Nanostructures and lithium electrochemical reactivity of lithium titanites and titanium oxides: A review

Being inherently safe and chemically compatible with the electrolyte, titanium oxide-based materials, including both Li-titanites and various TiO₂ polymorphs, are considered alternatives to carbonaceous anodes in Li-ion batteries. Given the commercial success of the spinel lithium titanites, TiO₂ polymorphs, in particular in nanostructured forms, have been fabricated and investigated for the applications. Nanostructuring leads to increased reaction areas, shortened Li⁺ diffusion and potentially enhanced solubility/capacity. Integration with an electron-conductive second phase into the TiO₂-based nanostructures eases the electron transport, resulting in further improved lithium electrochemical activity and the overall electrochemical performance. This paper reviews structural characteristics and Li-electrochemical reactivity, along with synthetic approaches, of nanostructures and nano-composites based on lithium titanites and TiO₂ polymorphs that include rutile, anatase, bronze and brookite.     

PVLab,a Powerful,Innovative Software Package for the Simulation of Photovoltaic Systems

This paper describes a new, highly modular, simulation tool named ＂PVLab＂ and developed by the GREMAN laboratory. It is designed to assist the designer in the sizing ofPV （photovoltaic） installations. The programming structure and physical models implemented within this tool are described, and several case studies are proposed to highlight its relevance. The predicted yearly electrical energy production of grid-connected PV plants is discussed. In particular, the predicted performance of such plants is compared with that given by the PVsyst software. PVLab has a high level of flexibility, allowing its physical models and databases （e.g., meteorological data） to be modified according to the user＇s needs. This is made possible through the use of expertise applied to all of the computing steps, and to the MATLAB development environment. The user＇s ability to control the source code itself will allow much greater progress to be made in the field of renewable energy applications than with PVsyst, which is currently the commercial reference.     

Growth and morphology of sputtered aluminum thin films on P3HT surfaces

Growth and morphology of an aluminum (Al) contact on a poly(3-hexylthiophene) (P3HT) thin film are investigated with X-ray methods and related to the interactions at the Al:P3HT interface. Grazing incidence small-angle scattering (GISAXS) is applied in situ during Al sputter deposition to monitor the growth of the layer. A growth mode is found, in which the polymer surface is wetted and rapidly covered with a continuous layer. This growth type results in a homogeneous film without voids and is explained by the strong chemical interaction between Al and P3HT, which suppresses the formation of three-dimensional cluster structures. A corresponding three stage growth model (surface bonding, agglomeration, and layer growth) is derived. X-ray reflectivity shows the penetration of Al atoms into the P3HT film during deposition and the presence of a 2 nm thick intermixing layer at the Al:P3HT interface.     

An enhanced Lemaitre model formulation for materials processing damage computation

The Lemaitre damage model is now widely used to deal with coupled damage analyses for various mechanical applications. In this article, different extensions of the model are presented and discussed to deal with complex multiaxial configurations—such as multi-stages bulk forming processes. A specific treatment is done to account for compressive damage growth, and a stress triaxiality cut-off value is considered to avoid any damage evolution below a critical negative triaxiality. The damage potential is also modified to deal with highly ductile materials, and the plastic strain is split into a negative part and a positive part to differentiate damage growth for compressive states of stress and for tensile states of stress. Finally, an anisotropic damage approach based on the comparison between grain flow orientation and principal loading directions is defined. A combination of these extensions is achieved within a single Lemaitre formulation. Application on different examples show the robustness and accuracy of the model defined in this paper.     

High-frequency homogenization for checkerboard structures: defect modes, ultrarefraction, and all-angle negative refraction

The counterintuitive properties of photonic crystals, such as all-angle negative refraction (AANR) [J. Mod. Opt.34, 1589 (1987)] and high-directivity via ultrarefraction [Phys. Rev. Lett.89, 213902 (2002)], as well as localized defect modes, are known to be associated with anomalous dispersion near the edge of stop bands. We explore the implications of an asymptotic approach to uncover the underlying structure behind these phenomena. Conventional homogenization is widely assumed to be ineffective for modeling photonic crystals as it is limited to low frequencies when the wavelength is long relative to the microstructural length scales. Here a recently developed high-frequency homogenization (HFH) theory [Proc. R. Soc. Lond. A466, 2341 (2010)] is used to generate effective partial differential equations on a macroscale, which have the microscale embedded within them through averaged quantities, for checkerboard media. For physical applications, ultrarefraction is well described by an equivalent homogeneous medium with an effective refractive index given by the HFH procedure, the decay behavior of localized defect modes is characterized completely, and frequencies at which AANR occurs are all determined analytically. We illustrate our findings numerically with a finite-size checkerboard using finite elements, and we emphasize that conventional effective medium theory cannot handle such high frequencies. Finally, we look at light confinement effects in finite-size checkerboards behaving as open resonators when the condition for AANR is met [J. Phys. Condens. Matter 15, 6345 (2003)].     

Synthesis and characterization of a water-soluble rigid-rod polymer

Water-soluble polyaramides have been prepared from 2,5-diaminobenzene-sulphonic-acid activated by TMSCl and terephthalic-acid-chloride. Using this method, we achieved molecular weights of our polymers up to 18,000 g mol⁻¹. Two model compounds were synthesized in order to establish the effect of trimethylsilyl-chloride, which was used as the activating agent for this reaction. The resulting sulphonated poly-aramides were characterized by: inherent viscosity measurements, size exclusion chromatography (SEC), DMA, TGA, flame absorbance atomic spectroscopy (FAAS), NMR spectroscopy and optical polarisation microscopy. In all cases, the polymers were easily soluble in hot water up to concentrations of 20 wt%. Upon cooling lyotropic alignment of molecular aggregates is observed at low polymer concentrations, typically 2–5 wt%. Polymers with low molecular weights do not show this behaviour. Films made from these sulphonated aramide polymers showed good thermal stability, and have interesting mechanical properties. Our results indicate the presence of a structure consisting of molecular aggregates.     

Multitrack Digital Data Storage: A Reduced Complexity Architecture

We describe a low-complexity noniterative detector for magnetic and optical multitrack high-density data storage. The detector is based on the M-algorithm architecture. It performs limited breadth-first detection on the equivalent one-dimensional (1-D) channel obtained by column-by-column helical unwinding of the two-dimensional (2-D) channel. The detection performance is optimized by the use of a specific 2-D minimum-phase factorization of the channel impulse response by the equalizer. An optimized path selection scheme maintains the complexity close to practical 1-D Viterbi. This scheme is based on an approximate path metric parallel sort network, taking advantage of the metrics' residual ordering from previous M-algorithm iterations. Such an architecture approaches maximum-likelihood performance on a high areal density uncoded channel for a practical number of retained paths M and bit error rate (BER) below 10^-4. The performance of the system is evaluated when the channel is encoded with multi-parity check (MPC) block inner code and an outer interleaved Reed-Solomon code. The inner code enhances the minimum error distance of the equalized channel and reduces the correct path losses of the M-algorithm path buffer. The decoding is performed noniteratively. Here, we compare the performance of the system to the soft iterative joint decoding of the read channels for data pages encoded with low-density parity check (LDPC) codes with comparable rates and block length. We provide an approximation of the 2-D channel capacity to further assess the performance of the system     

An Above-Elbow Prosthesis Employing Programmed Linkages

The use of EMG signals from residual muscles to control an above-elbow prosthesis has been tried, but presents many problems, not the least being that the prosthesis is under open-loop control. A more satisfactory control technique is extended physiological proprioception where the inherent proprioceptive feedback present within an intact joint is used to provide closed-loop control. We have developed a prototype of a self-contained above-elbow prosthesis which has electric-powered wrist and elbow joints controlled by an Intel 8751 microcomputer. Our technique is to control the positioning of this above-elbow prosthesis using the motion of the intact shoulder. Grasp, which does not involve positioning in space, is separately controlled using EMG signals from biceps and triceps muscles. The relationship between output (wrist and elbow positions) and input (shoulder position) can be set according to a program or linkage stored in the microcomputer memory. A choice from a range of linkages can enable the user to perform different tasks in different situations. We have verified experimentally that after an amputee has learned to associate the position of the wrist and elbow joints of the prosthesis with his shoulder position, the prosthesis will become a very useful aid. Also, because of the repeatability of operation and the inherent closed-loop nature of the prosthesis, the amputee will be motivated to wear it every day.