Identification of Pd3+ ions in zeolite L by temperature programmed reduction and electron paramagnetic resonance spectroscopy

Pd supported on KL zeolite has been studied by temperature programmed reduction (TPR) and electron paramagnetic resonance (EPR) spectroscopy. It has been found that upon calcination in pure oxygen Pd³⁺ and Pd²⁺ ions are formed; the Pd³⁺ ions are identified by their EPR signal. As Pd³⁺ ions in the cancrinite cages are difficult to reduce, the H₂ consumption in conventional TPR is below the stoichiometric amount.     

Deformable M-Reps for 3D Medical Image Segmentation

M-reps (formerly called DSLs) are a multiscale medial means for modeling and rendering 3D solid geometry. They are particularly well suited to model anatomic objects and in particular to capture prior geometric information effectively in deformable models segmentation approaches. The representation is based on figural models, which define objects at coarse scale by a hierarchy of figures—each figure generally a slab representing a solid region and its boundary simultaneously. This paper focuses on the use of single figure models to segment objects of relatively simple structure.A single figure is a sheet of medial atoms, which is interpolated from the model formed by a net, i.e., a mesh or chain, of medial atoms (hence the name m-reps), each atom modeling a solid region via not only a position and a width but also a local figural frame giving figural directions and an object angle between opposing, corresponding positions on the boundary implied by the m-rep. The special capability of an m-rep is to provide spatial and orientational correspondence between an object in two different states of deformation. This ability is central to effective measurement of both geometric typicality and geometry to image match, the two terms of the objective function optimized in segmentation by deformable models. The other ability of m-reps central to effective segmentation is their ability to support segmentation at multiple levels of scale, with successively finer precision. Objects modeled by single figures are segmented first by a similarity transform augmented by object elongation, then by adjustment of each medial atom, and finally by displacing a dense sampling of the m-rep implied boundary. While these models and approaches also exist in 2D, we focus on 3D objects.The segmentation of the kidney from CT and the hippocampus from MRI serve as the major examples in this paper. The accuracy of segmentation as compared to manual, slice-by-slice segmentation is reported.     

On Using a Warehouse to Analyze Web Logs

Analyzing Web Logs for usage and access trends can not only provide important information to web site developers and administrators, but also help in creating adaptive web sites. While there are many existing tools that generate fixed reports from web logs, they typically do not allow ad-hoc analysis queries. Moreover, such tools cannot discover hidden patterns of access embedded in the access logs. We describe a relational OLAP (ROLAP) approach for creating a web-log warehouse. This is populated both from web logs, as well as the results of mining web logs. We discuss the design criteria that influenced our choice of dimensions, facts and data granularity. A web based ad-hoc tool for analytic queries on the warehouse was developed. We present some of the performance specific experiments that we performed on our warehouse.     

Scene change detection techniques for video database systems

Scene change detection (SCD) is one of several fundamental problems in the design of a video database management system (VDBMS). It is the first step towards the automatic segmentation, annotation, and indexing of video data. SCD is also used in other aspects of VDBMS, e.g., hierarchical representation and efficient browsing of the video data. In this paper, we provide a taxonomy that classifies existing SCD algorithms into three categories: full-video-image-based, compressed-video-based, and model-based algorithms. The capabilities and limitations of the SCD algorithms are discussed in detail. The paper also proposes a set of criteria for measuring and comparing the performance of various SCD algorithms. We conclude by discussing some important research directions.     

Probabilistic Model for Polycrystalline Microstructures with Application to Intergranular Fracture

A two part probabilistic model for polycrystalline microstructures is described. The model utilizes a Poisson–Voronoi tessellation for the grain geometry and a vector random field model for the crystallographic orientation. The grain geometry model is calibrated to experimental data through the intensity of the Poisson point field underlying the Poisson–Voronoi tessellation and the orientation random field is calibrated to experimental data through its marginal distributions and second moment properties. Realizations of the random microstructure are generated by use of translation methods and are used, with simplified mechanical models, to investigate the problem of intergranular fracture. It is found that intergranular cracks exhibit some statistical properties of a scaled Brownian motion process.     

Sustained release microspheres of diclofenac sodium using PEGylated rosin derivatives

The PEGylated derivatives of rosin-PD-1 and PD-2 synthesized and characterized earlier (Nande et al., 2006) were investigated as potential materials for sustained release microsphere prepared by emulsion solvent evaporation method using diclofenac sodium (DCS) as model drug. All the microspheres exhibited smooth surfaces intercepted by pores; their sizes (d(90)) ranged between 11-24 microm. The entrapment efficiency (< 80%) of the microspheres increased proportionally with derivative concentration. Presence of solvent like isopropyl alcohol or dichloromethane rendered the microspheres with large sizes but with reduced drug entrapment. Microspheres with small size were obtained at an optimum viscosity of liquid paraffin; any change lead to increase in the particle size. Magnesium stearate was found to be most suitable detackifier in the present system. The drug release was directly related to the particle size--small sized microspheres released drug at a faster rate. The dissolution data complied with Higuchi equation while the mechanism of drug release was Fickian diffusion (n approximately 0.5). Controlled inhibition of edema, as tested by hind paw edema method, was observed for 10 h when the microspheres were administered intraperitoneally. The present study found the derivatives as promising materials for preparing microspheres for sustained delivery of DCS.     

Active vibration control of piezolaminated stiffened plates

The aim of this work is to present active vibration control of stiffened plates. A stiffened plate finite element with piezoelectric effects is formulated. The characteristic feature of the stiffener is that it can have any shape in plan and need not pass through the nodal lines of the finite element mesh. The coupling between the direct and the converse piezoelectric effects is neglected for simplicity. A velocity feedback algorithm is employed in the active control. Numerical examples for vibration control of isotropic and orthotropic stiffened plates have been presented.     

A survey of overlay and underlay paradigms in cognitive radio networks

In the recent years, wireless applications and services have grown tremendously, resulting to a shortage of radio spectrum. On one hand, most of the available radio spectrum has already been allocated to different users and service providers. On another hand, research and statistics have revealed that the spectrum utilization usability is very limited. To address this dilemma, the concept of cognitive radio has emerged, which promotes the use of overlay and underlay transmission techniques to boost the utilization of radio spectrum resources. This paper provides a comprehensive survey of these 2 techniques and compares them qualitatively based on several network parameters. Next, this paper simulates overlay and underlay transmission techniques in OMNeT++ simulator on different network parameters, namely, Primary user arrival rate, throughput, sensing duration, and energy consumption. Our findings reveal that neither the overlay nor the underlay technique is sufficient itself to fulfill the demands for future wireless systems, and adopting a hybrid access technique consisting of a joint utilization of overlay and underlay approaches is desirable. Furthermore, the key challenges and open research issues in radio spectrum resources utilization are discussed.