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排序方式: 共有171条查询结果,搜索用时 31 毫秒
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H. B. Mihiri Shashikala Arghya Chakravorty Shailesh Kumar Panday Emil Alexov 《International journal of molecular sciences》2021,22(1)
Ions play significant roles in biological processes—they may specifically bind to a protein site or bind non-specifically on its surface. Although the role of specifically bound ions ranges from actively providing structural compactness via coordination of charge–charge interactions to numerous enzymatic activities, non-specifically surface-bound ions are also crucial to maintaining a protein’s stability, responding to pH and ion concentration changes, and contributing to other biological processes. However, the experimental determination of the positions of non-specifically bound ions is not trivial, since they may have a low residential time and experience significant thermal fluctuation of their positions. Here, we report a new release of a computational method, the BION-2 method, that predicts the positions of non-specifically surface-bound ions. The BION-2 utilizes the Gaussian-based treatment of ions within the framework of the modified Poisson–Boltzmann equation, which does not require a sharp boundary between the protein and water phase. Thus, the predictions are done by the balance of the energy of interaction between the protein charges and the corresponding ions and the de-solvation penalty of the ions as they approach the protein. The BION-2 is tested against experimentally determined ion’s positions and it is demonstrated that it outperforms the old BION and other available tools. 相似文献
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Shailesh Kumar Singh Somnath Chattopadhyaya Alokesh Pramanik Sanjeev Kumar 《The International Journal of Advanced Manufacturing Technology》2018,95(5-8):1665-1676
Quantitative information about the contributions of individual cutting phenomena to linear roughness profiles may aid in optimizing processes with fewer expensive successive trial parts. Linear roughness profiles of metallic hard turned parts contain feed marks, each mark representing a snapshot in time of the state of the cut. This suggests that roughness measuring machines may be an attractive avenue for offline, inexpensive, non-destructive, quantitative evaluation of the time-dependent mechanisms active during the cut. Principal component analysis of feed marks reveals theoretically expected feed mark deformations without coercing the data by fitting. Novel in this paper, we show that those components of feed mark variability appear to correspond to radial and axial displacement of the cutting tool, ploughing, and side flow. Those components are sufficient to explain nearly all the variability between feed marks. The components are easily idealized in a general manner, and their influences on experimental profiles are quantified as percentage contributions to ordinary roughness parameters. 相似文献
136.
Shailesh Joshi J. S. Brahmaji Rao K. Sivasubramanian R. Kumar V. Jayaraman B. Venkatraman 《Journal of Polymer Research》2017,24(5):78
Towards development of lung tissue substitute used in the calibration of lung counters, seven sets of polyurethane (PU) foam were synthesized exhibiting a density range of 0.14–0.42 g/cm3 by varying the quantity of foaming agent (water) in the formulation. Foam sets were characterized by Fourier transform infrared spectroscopy, elemental analysis and thermo gravimetric analysis. Effect of density on the properties of PU foam is investigated. In addition, attenuation behavior of synthesized material for low energy (<100 keV) gamma rays was checked by using 241Am & 133Ba sources and planar high purity germanium detector. Moreover, the linear and mass attenuation coefficients of all sets were calculated and were found to be in agreement to the reported values. 相似文献
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Multifunctional Three‐Dimensional T‐Junction Graphene Micro‐Wells: Energy‐Efficient,Plasma‐Enabled Growth and Instant Water‐Based Transfer for Flexible Device Applications
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Shailesh Kumar Timothy van der Laan Amanda Evelyn Rider Lakshman Randeniya Kostya Ostrikov 《Advanced functional materials》2014,24(39):6114-6122
The “third‐generation” 3D graphene structures, T‐junction graphene micro‐wells (T‐GMWs) are produced on cheap polycrystalline Cu foils in a single‐step, low‐temperature (270 °C), energy‐efficient, and environment‐friendly dry plasma‐enabled process. T‐GMWs comprise vertical graphene (VG) petal‐like sheets that seemlessly integrate with each other and the underlying horizontal graphene sheets by forming T‐junctions. The microwells have the pico‐to‐femto‐liter storage capacity and precipitate compartmentalized PBS crystals. The T‐GMW films are transferred from the Cu substrates, without damage to the both, in de‐ionized or tap water, at room temperature, and without commonly used sacrificial materials or hazardous chemicals. The Cu substrates are then re‐used to produce similar‐quality T‐GMWs after a simple plasma conditioning. The isolated T‐GMW films are transferred to diverse substrates and devices and show remarkable recovery of their electrical, optical, and hazardous NO2 gas sensing properties upon repeated bending (down to 1 mm radius) and release of flexible trasparent display plastic substrates. The plasma‐enabled mechanism of T‐GMW isolation in water is proposed and supported by the Cu plasma surface modification analysis. Our GMWs are suitable for various optoelectronic, sesning, energy, and biomedical applications while the growth approach is potentially scalable for future pilot‐scale industrial production. 相似文献
139.
Lingxiang Zhu Deqiang Yin Yueling Qin Shailesh Konda Shawn Zhang Aiden Zhu Shuai Liu Ting Xu Mark T. Swihart Haiqing Lin 《Advanced functional materials》2019,29(36)
Mixed matrix membranes (MMMs) comprising size‐sieving fillers dispersed in polymers exhibit diffusivity selectivity and may surpass the upper bound for gas separation, but their performance is limited by defects at the polymer/filler interface. Herein, a fundamentally different approach employing a highly sorptive filler that is inherently less sensitive to interfacial defects is reported. Palladium nanoparticles with extremely high H2 sorption are dispersed in polybenzimidazole at loadings near the percolation threshold, which increases both H2 permeability and H2/CO2 selectivity. Performance of these MMMs surpasses the state‐of‐the‐art upper bound for H2/CO2 separation with polymer‐based membranes. The success of these sorption‐enhanced MMMs for H2/CO2 separation may launch a new research paradigm that taps the enormous knowledge of affinities between gases and nanomaterials to design MMMs for a wide variety of gas separations. 相似文献
140.
On the trade-offs between risk pooling and logistics costs in a multi-plant network with commonality 总被引:1,自引:0,他引:1
This paper examines the benefits and costs of two alternative manufacturing network configurations in the presence of component commonality. We evaluate the trade-off between the decreased logistics costs and loss of risk-pooling benefits in plant networks which spread component manufacturing over each plant (product network) as compared to those that consolidate component manufacturing in a single plant (process network). We examine for conditions that mean that a product network would be chosen instead of a process network and vice-versa. We find that the risk-pooling benefit obtained by consolidating common subassembly production is reduced when the cost of acquiring common component capacity is sufficiently high or low. A post-optimality sensitivity analysis for the process network provides insights into subtle substitution effects, which are a direct outcome of cost mix differentials and network structure and complementarity effects, which are induced by the considered sequential assembly system. Our results suggest that the impact of operational cost parameters on strategic decisions can often be non-intuitive. Overall, our analysis provides a link between strategic and operational decision-making in supply chain management, in the context of multi-plant configuration. 相似文献