Influence of TiN dopant on microstructure of TiB2 ceramic sintered by spark plasma

In this study, the impact of TiN as a sintering aid on the relative density and microstructure of TiB₂ ceramic was investigated. Monolithic TiB₂ and TiB₂ doped with 5?wt% TiN were sintered at 1900?°C for 7?min dwell time under the pressure of 40?MPa by spark plasma. The addition of TiN affected the microstructure of TiB₂-based sample considerably depicting the finer grains in the as-sintered ceramic. X-ray diffraction evaluation indicated that no interaction occurred between the initial materials. However, detail investigation by the map analysis and energy dispersive spectroscopy results revealed the formation of in-situ nano-sized hBN secondary phase in the TiN-doped TiB₂. In addition, TiN played a remarkable role on increasing the relative density of TiN-doped TiB₂ ceramic producing a nearly fully dense ceramic with relative density of 99.9% in comparison with the monolithic ceramic having 96.7% relative density.     

Water leakage problems at the Tangab Dam Reservoir (SW Iran), case study of the complexities of dams on karst

Bulletin of Engineering Geology and the Environment - The Tangab Dam was constructed at a unique geological structure, within a karst valley at the deepest point of a saddle-shaped feature which...     

Experimental characterization of the small strain shear modulus of soft clay stabilized with cement and nano-SiO2 using bender element tests

Bulletin of Engineering Geology and the Environment - The accurate and efficient modification of the static and dynamic properties of problematic soils is a primary concern in geotechnical...     

Fermentation of table cream by Lactobacillus plantarum strains: effect on fungal growth,aflatoxin M1 and ochratoxin A

Aflatoxin M1 (AFM₁) and ochratoxin A (OTA) are two main mycotoxins in milk and dairy products. In the present work, the ability of four Lactobacillus strains (L. plantarum PTCC 1058, L. plantarum LP3, L. plantarum AF1 and L. plantarum LU5) to remove AFM1 and OTA in fermented cream was studied during 24 h fermentation. The antifungal activity of the mentioned lactobacilli against the defined fungi (Aspergillus flavus PTCC 5004, Aspergillus parasiticus PTCC 5018, Aspergillus nidulans PTCC 5014, Aspergillus ochraceus PTCC 5060) was also evaluated. The results showed that the cell counts of all strains were increased by 64–70% during fermentation. All Lactobacillus strains decreased the amount of AFM₁ significantly (P ≤ 0.05) in the range of 26–52%, which the highest AFM₁-reducing effect was related to L. plantarum LU5 (from 0.5 to 0.24 μg kg⁻¹). The mean OTA removal by Lactobacillus strains in fermented cream also ranged from 32 to 58%. Amongst Lactobacillus strains, the cell-free culture supernatants of L. plantarum LU5 showed the highest (inhibition zone of 26.7 ± 1.2 mm) and L. plantarum LP3 and L. plantarum PTCC 1058 the lowest antifungal activities. The fermented creams contained Lactobacillus strains exhibited the highest and lowest antifungal activities against A. ochraceus and A. parasiticus, respectively. L. plantarum LU5, with the inhibition zone of 27.6 ± 0.9 mm, was the most effective fungal inhibitor, while L. plantarum PTCC 1058 had the lowest antifungal activity.     

Experimental Investigation on the Removal of p-Toluic Acid from Aqueous Solution using Functionalized Polymeric Sorbent

Polystyrene-divinylbenzene copolymer (PsDVB) was covalently functionalized with monoethanolamine (MEA), diethanolamine (DEA), and triethanolamine (TEA) by a simple method. The functionalized sorbents were characterized in terms of functionality and morphology, and used for the removal of p-toluic acid (p-TA) from aqueous solution. It was found that DEA-PsDVB has higher adsorption capacity than MEA- and TEA-PsDVB due to more accessible nitro and hydroxyl groups on its surface. Further investigation on the adsorptive properties of DEA-PsDVB indicated that the maximum uptake of p-TA occurred at the optimum pH of 5.3. The kinetics data was successfully represented by the pseudo-first-order model, and the behavior of the adsorption isotherms followed the Freundlich model well. Thermodynamic studies showed that the adsorption of p-TA onto DEA-PsDVB was an endothermic and spontaneous process along with the positive change in entropy. The regeneration of DEA-PsDVB was performed with 0.1 M NaOH solution, and results showed that 99% of the initial capacity was conserved after eight successive adsorption/regeneration cycles.     

Optimisation of a combined Stirling cycle–organic Rankine cycle using a genetic algorithm

In a Stirling cycle a huge amount of energy is wasted due to the losses. This wasted energy may be utilised as a heat source for the boiler of an organic Rankine cycle (ORC). Combination of these two cycles leads to an increased cycle efficiency compared to a single Stirling cycle and the analysis and optimisation of the integrated system is carried out. Optimisation is performed using the genetic algorithm and considering three decision variables: the temperature of the cold tank of the Stirling cycle, the pressure ratio and the temperature of the ORC condenser. In optimisation, the efficiency is considered as the objective function and the highest value is achieved by adjusting the decision variables. Using this method, the efficiency of the overall combined cycle was improved in which the highest efficiency was obtained to be 41.5%.     

Effect of different levels of fat and inulin on the microbial growth and metabolites in probiotic yogurt containing nonviable bacteria

Effects of different levels of fat and inulin on bacterial cell counts, degree of proteolysis and concentrations of organic acids in the yogurt containing inactivated cells of probiotic strains Bifidobacterium animalis and Lactobacillus acidophilus were investigated. Results showed that both L. acidophilus and B. animalis grew well in the yogurt samples reaching cell counts higher than 10⁶ CFU mL^?1 at the final pH of 4.5. Inulin at the concentration of 1% had no significant effects on the production of organic acids and cell counts of L. acidophilus, but promoted the growth of B. animalis with a reduction in the degree of proteolysis. Generally, different fat levels showed significant effects on the production of organic acids and nonsignificant effects on the cell counts of probiotic bacteria and degree of proteolysis. In case of lactic acid, the ratio of L‐ (+)to D‐ (?) isomer ranged from 50/50 to 80/20 in yogurt samples.     

Antibacterial effects of chitosan coating containing Mentha aquatica L. essence against Escherichia coli,Staphylococcus aureus and Listeria monocytogenes in Iranian white cheese

The effect of a chitosan coating and Mentha aquatica L. essence on Iranian white cheese was investigated. Results showed 100% inhibition of Escherichia coli growth using 1.5% essence after 10 days. After 15 days of incubation, the Staphylococcus aureus population was reduced by 44.2%, 70.0%, and 88.5% using 0.5, 1.0 and 1.5% essence, respectively. After 15 days, Listeria monocytogenes growth was inhibited by 63.84%, 70.12%, and 85.9% using 0.5, 1.0, and 1.5% essence, respectively. Inhibition zone diameter studies also confirmed the antibacterial effects of applied coating against all the above‐mentioned bacteria in Iranian white cheese.     

An improved cluster formation process in wireless sensor network to decrease energy consumption

Wireless sensor network has special features and many applications, which have attracted attention of many scientists. High energy consumption of these networks, as a drawback, can be reduced by a hierarchical routing algorithm. The proposed algorithm is based on the Low Energy Adaptive Clustering Hierarchy (LEACH) and Quadrant Cluster based LEACH (Q-LEACH) protocols. To reduce energy consumption and provide a more appropriate coverage, the network was divided into several regions and clusters were formed within each region. In selecting the cluster head (CH) in each round, the amount of residual energy and the distance from the center of each node were calculated by the base station (including the location and residual energy of each node) for all living nodes in each region. In this regard, the node with the largest value had the highest priority to be selected as the CH in each network region. The base station calculates the CH due to the lack of energy constraints and is also responsible for informing it throughout the network, which reduces the load consumption and tasks of nodes in the network. The information transfer steps in this protocol are similar to the LEACH protocol stages. To better evaluate the results, the proposed method was implemented with LEACH LEACH-SWDN, and Q-LEACH protocols using MATLAB software. The results showed better performance of the proposed method in network lifetime, first node death time, and the last node death time.