Kinetic and equilibrium studies in removing lead ions from aqueous solutions by natural sepiolite

The capacity of sepiolite for the removal of lead ions from aqueous solution was investigated under different experimental conditions. The Langmuir and Freundlich equations, which are in common use for describing sorption equilibrium for wastewater-treatment applications, were applied to data. The constants and correlation coefficients of these isotherm models for the present system at different conditions such as pH, temperature and particle size were calculated and compared. The equilibrium process was well described by the Langmuir isotherm model and the maximum sorption capacity was found to be 93.4 mg/g for the optimal experimental condition. The thermodynamic parameters (DeltaG(o), DeltaH(o) and DeltaS(o)) for lead sorption on the sepiolite were also determined from the temperature dependence. The influences of specific parameters such as the agitation speed, particle size and initial concentration for the kinetic studies were also examined. The sorption kinetics were tested for first order reversible, pseudo-first order and pseudo-second order reaction and the rate constants of kinetic models were calculated. The best correlation coefficients were obtained using the pseudo-second order kinetic model, indicating that lead uptake process followed the pseudo-second order rate expression.     

Rapid Light‐Triggered Drug Release in Liposomes Containing Small Amounts of Unsaturated and Porphyrin–Phospholipids

Prompt membrane permeabilization is a requisite for liposomes designed for local stimuli‐induced intravascular release of therapeutic payloads. Incorporation of a small amount (i.e., 5 molar percent) of an unsaturated phospholipid, such as dioleoylphosphatidylcholine (DOPC), accelerates near infrared (NIR) light‐triggered doxorubicin release in porphyrin–phospholipid (PoP) liposomes by an order of magnitude. In physiological conditions in vitro, the loaded drug can be released in a minute under NIR irradiation, while liposomes maintain serum stability otherwise. This enables rapid laser‐induced drug release using remarkably low amounts of PoP (i.e., 0.3 molar percent). Light‐triggered drug release occurs concomitantly with DOPC and cholesterol oxidation, as detected by mass spectrometry. In the presence of an oxygen scavenger or an antioxidant, light‐triggered drug release is inhibited, suggesting that the mechanism is related to singlet oxygen mediated oxidization of unsaturated lipids. Despite the irreversible modification of lipid composition, DOPC‐containing PoP liposome permeabilization is transient. Human pancreatic xenograft growth in mice is significantly delayed with a single chemophototherapy treatment following intravenous administration of 6 mg kg^?1 doxorubicin, loaded in liposomes containing small amounts of DOPC and PoP.     

Dexterous workspace optimization of an asymmetric six-degree of freedom Stewart–Gough platform type manipulator

In this paper, an asymmetric Generalized Stewart–Gough Platform (GSP) type parallel manipulator is designed by considering the type synthesis approach. The asymmetric six-Degree Of Freedom (DOF) manipulator optimized in this paper is selected among the GSPs classified under the name of 6D. The dexterous workspace optimization of Asymmetric parallel Manipulator with tEn Different Linear Actuator Lengths (AMEDLAL) subject to kinematics and geometric constraints is performed by using the Particle Swarm Optimization (PSO). The condition number and Minimum Singular Value (MSV) of homogenized Jacobian matrix are employed to obtain the dexterous workspace of AMEDLAL. Finally, the six-DOF AMEDLAL is also compared with the optimized Traditional Stewart–Gough Platform Manipulator (TSPM) considering the volume of the dexterous workspace in order to demonstrate its kinematic performance. Comparisons show that the manipulator proposed in this study illustrates better kinematic performance than TSPM.     

A novel microbial BOD biosensor developed by the immobilization of P. Syringae in micro‐cellular polymers

BACKGROUND: A biochemical oxygen demand (BOD) sensor, based on an immobilized Pseudomonas syringae in highly porous micro‐cellular polymer (MCP) in combination with a dissolved oxygen electrode, has been developed for the analysis of biodegradable organic compounds in aqueous samples. Microorganisms were immobilized in a molded MCP disk and a wastewater sample was injected into the biocomposite disk by a flow injection system. Dissolved oxygen (DO) changes as a measure of soluble BOD was read with a DO probe placed into a flow cell carrying biocatalytically activated disk. RESULTS: Optimal response of the MCP BOD sensor was obtained at pH 6.8 and 25 °C with a typical response time of 3–5 min for a 2 mm thick molded polymeric disk. The sensor showed detection linearity over the range 5–100 mg L^?1 BOD₅ (r² > 0.99) at a flow rate of 0.6 mL min^?1. The repeatability and reproducibility of the sensor response were found to be 3.08% and 7.77%, respectively. BOD values produced with this biosensor for various municipal and industrial wastewaters correlated well with those determined by the conventional 5‐day BOD test. CONCLUSION: This new biosensor was different from present amperometric BOD biosensor configurations in which the biocatalyst (microbial/enzymatic) is placed between cellulose and Teflon membranes installed on a DO probe. The use of a molded MCP disk coniainng microbial activity offers better stability and lifetime for commercial use in environmental monitoring. Copyright © 2008 Society of Chemical Industry     

Synthesis of poly(2,5-Thienylene Vinylene) and its derivatives: Low band gap materials for photovoltaics

Poly-(2,5-Thienylene Vinylene) (PTV) derivatives have been synthesised via the “dithiocarbamate precursor route” in good yield and satisfactory molecular weight. Structural characterisations of the conjugated PTV polymers reveal an optical band gap around 1.8 eV. Organic field effect transistors and organic based photovoltaic devices were made with the plain PTV, via a precursor approach. More specifically, solar cells were produced using a blend of the precursor PTV polymer and PCBM (1-(3-methoxycarbonyl) propyl-1-phenyl [6,6] C₆₁) at various ratios, converted in situ in thin film. A promising power efficiency of 0.76% was achieved.     

Goodput and throughput comparison of single‐hop and multi‐hop routing for IEEE 802.11 DCF‐based wireless networks under hidden terminal existence

We investigate how multi‐hop routing affects the goodput and throughput performances of IEEE 802.11 distributed coordination function‐based wireless networks compared with direct transmission (single hopping), when medium access control dynamics such as carrier sensing, collisions, retransmissions, and exponential backoff are taken into account under hidden terminal presence. We propose a semi‐Markov chain‐based goodput and throughput model for IEEE 802.11‐based wireless networks, which works accurately with both multi‐hopping and single hopping for different network topologies and over a large range of traffic loads. Results show that, under light traffic, there is little benefit of parallel transmissions and both single‐hop and multi‐hop routing achieve the same end‐to‐end goodput. Under moderate traffic, concurrent transmissions are favorable as multi‐hopping improves the goodput up to 730% with respect to single hopping for dense networks. At heavy traffic, multi‐hopping becomes unstable because of increased packet collisions and network congestion, and single‐hopping achieves higher network layer goodput compared with multi‐hop routing. As for the link layer throughput is concerned, multi‐hopping increases throughput 75 times for large networks, whereas single hopping may become advantageous for small networks. The results point out that the end‐to‐end goodput can be improved by adaptively switching between single hopping and multi‐hopping according to the traffic load and topology. Copyright © 2015 John Wiley & Sons, Ltd.     

A distributed activity scheduling algorithm for wireless sensor networks with partial coverage

One of the most important design objectives in wireless sensor networks (WSN) is minimizing the energy consumption since these networks are expected to operate in harsh conditions where the recharging of batteries is impractical, if not impossible. The sleep scheduling mechanism allows sensors to sleep intermittently in order to reduce energy consumption and extend network lifetime. In applications where 100% coverage of the network field is not crucial, allowing the coverage to drop below full coverage while keeping above a predetermined threshold, i.e., partial coverage, can further increase the network lifetime. In this paper, we develop the distributed adaptive sleep scheduling algorithm (DASSA) for WSNs with partial coverage. DASSA does not require location information of sensors while maintaining connectivity and satisfying a user defined coverage target. In DASSA, nodes use the residual energy levels and feedback from the sink for scheduling the activity of their neighbors. This feedback mechanism reduces the randomness in scheduling that would otherwise occur due to the absence of location information. The performance of DASSA is compared with an integer linear programming (ILP) based centralized sleep scheduling algorithm (CSSA), which is devised to find the maximum number of rounds the network can survive assuming that the location information of all sensors is available. DASSA is also compared with the decentralized DGT algorithm. DASSA attains network lifetimes up to 92% of the centralized solution and it achieves significantly longer lifetimes compared with the DGT algorithm.     

微生物对混凝土的侵蚀(英文)

微生物侵蚀会导致混凝土的严重破坏,尤其导致了城市污水收集和处理系统的过早破坏,使其需要提前修复。世界范围内的研究结果表明:处于污水和下水道污泥中的混凝土会遭受由硫酸盐、酸、CO2等导致的严重破坏。评述了混凝土处于利于细菌生长和生物降解环境中时的细菌、微生物侵蚀破坏过程。此外还分析了硫酸产生的机理(硫循环)、用于污水管道系统和农用工业的混凝土的受侵蚀破坏机理以及评价混凝土抵抗微生物侵蚀的方法。