Recent advances in nanotechnology, chemical/physical texturing and thin film coating technology generate definite possibilities for sustaining a dropwise mode of condensation for much longer durations than was previously possible. The availability of superior experimental techniques also leads to deeper understanding of the process parameters controlling the relevant transport phenomena, the distinguishing feature of which is the involvement of a hierarchy of length/time scales, proceeding from nuclei formation, to clusters, all the way to macroscopic droplet ensemble, drop coalescence, and subsequent dynamics. This paper is an attempt to connect and present a holistic framework of modeling and studying dropwise condensation at these multiple scales. After a review of the literature, discussions on the following problems are presented: (i) atomistic modeling of nucleation; (ii) droplet–substrate interaction; (iii) surface preparation; (iv) simulation of fluid motion inside sliding drops; (v) experimental determination of the local/ average heat transfer coefficient; and (vi) a macroscopic model of the complete dropwise condensation process underneath horizontal and inclined surfaces. The study indicates that hierarchal modeling is indeed the way forward to capture the complete process dynamics. The microscopic phenomena at the three-phase contact line, leading to the apparent droplet contact angle, influence the shear stress and heat transfer. The nucleation theory captures the quasi-steady-state behavior quite satisfactorily, although the early atomistic nucleation was not seen to have a profound bearing on the steady-state behavior. The latter is strongly governed by the coalescence dynamics. Visual observation of dropwise condensation provides important information for building hierarchical models. 相似文献
Collagen is heavily hydroxylated. Experiments show that proline hydroxylation is important to triple helix (monomer) stability, fibril assembly, and interaction of fibrils with other molecules. Nevertheless, experiments also show that even without hydroxylation, type I collagen does assemble into its native D-banded fibrillar structure. This raises two questions. Firstly, even though hydroxylation removal marginally affects macroscopic structure, how does such an extensive chemical change, which is expected to substantially reduce hydrogen bonding capacity, affect local structure? Secondly, how does such a chemical perturbation, which is expected to substantially decrease electrostatic attraction between monomers, affect collagen’s mechanical properties? To address these issues, we conduct a benchmarked molecular dynamics study of rat type I fibrils in the presence and absence of hydroxylation. Our simulations reproduce the experimental observation that hydroxylation removal has a minimal effect on collagen’s D-band length. We also find that the gap-overlap ratio, monomer width and monomer length are minimally affected. Surprisingly, we find that de-hydroxylation also has a minor effect on the fibril’s Young’s modulus, and elastic stress build up is also accompanied by tightening of triple-helix windings. In terms of local structure, de-hydroxylation does result in a substantial drop (23%) in inter-monomer hydrogen bonding. However, at the same time, the local structures and inter-monomer hydrogen bonding networks of non-hydroxylated amino acids are also affected. It seems that it is this intrinsic plasticity in inter-monomer interactions that preclude fibrils from undergoing any large changes in macroscopic properties. Nevertheless, changes in local structure can be expected to directly impact collagen’s interaction with extra-cellular matrix proteins. In general, this study highlights a key challenge in tissue engineering and medicine related to mapping collagen chemistry to macroscopic properties but suggests a path forward to address it using molecular dynamics simulations. 相似文献
Ordered mesoporous Fe2O3 was synthesized using cetyltrimethylammonium chloride (CTAC) and polyethylene glycol octadecyl ether (Brij 76) surfactant templates. The gel time was monitored as a function of the concentration ratio of precursor to the surfactant. As-prepared FeOOH gels were extracted in ethanol to remove the surfactant and calcined at 200–400°C for 6 h so that α-Fe2O3 is produced. The FTIR spectra of these gels reveal complete removal of surfactant and water impurities and the presence of Fe-O vibrations. TEM images show ordering of mesopores in the gels prepared using surfactant templating and no ordering of the pores in the gels prepared without surfactant. The gels after calcinations were mixed with aluminum nanoparticles to prepare nanoenergetic composites. The burn rate of the nanocomposites containing ordered mesoporous Fe2O3 mixed with Al nanoparticles was compared with the one containing Fe2O3 with no ordering of mesopores and Al nanoparticles. 相似文献
A novel method for the residue analysis of wine spoilage compound 2,4,6-trichloroanisole is reported. Wine (60 ml) was extracted with 2 ml toluene in presence of 24 g MgSO4 and 6 g NaCl. Cleanup of the toluene phase by dispersive solid phase extraction with mixture of 100 mg CaCl2, 25 mg primary secondary amine and 50 mg MgSO4 was effective in minimising co-extractives and matrix effects. Time-of-flight and tandem mass spectrometric parameters were optimised to achieve linearity over 0.25–500 ng ml−1 and method detection limit 0.0083 ng ml−1 which is well below the odour threshold of 0.04 ng ml−1. Recoveries at 0.04, 0.2 and 0.8 ng ml−1 were within 80–110% (±8%). The method was reproducible when tested for Argentinean wines with intra-laboratory Horwitz ratios being <0.20 in white and red wines at both the laboratories of India and Argentina. The method could be successfully applied for incurred wine samples. 相似文献
Intra-WBSN are generally short range wireless health monitoring networks, consisting of strategically placed miniaturized, intelligent and low powered bio-sensors. They perform various applications in healthcare, fitness, military, sport and consumer electronics. The network stability and the network longevity of such networks have prime focus in current research. Routing schemes have a significant potential to make such network energy efficient by sending the sensing data properly and promptly. In this paper, we have proposed a relay based cooperative routing scheme to achieve high energy efficiency. Sensing data from the bio-sensor node have been delivered on the basis data priority. The sensing data with high priority has been directly transmitted to body network controller (BNC). The delivery of normal sensing data from bio-sensor to the BNC through relay nod or cooperative node. These nodes are deployed in clothes, they can be easily replaced or recharged, it provide effective, easy and comfortable health monitoring. Through simulation results, the proposed routing protocol achieved improved performance in terms of energy efficiency, network stability, network lifetime, path-loss and throughput in comparison to the existing routing schemes.
This paper presents the design of a two-stage pseudo-differential operational transconductance amplifier (OTA) and its application
in low-frequency continuous time filters. The OTA was designed in a 0.18 μm, 0.45 V VT CMOS process. An improved bulk-mode common-mode feedback (CMFB) circuit has been designed which does not load the OTA compared
to prior art. A self cascode load structure and partial positive feedback provide higher gain. The bulk terminals of all transistors
have been biased to lower their threshold voltages (VT) and maximize signal swing. The OTA operates at a supply voltage of 0.5 V and consumes only 28 μW of power. Rail-to-rail
input is made possible by using the transistor’s bulk terminal as the input. For a load of 20 pF the OTA has a measured DC
gain of 63 dB and a gain-bandwidth product of 570 kHz. To demonstrate the use of the OTA in practical circuits, three active
RC filters were designed: a 10 kHz Butterworth filter, a 10 kHz Bessel filter, and a 2.5 kHz Tschebycheff filter. 相似文献