Photocatalytic degradation of 4-nitroaniline using solar and artificial UV radiation

The photocatalytic degradation (PCD) of 4-nitroaniline was studied in the presence of TiO₂ suspensions in a batch and continuous annular reactor. Artificial and solar radiation was employed as sources of UV radiation. The effect of catalyst loading, pH, presence of anions and initial concentration on the rate of photocatalytic degradation was investigated. p-Aminophenol, p-benzoquinone and hydroquinone were identified as the intermediates during the degradation process. A kinetic expression for PCD of 4-NA is provided.     

An Experimental Study on the Additional Settlement of Footings Resting on Granular Soils by Water Table Rise

When the water table rises in a granular soil mass, a large additional settlement of footing resting on such a soil mass is commonly expected. Laboratory model tests show that when the water table rises to the footing level, there can be an additional 400 to 500% of the settlements compared to when the soil is dry. To understand the mechanics of the additional settlements of footings resting on the granular soil masses caused by water table rise, an investigation into the change in the Young's modulus of soil was therefore made using oedometer tests. A relation between the saturated and the dry Young's moduli of the granular soils is presented for use in the elastic analysis of footing settlements. The findings of the investigation were then used to predict the additional settlements of a model footing when subjected to a water table rise, using elastic analysis. The theoretical predictions of the additional settlements are lower than the actual additional settlements observed in the settlement tests conducted in the laboratory using model tests. The model tests show that the additional settlements are larger in loose sands than in dense sands.     

Integrated Study of APS YSZ Coatings with Different Spray Angle

Spray parameters play an important role on the microstructure and properties of plasma-sprayed coatings. Parameters such as spray distance, plasma gas flow and current, raster speed, and spray angle all can be varied. In this paper, an integrated study to investigate the effects and influences of spray angle on properties of yttria-stabilized zirconia coatings was carried out with spray angles of 60°, 75°, and 90° (to the substrate surface). In situ coating property sensor based on beam curvature measurements was used to measure the evolving stress and elastic moduli of the resultant coatings and combined with other characterization tools for thermo-physical property and microstructure analysis, such as laser flash and scanning electron microscopy. The results indicate that the coating with 60° spray angle had the lowest thermal conductivity and more compliant structure. This study seeks to understand the mechanism for this effect and will provide important insight into parametric sensitivities on complex spray parts.     

Platelet-Released Factors: Their Role in Viral Disease and Applications for Extracellular Vesicle (EV) Therapy

Platelets, which are small anuclear cell fragments, play important roles in thrombosis and hemostasis, but also actively release factors that can both suppress and induce viral infections. Platelet-released factors include sCD40L, microvesicles (MVs), and alpha granules that have the capacity to exert either pro-inflammatory or anti-inflammatory effects depending on the virus. These factors are prime targets for use in extracellular vesicle (EV)-based therapy due to their ability to reduce viral infections and exert anti-inflammatory effects. While there are some studies regarding platelet microvesicle-based (PMV-based) therapy, there is still much to learn about PMVs before such therapy can be used. This review provides the background necessary to understand the roles of platelet-released factors, how these factors might be useful in PMV-based therapy, and a critical discussion of current knowledge of platelets and their role in viral diseases.     

Computational study of 5<Emphasis Type="Italic">d</Emphasis> transition metal mononitrides and monoborides using density functional method

5d-metal mononitrides and monoborides viz. X-N and X-B (X = La, Hf, Ta, W, Re, Os, Ir, Pt, Au, Hg) are studied using density functional method based B3LYP functional with LANL2DZ and SDD basis set. The lowest spin state, electron affinities, ionization potentials and binding energies for mononitrides and monoborides are obtained. The electronic state and electronic configuration of mononitrides and monoborides are discussed. Orbitals involved in bond formation are identified. The properties of mononitrides and monoborides are compared. It is found that 5d-metal atoms form stronger bond with nitrogen atom than the boron atom. The range of binding energy, electron affinity and ionization potential is wider for mononitrides than that for monoborides. The properties of 5d-metal mononitrides and 3d-metal mononitrides are also compared. The binding energies for the former are lower than those for the latter.     

Measurement and Stochastic Computational Modeling of the Elastic Properties of Parallel Strand Lumber

This paper describes a model for the spatial variation of the elastic modulus of parallel strand lumber (PSL) that is based on bending experiments and also describes a validated stochastic computational model that incorporates orthotropic elasticity and uncertainty in strand geometry and material properties. The PSL exhibits significant variability both within members and between members, but this variability is less than that of equivalent sawn-wood members, and decreases with increasing member size. The correlation length of the elastic modulus is found to be several meters and is independent of the cross-sectional size. The variance of PSL elastic modulus is found to scale inversely with the number of strands in the cross section. The validated computational model is flexible enough to allow preliminary exploration of the properties of new mixes of species and strand sizes in PSL material design.     

Electrohydrodynamic atomization (EHDA) of high-conductivity pure solvent

ABSTRACT

In this study, the effects of flow rate, liquid conductivity and neutralizer strength on the operating and output characteristics are examined for an Electrohydrodynamic atomization (EHDA)-based aerosol generator system, designed and built in our laboratory. Ethylene glycol is used for generating the droplets. It is seen that stable cone-jet mode could be obtained for solvent conductivity as high as 240 μS/cm. While the output number concentration was found to increase with both flow rate and conductivity, the mean particle diameters decreased with increasing conductivity and increased with flow rate. The mean droplet size and output number concentration are found to be about three times more sensitive to changes in conductivity as compared to that of flow rate in the range of 26–150 μS/cm. It is also observed that throughput from the system is strongly dependent on the strength of the charge neutralizer. In the present setup, 8 μCi ²⁴¹Am bipolar neutralizer in axisymmetric configuration was found to be sufficient to neutralize the generated droplets.     

Data Replication in Cooperative Mobile Ad-Hoc Networks

The mobile computing environment provides many benefits such as ubiquitous access to computing but includes constraints on resources such as available bandwidth and battery life. Replication is a widely recognized method for balancing the demands of storage space with bandwidth and battery life. We propose a novel scheme that seeks to strategically balance these constrained resources through a cooperative game-theory approach for replication in a mobile environment. Our replication strategy relies on the cooperation of the nodes within the network to make replica caching decisions which are spatiotemporally local-optimal for the network from an energy and bandwidth conservation standpoint. In cooperative altruistic data replication, each node calculates the net global benefit, for caching a replica of the requested data, as the result data is returned from the responding node to the requesting node, where it determines the spatiotemporally local-optimal node for replicating the data item. Performance results from our research indicate that our scheme, CADR, improves the query response time by 25 and 45 %, mean hop count is improved by 26 and 46 %, query error is reduced by 30 and 48 %, while energy utilization is reduced 30 and 57 % when compared with both another game theoretic replication approach and standard cooperative caching respectively.     

Multiple sourcing decisions using integrated AHP and knapsack model: a case on carton sourcing

Purchase allocation is a multi criteria decision making (MCDM) problem. Multitude of qualitative and quantitative factors is involved in the multiple sourcing decisions. Analytic hierarchy process (AHP) has widely been used to find out the relative rankings of suppliers. AHP can be combined with regular supplier quantitative audit process. In classical AHP, decision maker (DM) has to pair wise compare suppliers for each factor, whereas the proposed audit based simplified AHP will remove the complexity of comparison. Quarterly audit-based AHP rankings and supplier performance probability products can be used in place of revenues in the backward recursive resource allocation knapsack model. This combined model will decompose purchase allocation problem into different stages and combine one supplier at each stage and provide the optimum and feasible solution in the end. Solution at each stage is also a feasible option. This model is only applicable when the total order quantity and the capacity of all suppliers are integer multiples of economic or minimum order quantity. This integrated model thus provides number of orders/supplier.     

Field Assessment of the Performance of a Ballasted Rail Track with and without Geosynthetics

Understanding the complex mechanisms of stress transfer and strain accumulation in layers of track substructure under repeated wheel loading is essential to predict the desirable track maintenance cycle as well as the design of the new track. Various finite element and analytical techniques have been developed in the past to understand the behavior of composite track layers subjected to repeated wheel loads. The mechanical behavior of ballast is influenced by several factors, including the track confining pressure, type of aggregates, and the number of loading cycles. A field trial was conducted on an instrumented track at Bulli, New South Wales, Australia, with the specific aims of studying the benefits of a geocomposite installed at the ballast-capping interface, and to evaluate the performance of moderately graded recycled ballast in comparison to traditionally very uniform fresh ballast. It was found that recycled ballast can be effectively reused if reinforced with a geocomposite. It was also found that geocomposite can effectively reduce vertical and lateral strains of the ballast with obvious implications for improved track stability and reduced maintenance costs.