Understanding of attachment efficiency and induction time between bubbles and pyrite particles in flotation

The fundamental flotation models are useful for understanding flotation mechanisms. However, these models cannot be used for design and optimization of flotation circuits because it is very difficult to determine induction times experimentally during flotation despite using advanced high-speed cameras. Thus, there is a need to develop the model that can be used for practical applications, which is the main objective in this work. The developed models were successful in predicted P_a (attachment efficiency) and t_i (induction time) at various chemical conditions. The values of P_a (attachment efficiency) were strongly affected by particle size, collector concentration and pulp pH while the values of t_i (induction time) were affected by particle size and collector concentration and the values of k (flotation rate constant) were affected by collector concentration only. It means that P_a is much more sensitive than t_i and k to detect the changes in the flotation experimental conditions. The slopes of t_i vs P_a functions were larger at different particle sizes than those at different collector concentrations, demonstrating that the effect of particle size was more dominant than the effect of collector concentration on P_a. This paper demonstrated that understanding of P_a is essential for better analysing flotation mechanisms.     

Influence of slip length on filtration performance of fine particles

Fine particle filtration has been known to become progressively inefficient as the filter cake builds up owing to restricted movement of liquid through the small cavities formed in the cake. In different chemical industries, this restricts higher throughput rates and also results in higher transportation costs due to increase in moisture content. This paper discusses the influence of using a surfactant, DAH (dodecylamine hydrochloride), in enhancing the filtration rate of a finely ground particles and the reduction of moisture content in the cake. The observed enhanced filtration rate has been attributed to a reduction in the resistance to liquid flow due to the increase in hydrophobicity at the particle surface. The resulting enhanced filtration rate has been modelled by superimposing a slip velocity at the boundary of the capillaries formed in the cake. The model evaluates the cake and medium resistances by incorporating a slip length into the filtration equation which varies with the concentration of hydrophobic reagent and the effective size of capillaries. The increase in filtration rate is more pronounced for finer particle slurries. Also, it has been observed that the moisture content of the filter cakes formed was reduced.     

In-depth study of mechanical properties of poly(lactic acid)/thermoplastic polyurethane/hydroxyapatite blend nanocomposites

Journal of Materials Science - The present study evaluates the effect of adding different contents of hydroxyapatite (HA) nanoparticles on the mechanical properties of poly(lactic...     

Probabilistic Event Based Rainfall-Runoff Modeling Using Copula Functions

Multivariate probability analysis of hydrological elements using copula functions can significantly improve the modeling of complex phenomena by considering several dependent variables simultaneously. The main objectives of this study were to: (i) develop a stand-alone and event-based rainfall-runoff (RR) model using the common bivariate copula functions (i.e. the BCRR model); (ii) improve the structure of the developed copula-based RR model by using a trivariate version of fully-nested Archimedean copulas (i.e. the FCRR model); and (iii) compare the performance of the developed copula-based RR models in an Iranian watershed. Results showed that both of the developed models had acceptable performance. However, the FCRR model outperformed the BCRR model and provided more reliable estimations, especially for lower joint probabilities. For example, when joint probabilities were increased from 0.5 to 0.8 for the peak discharge (q_p) variable, the reliability criteria value increased from 0.0039 to 0.8000 in the FCRR model, but only from 0.0010 to 0.6400 in the BCRR model. This is likely because the FCRR considers more than one rainfall predictor, while the BCRR considers only one.

     

A decoupled source current reconstruction method for noisy and reactive near‐field to far‐field transformation

In this article, a decoupled source current reconstruction method (SRM) for noisy and reactive near‐field (NF) to far‐field (FF) transformation is introduced. It is shown that the traditional SRM for NF/FF transformation shows instability in the regions that the amounts of noise or reactive radiations are noticeable. Therefore, in these regions, equivalent currents should be determined from a Tikhonov SRM equation. However, this equation increases the computational cost of the SRM. To simplify the Tikhonov SRM equation, a Tikhonov radial field retrieval algorithm is also proposed. In this algorithm, the Tikhonov integral equation is decoupled by considering and retrieving the radial components of the electric field. Results of far‐field calculation with both the proposed Tikhonov SRM equation and Tikhonov radial field retrieval algorithm with three different antennas are presented and compared with those of the full‐wave simulation and measurements. The results show more accurate field transformation with the proposed algorithms.     

Synthesis of copolymers of a linoleic acid derivative and properties of the copolymer films

Addition copolymers of maleic anhydride and a commercially available conjugated fatty acid, Pamolyn 380, were synthesized via thermal initiation. The copolymers had moderately high molecular weights and were obtained in reasonable yields. The copolymers were characterized by nuclear magnetic resonance and infrared spectroscopy and by elemental analysis. Based on this analytical data and examples from the literature, the copolymers were assigned regularly alternating chain morphology. Coatings were formulated with the copolymers, and films over a metal substrate were evaluated. The films were found to have excellent solvent resistance, high hardness, and good gloss. © 2001 John Wiley & Sons, Inc. J Appl Polym Sci 80: 261–267, 2001     

Special all-round fillet weld for anchor rods of base-plate T-stub connections

The eccentricity between connected steel parts and the anchor rods in base-plate T-stub connections makes base plates the weaker components in tension and compression. Additionally, the oversized holes in base plates lead to irregular placement of anchor rods, resulting in an unsymmetrical shear behavior. Thus, this paper aims to develop a special all-round fillet weld to connect the anchor rods beneath the base plate concentrically to the steel part, removing the base plate from the load-transferring chain. Accordingly, design criteria were first developed based on Eurocode's directional method considering all the potential failure modes. Next, results were validated by conducting experimental work. The digital image correlation technique (DIC) was also used to capture the strain distribution developed over the tested specimen till failure. Consequently, numerical analysis was carried out to investigate the fracture strength and the fracture angle and compare the special fillet weld with its equivalent standard one, which has the same weld volume. The results indicated that the proposed design criteria produced safe strength prediction for the developed special all-round fillet weld. Furthermore, the results revealed that using a special all-round fillet weld instead of the equivalent standard one can increase the strength by about 8% and improve the ductility of the weld. However, it decreases the stiffness of the weld by about 21%. The fracture surface occurred at $15°$ from the face of the anchor rod, which produced a higher strength than the predicted tensile strength calculated according to the theoretical throat plane.     

Heat capacity of hexagonal boron nitride sheet in Holstein model

The effects of electron-phonon interaction on the electronic heat capacity of hexagonal boron nitride plane are investigated within the Holstein Hamiltonian model and Green’s function formalism. By using different electron-phonon coupling constants of boron and nitrogen sublattices, it is found that the specific heat has different behaviors in two temperature regions. In the low temperature region, the electronphonon interaction causes the enhancement of specific heat due to decreasing the band gap, while heat capacity reduces in the high temperature region because of decreasing the excitation spectrum.     

Plasma Enhanced Lithium Coupled with Cobalt Fibers Arrays for Advanced Energy Storage

Construction of high efficiency and stable Li metal anodes is extremely vital to the breakthrough of Li metal batteries. In this study, for the first time, groundbreaking in situ plasma interphase engineering is reported to construct high-quality lithium halides-dominated solid electrolyte interphase layer on Li metal to stabilize & protect the anode. Typically, SF₆ plasma-induced sulfured and fluorinated interphase (SFI) is composed of LiF and Li₂S, interwoven with each other to form a consecutive solid electrolyte interphase. Simultaneously, brand-new vertical Co fibers (diameter: ≈5 µm) scaffold is designed via a facile magnetic-field-assisted hydrothermal method to collaborate with plasma-enhanced Li metal anodes (SFI@Li/Co). The Co fibers scaffold accommodates active Li with mechanical integrity and decreases local current density with good lithiophilicity and low geometric tortuosity, supported by DFT calculations and COMSOL Multiphysics simulation. Consequently, the assembled symmetric cells with SFI@Li/Co anodes exhibit superior stability over 525 h with a small voltage hysteresis (125 mV at 5 mA cm⁻²) and improved Coulombic efficiency (99.7%), much better than the counterparts. Enhanced electrochemical performance is also demonstrated in full cells with commercial cathodes and SFI@Li/Co anode. The research offers a new route to develop advanced alkali metal anodes for energy storage.