An assessment of the ability of computational fluid dynamic models to predict reactive gas–solid flows in a fluidized bed

Fine grid, two dimensional simulations of reactive gas–solid flows occurring in a fluidized bed reactor were carried out using the Eulerian multi-fluid kinetic theory of granular flow (KTGF) approach in the commercial flow solver, ANSYS FLUENT 12.1. The fuel reactor of a pilot scale Chemical Looping Combustion rig, operated in the bubbling fluidization regime at the Vienna University of Technology, was simulated. Grid dependence studies were carried out as well as sensitivity studies to the fuel inlet condition and the inclusion of gas phase turbulence. Simulations could not accurately reproduce the experimental trend for the case when highly reactive nickel oxide was used as the oxygen carrier material, but in general satisfactory quantitative agreement was observed. The failure to correctly capture the experimental trend was primarily attributed to the fine length-scales at the feed gas inlets not being adequately resolved even at the finest grid investigated. The trend quickly worsened when coarser grids were used, indicating that the generality of the model is lost when grid dependence effects are present. A number of possible dimensional effects were also discussed. Subsequently, the model was used to successfully capture another experimental trend obtained with a much less reactive ilmenite oxygen carrier material. The model captured this trend correctly because the reaction was now limited by the reaction rate and not by species transfer to the large scale gas-emulsion interfaces. Results were therefore not as sensitive to the correct hydrodynamic modelling of the interface, especially near the gas inlets, and the model retained its generality over a wide range of operating conditions.     

Double Dianhydride Backbone Polyimide Aerogels with Enhanced Thermal Insulation for High‐Temperature Applications

Aerogels owe their high thermal insulation and other unique properties to their nanostructure configuration. However, controlling the aerogels' morphology is always a scientific challenge. In this study, double dianhydride backbone (double backbone) polyimide aerogels with tailored nanostructure assembly are created for the first time. This is achieved by controlled polymerization reaction of oligomers with distinct dianhydride monomers. Combining the two oligomers through a controlled polymerization reaction is a successful strategy for tailoring the aerogels nanostructure assembly as well as other properties. The fabricated double backbone aerogel presents 40% reduced thermal conductivity of 19.7 mW mK^?1 over previously studied polyimide aerogels along with the compression modulus of 1.64 MPa at a relatively low density of 0.068 g cm^?3. Such low thermal conductivity is comparable with the inorganic counterparts. Light in weight and high thermally insulated polyimide aerogels with suitable mechanical properties and high service temperature are an appropriate replacement for current fireproof insulation materials.     

Melatonin Modulates Plant Tolerance to Heavy Metal Stress: Morphological Responses to Molecular Mechanisms

Heavy metal toxicity is one of the most devastating abiotic stresses. Heavy metals cause serious damage to plant growth and productivity, which is a major problem for sustainable agriculture. It adversely affects plant molecular physiology and biochemistry by generating osmotic stress, ionic imbalance, oxidative stress, membrane disorganization, cellular toxicity, and metabolic homeostasis. To improve and stimulate plant tolerance to heavy metal stress, the application of biostimulants can be an effective approach without threatening the ecosystem. Melatonin (N-acetyl-5-methoxytryptamine), a biostimulator, plant growth regulator, and antioxidant, promotes plant tolerance to heavy metal stress by improving redox and nutrient homeostasis, osmotic balance, and primary and secondary metabolism. It is important to perceive the complete and detailed regulatory mechanisms of exogenous and endogenous melatonin-mediated heavy metal-toxicity mitigation in plants to identify potential research gaps that should be addressed in the future. This review provides a novel insight to understand the multifunctional role of melatonin in reducing heavy metal stress and the underlying molecular mechanisms.     

GEOPHYSICAL CHARACTERIZATION OF THE SANGU GAS FIELD,OFFSHORE, BANGLADESH: CONSTRAINTS ON RESERVOIRS

The only produced offshore gas field in Bangladesh, known as the Sangu field, is located in the Hatiya Trough in the east of the Bay of Bengal, and has estimated total reserves of about 1055 BCF GIIP. The early shut-down of the field in October 2013 may have resulted in significant volumes of recoverable gas being left in the subsurface over a depth range of 1893 m to 3640 m. In this paper, seismic and well log data were analyzed and interpreted in order to investigate the structure and stratigraphy of the Sangu field, together with the lithology, extent and petrophysical properties of the reservoir. The general lithostratigraphy at Sangu has some similarity to that of the Surma Basin of the Bengal Foredeep. Reservoir rocks consist of Miocene and Pliocene deltaic sandstones and deep-water clastics. The source rock is the Miocene Bhuban Shale which is mature for gas generation in the Hatiya Trough. Three Neogene seismic stratigraphic megasequences were recognised at Sangu and are interpreted to have been deposited respectively in fluvial, delta front and shelf slope or marginal marine settings. Based on an analysis of wireline logs from wells Sangu-1 and Sangu-5 and on seismic-to-well ties, a series of reservoir units referred to (from the base up) as the T1 (E, D, C, A&B), Supra-T1, T2 and T3 have been identified. Petrophysical analyses showed that the average total porosity of these reservoir units is >13%, the permeability is in general less than10 mD, and the gas saturation ranges from 24% to 80%. Mapping of the reservoirs shows that the structure at Sangu is an asymmetric anticline with a NNW-SSE axial trend. Amplitude data have allowed the delineation of two other potential reservoir zones in the field at depths of 2900-3000 m and 3550-3750 m. The study will contribute to future offshore gas exploration and development in the Bay of Bengal region based on the geological and geophysical characteristics of the reservoirs delineated.     

Word of Mouth impact on the adoption of mobile banking in Iran

Purpose

The purpose of this paper is to explore word of mouth impact on the adoption of mobile banking in Iran. This study provides insights into factors affecting the adoption of mobile banking in Iran.

Fusion reactions in high-density hydrogen: A fast route to small-scale fusion?

High-density atomic hydrogen, which is believed to be a quantum liquid, can be formed by heterogeneous catalysis at the surface of hydrogen-transfer metal oxide catalysts. Extensive studies have been made of the hydrogen phase named H(1), with interatomic distance of 150 pm found by Coulomb explosion measurements. This bond distance corresponds to a material density of 0.5–0.7 kg dm⁻³. The use of this material as fusion target for inertial confinement fusion (ICF) is proposed in J Fusion Energy 2008;27:296–300. A much denser hydrogen (deuterium) material D(−1) also exists with an interatomic distance of 2.3 pm. This material is probably the inverse of metallic D(1), where nuclei and electrons exchange their roles. The ICF process would be greatly simplified if the intended initial multi-laser compression stage was not necessary. The close-packed density of D(−1) is calculated from the bond distance as >130 kg cm⁻³. This is much higher than that required for “fast ignition” laser-driven fusion (>0.3 kg cm⁻³). It may mean that a method already exists to prepare dense hydrogen fuel for small-scale laser-driven fusion. The high energy particles observed experimentally (up to 150 keV/atomic mass unit in the peak or 10⁹ K) indicate that high energy processes exist at relatively low laser intensities.     

Modeling of Dispersive Materials Using Dispersion Models for FDTD Application

A nonlinear optimization algorithm based on the Nelder Mead method is used to characterize the frequency dependent permittivity of 15 materials based on Lorentz, modified Lorentz, Drude and Lorentz-Drude models. The optimized model parameters are used to calculate the complex relative permittivity of each material and compare it with experimental data. In each case, a very good match is found between the optimized and experimental data over a long wavelength range. Comparative study of the models used for each material is performed based on accuracy, wavelength range of applicability and computational efficiency. The parameters presented can be used for computer simulation of electromagnetic wave phenomena involving these materials.     

Prediction of CO<Subscript>2</Subscript> mass transfer parameters to light oil in presence of surfactants and silica nanoparticles synthesized in cationic reverse micellar system

CO₂ miscible injection method combined with surfactants and silica nanoparticles was studied to investigate the effect of these additives on CO₂ mass transfer parameters to the light oil, including diffusion coefficient, mass transfer coefficient and solubility. Silica nanoparticles with controlled size distribution were synthesized in isooctane/1-hexanol/CTAB/ammonium hydroxide, a highly-stable reverse micellar system with w _o =5. The presence of Si-O-Si and Si-O-H bonds in FTIR spectra of the system revealed that silica nanoparticles are formed by partial hydrolysis of TEOS. Results of DLS indicated that the average size and size distribution of the synthesized nanoparticles were 27.6 nm and 13-76 nm, respectively. Diffusion tests were carried out using CO₂ gas and three liquid systems: isooctane/1-hexanol, isooctane/1-hexanol/CTAB reverse micellar system without nanoparticles, and isooctane/1-hexanol/CTAB reverse micellar system with nanoparticles. Results of modeling and optimization of the gas-liquid systems under nonequilibrium interface condition, using pressure decay data show that the presence of surfactants and nanoparticles leads to decreased gas diffusion coefficient; while increased interface mass transfer resistance due to presence of aqueous droplets and nanoparticles as well as lower solubility of CO₂ in the light oil are the results of applying these additives, which limits their application. The obtained CO₂ diffusion coefficients for isooctane/1-hexanol, reverse micellar system without nanoparticles, and reverse micellar system with nanoparticles are 8.5550×10^?8, 8.2216×10^?8, and 8.1114×10^?8 m²/s, respectively.     

Innovative Internally Circulating Reactor Concept for Chemical Looping‐Based CO2 Capture Processes: Hydrodynamic Investigation

An experimental hydrodynamic investigation has been carried out for a novel internally circulating chemical looping (ICCL) reactor concept proposed to reduce the technical complexities encountered in conventional chemical looping combustion (CLC) and reforming (CLR) technologies. The concept consists of a single reactor with internal physical separations dividing it into two sections, i.e., the fuel and air sections. The trade‐off for this reduction in process complexity is increased gas leakage between the two reactor sections, so a pseudo‐2D cold‐flow experimental unit was designed. The ICCL concept remains highly efficient in terms of CO₂ separation while ensuring significant process simplifications. The solids circulation rate also proved easy to control by adjusting the fluidization velocity ratio and the bed loading. In the light of the excellent hydrodynamic performance, the ICCL concept appears to be well‐suited for further development as a CLC/CLR reactor model.     

<Emphasis Type="Italic">Brassica rapa</Emphasis> var. <Emphasis Type="Italic">japonica</Emphasis> Leaf Extract Mediated Green Synthesis of Crystalline Silver Nanoparticles and Evaluation of Their Stability,Cytotoxicity and Antibacterial Activity

Silver nanoparticles (AgNPs) were successfully synthesized from the reduction of Ag⁺ using AgNO₃ solution as a precursor and Brassica rapa var. japonica leaf extract as a reducing and capping agent. This study was aimed at synthesis of AgNPs, exhibiting less toxicity with high antibacterial activity. The characterization of AgNPs was carried out using UV–Vis spectrometry, energy dispersive X-ray spectrometry, fourier transform infrared spectrometry, field emission scanning electron microscopy, X-ray diffraction, atomic absorption spectrometry, and transmission electron microscopy analyses. The analyses data revealed the successful synthesis of nano-crystalline Ag possessing more stability than commercial AgNPs. The cytotoxicity of Brassica AgNPs was compared with commercial AgNPs using in vitro PC12 cell model. Commercial AgNPs reduced cell viability to 23% (control 97%) and increased lactate dehydrogenase activity at a concentration of 3 ppm, whereas, Brassica AgNPs did not show any effects on both of the cytotoxicity parameters up to a concentration level of 10 ppm in PC12 cells. Moreover, Brassica AgNPs exhibited antibacterial activity in terms of zone of inhibition against E. coli (11.1?±?0.5 mm) and Enterobacter sp. (15?±?0.5 mm) which was higher than some previously reported green-synthesised AgNPs. Thus, this finding can be a matter of interest for the production and safe use of green-AgNPs in consumer products.