decisions must be taken jointly to maximize total revenue. We present a tabu search algorithm that solves the order acceptance and scheduling problem on a single machine with release dates and sequence dependent setup times. We analyze the performance of the tabu search algorithm on an extensive set of test instances with up to 100 orders and compare it with two heuristics from the literature. In the comparison, we report optimality gaps which are calculated with respect to bounds generated from a mixed integer programming formulation. The results show that the tabu search algorithm gives near optimal solutions that are significantly better compared to the solutions given by the two heuristics. Furthermore, the run time of the tabu search algorithm is very small, even for 100 orders. The success of the proposed heuristic largely depends on its capability to incorporate in its search acceptance and scheduling decisions simultaneously. 相似文献
98.
Salman Khan Mukhtaj Khan Nadeem Iqbal Mohd Amiruddin Abd Rahman Muhammad Khalis Abdul Karim 《计算机、材料和连续体(英文)》2022,72(2):2243-2258
Piwi-interacting Ribonucleic acids (piRNAs) molecule is a well-known subclass of small non-coding RNA molecules that are mainly responsible for maintaining genome integrity, regulating gene expression, and germline stem cell maintenance by suppressing transposon elements. The piRNAs molecule can be used for the diagnosis of multiple tumor types and drug development. Due to the vital roles of the piRNA in computational biology, the identification of piRNAs has become an important area of research in computational biology. This paper proposes a two-layer predictor to improve the prediction of piRNAs and their function using deep learning methods. The proposed model applies various feature extraction methods to consider both structure information and physicochemical properties of the biological sequences during the feature extraction process. The outcome of the proposed model is extensively evaluated using the k-fold cross-validation method. The evaluation result shows that the proposed predictor performed better than the existing models with accuracy improvement of 7.59% and 2.81% at layer I and layer II respectively. It is anticipated that the proposed model could be a beneficial tool for cancer diagnosis and precision medicine. 相似文献
99.
Imran Khan Salman Khan Shiuan-Yau Wu Hsin-Tsung Chen Amir Zada Liu Linlin Ahmed Ismail Sharafat Ali Fazal Raziq Mustafa Haider Javid Khan Sami Ullah Shin-pon Ju Shiliang Wang 《Small (Weinheim an der Bergstrasse, Germany)》2023,19(25):2208179
The realization of solar-light-driven CO2 reduction reactions (CO2 RR) is essential for the commercial development of renewable energy modules and the reduction of global CO2 emissions. Combining experimental measurements and theoretical calculations, to introduce boron dopants and nitrogen defects in graphitic carbon nitride (g-C3N4), sodium borohydride is simply calcined with the mixture of g-C3N4 (CN), followed by the introduction of ultrathin Co phthalocyanine through phosphate groups. By strengthening H-bonding interactions, the resultant CoPc/P-BNDCN nanocomposite showed excellent photocatalytic CO2 reduction activity, releasing 197.76 and 130.32 µmol h−1 g−1 CO and CH4, respectively, and conveying an unprecedented 10-26-time improvement under visible-light irradiation. The substantial tuning is performed towards the conduction and valance band locations by B-dopants and N-defects to modulate the band structure for significantly accelerated CO2 RR. Through the use of ultrathin metal phthalocyanine assemblies that have a lot of single-atom sites, this work demonstrates a sustainable approach for achieving effective photocatalytic CO2 activation. More importantly, the excellent photoactivity is attributed to the fast charge separation via Z-scheme transfer mechanism formed by the universally facile strategy of dimension-matched ultrathin (≈4 nm) metal phthalocyanine-assisted nanocomposites. 相似文献
100.
Influence of religiosity and spiritual coping on health‐related quality of life in Saudi haemodialysis patients 下载免费PDF全文