Design and implementation of all MOS micro-power voltage reference circuit

In this work we are proposing the all MOST based reference voltage generating circuit, which utilizes the classical principle of addition of two voltages with opposite temperature coefficients. The targeted application of the proposed circuit is a low-dropout regulator which is used in a RF energy harvesting system. The proposed voltage reference circuit is implemented using a standard 0.18 μm CMOS technology. It generates the average reference voltage of 543.658 mV with an average temperature coefficient of 17.43 ppm/°C in the temperature range of ?40 to +85 °C, for the operating supply voltage ranging from 1.25 to 2 V. The maximum power consumption of the proposed architecture is ≈1.5 μW, including power dissipation in bias circuitry and the reference voltage generating core at 2 V supply voltage. The averaged measured line regulation is 1.642 mV/V. The measured power-supply rejection ratio without any filtering capacitor at 100 Hz and 1 MHz are ?62.24 and ?18.94 dB, respectively. Additionally, the measured noise density without any filtering capacitor at 10 Hz and 100 KHz is 20.54 and \(0.30\,\upmu \hbox {V}/\sqrt{\hbox{Hz}}\) , respectively. The proposed circuit has silicon area of ≈0.007 mm².     

Effect of prolonged isothermal exposure on elevated-temperature,time-dependent fatigue-crack propagation in INCONEL alloy 783

The effect of isothermal exposure on the elevated-temperature, time-dependent fatigue-crack propagation (FCP) in INCONEL Alloy 783 is investigated. Commercially produced Alloy 783 was annealed and aged following the standard heat-treatment procedure. One set of specimens was then isothermally exposed at 500 °C for 3000 hours. All specimens were subjected to FCP tests with various hold-time periods and sustained-loading crack-growth tests at 538 °C and 650 °C in a laboratory-air environment. Without a hold time, the as-produced and isothermally exposed materials had comparable FCP rates at both test temperatures. With hold times of 100 and 300 seconds, the as-produced and isothermally exposed specimens had comparable FCP rates at 538 °C. Hold-time testing of the as-produced material at 650 °C showed abnormal time-dependent FCP and sustained-loading crack-growth retardation. However, hold-time testing of isothermally exposed material at 650 °C showed the steady sustained-loading crack growth and fully time-dependent FCP typically observed in many superalloys. Comparison with Alloy 718 data from the literature shows that FCP rates of as-produced Alloy 718 and isothermally exposed Alloy 783 are comparable at 650 °C. A fully time-dependent FCP model based on the damage-zone concept and a thermal-activation equation is proposed to characterize the FCP behaviors.     

Comparison of the properties of porous silicon films with different back contacts (Ag, Al) for possible photovoltaic applications

In this work, porous silicon (PS) films were prepared by anodization on polished substrates of (1 0 0) Si for a fixed current density (I_d)20 mA cm⁻² and for a fixed anodization time of 30 min using different screen-printed (SP) back contacts, namely Ag and Al. The properties of PS formed using Ag as the back contact were found to be superior compared to the corresponding film using Al as the back contact. The PS formed with Ag-back contact exhibits higher porosity, negligible photoluminescence (PL) decay, better adherence to the substrate and smooth surface morphology compared to that formed with Al as the back contact for the same current density and time of anodization. Fourier transform infrared (FTIR) studies indicated significant presence of Si–O related features at 1050–1150 cm⁻¹ for PS films formed with Al as back contact, which could be responsible for traps and interface (PS–Si) defect densities as compared to corresponding PS films with Ag as the back contact. Measurements of capacitance–voltage (C–V) and current–voltage (I–V) were used for the investigation of the electrical properties of PS films with different back contacts. The frequency-dependent C–V characteristics were analysed to understand the effects of interface states and traps on the properties of PS films. The results have been analysed in terms of eutectic temperature and back surface field (BSF) across the metal–silicon interface.     

Oxidative cyanide-free cyanation on arylboronic acid derivatives using aryl/heteroaryl thiocyanate using novel IL-PdCl4 catalyst under mild condition

An efficient and simple method is reported for the cyanation on arylboronic acid using various simple/indole thiocyanates using a new IL-PdCl₄ catalyst. The cascade process involves a coupling reaction without any additive to give a wide range of cyanide derivatives. Cyanation on various arylboronic acids underwent smoothly affording the corresponding arylnitriles in good to high yields.     

Visible-Light-Mediated Decarboxylative Thiocyanation of Cinnamic acids: An Efficient Photocatalytic Approach to the Synthesis of (E)-Vinyl Thiocyanates

Catalysis Letters - A simple and novel methodology for the synthesis of vinyl thiocyanates from decarboxylative cross-coupling reaction of cinnamic acids with KSCN under the synergistic...     

Capacity investment and the value of operational flexibility in manufacturing systems with product blending

A distinct feature of process industries such as food, chemical and consumer packaged goods is the blending of intermediates into finished goods. In the context of such manufacturing systems the levels of different inputs that can be blended to process a final good define the range of flexibility. Likewise, the cost for using (blending) different inputs defines the mobility element of flexibility. In this paper, we investigate capacity investment and the value of flexibility in the presence of such product blending constraints. We are motivated by recent case studies of food manufacturers, in particular, those manufacturers that seek to increase flexibility via blending of intermediates. We analyse stochastic programs under demand uncertainty of such manufacturing systems. We provide analytical insights into trade-offs when range and mobility are interdependent. Our analytical work gives structural insights into subtle complementarity and substitution effects between dedicated and shared resources in the presence of blending. We analytically show that there is a degradation in the cost performance of such systems with an increase in correlation. We characterise the optimal blending fraction that balances the benefits of higher range with higher costs (lower mobility). Our numerical work shows that a moderate level of blending can significantly improve flexibility and that well-known guidelines for designing limited flexibility change in the presence of blending. For example, blending, even if optimally designed, weakens the appeal of chaining configurations. Overall our work guides resource configuration in industries where product blending is an integral part of the production process.     

Study on electrochemical behavior of Nano‐ZnO modified alkyd‐based waterborne coatings

A nano‐composite coating was formed using nano‐ZnO as pigment in different concentrations, to a specially developed alkyd‐based waterborne coating. The nano‐ZnO modified composite coatings were applied on mild steel substrate by dipping. The dispersion of nano‐ZnO particles in coating system was investigated by scanning electron microscopic and atomic force microscopic techniques. The effect of the addition of these nano‐pigments on the electrochemical behavior of the coating was investigated in 3.5% NaCl solution, using electrochemical impedance spectroscopy. Coating modified with higher concentration of nano‐ZnO particles showed comparatively better performance as was evident from the pore resistance (R_po) and coating capacitance (C_c) values after 30 days of exposure. In general, the study showed an improvement in the corrosion resistance of the nano‐particle modified coatings as compared with the neat coating, confirming the positive effect of nano‐particle addition in coatings. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2009     

“Effect of nano-ZnO particles on the corrosion behavior of alkyd-based waterborne coatings”

A nano-composite was formed by incorporating nano-ZnO in a specially developed alkyd-based waterborne coating to different loading levels. The nano-ZnO based composite coatings were applied on mild steel substrate by dipping. The coated panels were subjected to various test environments like salt-spray, humidity, UV and mechanical tests like scratch and abrasion. The improvement in electrochemical performance and mechanical properties of the composite coatings were evaluated using various analytical techniques. FTIR technique was used to investigate the interaction between nano-ZnO particles and the polymer functionalities. Differential scanning calorimetry (DSC) was done to study the curing behavior of nano-composite coatings. SEM and AFM were used to investigate dispersion of nano-ZnO particles and the changes in the surface behavior of the coatings before and after exposure to the test environment. The result showed that, with increase in the concentration of nano-ZnO there was an improvement in the corrosion resistance, UV resistance and mechanical properties of the coatings indicating the positive effect of addition of nano-ZnO particles in the coatings.     

Controlled modification of Pt/Al2O3 for the preferential oxidation of CO in hydrogen: A comparative study of modifying element

The catalytic performance of a series of Pt/Al₂O₃ catalysts, modified with Cr, Mn, Fe, Co, Ni, Cu and Sn, has been tested for the preferential oxidation of CO in hydrogen. The promoters were deposited onto the surface of a 5 wt.% monometallic Pt/Al₂O₃ catalyst using a controlled surface approach, to give a nominal promoter:Pt surface atomic ratio of 1:2 (corresponding to typically 0.15–0.25 wt.% of the promoting metal). The aim of this approach was to selectively create the Pt-promoter oxide interfacial sites considered to be important for the non-competitive dual-site mechanism proposed for such promoted catalysts. In this mechanism the promoting oxide is believed to act as an active oxygen provider, providing oxygen for the oxidation of the CO on the Pt. The catalysts were characterised using TEM, EDX, ICP-AES and CO chemisorption and results suggest that the promoter was successfully deposited on to the Pt surface. Even at the low loadings of promoter used, significant enhancement was observed in the catalytic performance of the PROX reaction in a simulated reformate mixture, for the Fe- and Co-promoted catalysts in particular (and to a lesser extent the Mn, Sn, Cu- and Ni-promoted catalysts), highlighting the successful preparation of the Pt-promoting metal oxide interfacial sites. The Mn-promoted catalyst, however showed no enhancement in the absence of water suggesting that the form of the promoting metal oxide may be particularly important for promotion of Pt for the PROX reaction.